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Author: N. Kharasch Publisher: Elsevier ISBN: 1483224856 Category : Science Languages : en Pages : 637
Book Description
Organic Sulfur Compounds, Volume I deals with the chemistry of organic sulfur compounds such as disulfides, polysulfides, olefins, acetylenes, and chloroethylenes. Topics covered range from the inorganic acids of sulfur and the thermodynamics of organic sulfur compounds to some applications of isotopic sulfur and the stereochemistry of disulfides and polysulfides. The mechanism of oxidation of thiols to disulfides is also discussed. Comprised of 40 chapters, this volume first considers the precise structures of elemental sulfur in relation to the reactions of sulfur compounds, followed by an analysis of the inorganic acids of sulfur. The reader is then introduced to the thermodynamics of organic sulfur compounds and the bonding characteristics of the sulfur atom, as well as the infrared spectra of organosulfur compounds. Subsequent chapters focus on the ionic scission of the sulfur-sulfur bond; nucleophilic reactions of thiols with acetylene and chloroethylene; reactions of sulfur with olefins; and the chemistry of isothiocyanates. This book should prove useful to advanced students, practitioners, and research workers in the field of organic chemistry.
Author: N. Kharasch Publisher: Elsevier ISBN: 1483224856 Category : Science Languages : en Pages : 637
Book Description
Organic Sulfur Compounds, Volume I deals with the chemistry of organic sulfur compounds such as disulfides, polysulfides, olefins, acetylenes, and chloroethylenes. Topics covered range from the inorganic acids of sulfur and the thermodynamics of organic sulfur compounds to some applications of isotopic sulfur and the stereochemistry of disulfides and polysulfides. The mechanism of oxidation of thiols to disulfides is also discussed. Comprised of 40 chapters, this volume first considers the precise structures of elemental sulfur in relation to the reactions of sulfur compounds, followed by an analysis of the inorganic acids of sulfur. The reader is then introduced to the thermodynamics of organic sulfur compounds and the bonding characteristics of the sulfur atom, as well as the infrared spectra of organosulfur compounds. Subsequent chapters focus on the ionic scission of the sulfur-sulfur bond; nucleophilic reactions of thiols with acetylene and chloroethylene; reactions of sulfur with olefins; and the chemistry of isothiocyanates. This book should prove useful to advanced students, practitioners, and research workers in the field of organic chemistry.
Author: Christopher T Walsh Publisher: Royal Society of Chemistry ISBN: 1839161442 Category : Science Languages : en Pages : 430
Book Description
This volume aims to provide an in-depth view of the complete biochemistry of sulfur with an emphasis on aspects not covered elsewhere. Given its role in the formation of proteins and presence in the amino acids methionine and cysteine, sulfur is essential to life. Current literature on the biochemistry of sulfur is vast and widely dispersed, as such this volume is intended as a single-source for everything concerning sulfur biochemistry from metabolic roles of inorganic sulfur, to thiol and thioether chemical biology, to the university of cysteine chemistry in proteomes. Authored by a renowned biochemist and experienced writer and educator, this book is ideal for students and researchers in biochemistry, biology and the life sciences with an interest in sulfur and its role in life.
Author: Eric Block Publisher: Academic Press ISBN: 1483216438 Category : Science Languages : en Pages : 336
Book Description
Organic Chemistry, Volume 37: Reactions of Organosulfur Compounds covers the basics of organosulfur chemistry and the characteristics of organically bound sulfur, with an emphasis on reactions, particularly those of synthetic utility. The book discusses the preparation, nature, stereochemical aspects, reactions, and the kinetic and thermodynamic assessment of the stability of sulfur-containing carbanions; the preparation and reactions of sulfur ylides; and the preparation, assessment of stability, and reactions of sulfur-containing carbocations. The text also describes preparation, assessment of stability, nature, and reactions of sulfur-containing radicals, organosulfur carbenes, and carbenoids; as well as the the pericyclic reactions of organosulfur compounds. Chemists, biochemists, and students taking related courses will find the book useful.
Author: Patrick Metzner Publisher: Elsevier ISBN: 1483289281 Category : Science Languages : en Pages : 219
Book Description
Designed for the practising organic chemist, this book details over a hundred experimental procedures using sulfer compounds in organic synthesis. Many of these methods are new to the literature, having been published since 1991, and illustrate the striking versatility of the use of sulfur reagents. Examples are simple to perform and extremely useful, and as such this book will be an invaluable aid to all involved in synthetic organic chemistry, whether in academic or industrial laboratories.
Author: Xuefeng Jiang Publisher: Springer Nature ISBN: 3030255980 Category : Science Languages : en Pages : 477
Book Description
The series Topics in Current Chemistry Collections presents critical reviews from the journal Topics in Current Chemistry organized in topical volumes. The scope of coverage is all areas of chemical science including the interfaces with related disciplines such as biology, medicine and materials science. The goal of each thematic volume is to give the non-specialist reader, whether in academia or industry, a comprehensive insight into an area where new research is emerging which is of interest to a larger scientific audience. Each review within the volume critically surveys one aspect of that topic and places it within the context of the volume as a whole. The most significant developments of the last 5 to 10 years are presented using selected examples to illustrate the principles discussed. The coverage is not intended to be an exhaustive summary of the field or include large quantities of data, but should rather be conceptual, concentrating on the methodological thinking that will allow the non-specialist reader to understand the information presented. Contributions also offer an outlook on potential future developments in the field.
Author: S. Oae Publisher: Springer Science & Business Media ISBN: 1468420496 Category : Science Languages : en Pages : 714
Book Description
In recent years organic sulfur chemistry has been growing at an even faster pace than the very rapid development in other fields of chemistry. This phenomenal growth is undoubtedly a reflection of industrial and public demands: not only was sulfur recently in overall surplus for the first time in the history of the chemical industry but it has now become a prin cipal environmental hazard in the form of sulfur dioxide, sulfuric acid and hydrogen sulfide. Another reason, discernible in the last fifteen years, has been the desire, on the part of individual chemists and all types of research managers, to move away from the established chemistry of carbon into the less well understood and sometimes virgin chemistries of the other elements which form covalent bonds. As a result of this movement the last decade has seen the development of sulfur chemistry into a well-organized and now much better understood branch of organic chemistry. Enough of the detail has become clear to see mechanistic interrelationships between previously unconnected reactions and with this clarification the whole subject has in tum become systema tized and subdivided. The divalent sulfur chemistry of thiols, monosulfides, disulfides and polysulfides is a large area in itself, much of it devoted to oxidation-reduction and the breakage and formation of sulfur-sulfur bonds, although interesting discoveries are now being made about the reac tivity of certain sulfur-carbon bonds. Of course, this area has its own mas sive biochemical branch involving enzymes and proteins.
Author: Francesco A. Devillanova Publisher: Royal Society of Chemistry ISBN: 0854043667 Category : Science Languages : en Pages : 889
Book Description
Provides an overview of the developments on the chemistry of the chalcogen group elements (S, Se and Te). Organised into two parts, this book deals systematically with the chemistry of chalcogens in relation to other group elements in the periodic table, and also includes an overview of metal-chalcogenides and metal-polychalcogenides.
Author: Leo A. Paquette Publisher: John Wiley & Sons ISBN: 1118634861 Category : Science Languages : en Pages : 1957
Book Description
There are a lot of books available about the chemistry and biology of sulfur. However, this is the first book with a compilation of all relevant Sulfur containing reagents. Synthetic chemists, most particularly in the medicinal and pharmaceutical chemists, are often called upon to prepare compounds that contain Sulfur as a key structural feature. In the past, this seemed to be a domain for specialists; today every synthetic chemist working in these area is expected to synthesize compounds containing sulfides, sulfates, sulfones, etc. This book offers an important source of information for the selection and handling of the right reagents.
Author: R. J. Cremlyn Publisher: John Wiley & Sons ISBN: Category : Science Languages : en Pages : 272
Book Description
Sulfur chemistry is becoming increasingly important as the role of this element is explored in both biological and environmental fields. After the initial chapters have discussed the synthesis, reactivity, and properties of the compounds in general, each of the next nine chapters takes a specific sulfur containing functional group and expands the discussion on synthetic procedures. The final chapter looks at the major uses of organo-sulfur compounds and their impact on biological and environmental areas.
Author: Institute of Medicine Publisher: National Academies Press ISBN: 030904832X Category : Medical Languages : en Pages : 448
Book Description
Recently, World War II veterans have come forward to claim compensation for health effects they say were caused by their participation in chemical warfare experiments. In response, the Veterans Administration asked the Institute of Medicine to study the issue. Based on a literature review and personal testimony from more than 250 affected veterans, this new volume discusses in detail the development and chemistry of mustard agents and Lewisite followed by interesting and informative discussions about these substances and their possible connection to a range of health problems, from cancer to reproductive disorders. The volume also offers an often chilling historical examination of the use of volunteers in chemical warfare experiments by the U.S. militaryâ€"what the then-young soldiers were told prior to the experiments, how they were "encouraged" to remain in the program, and how they were treated afterward. This comprehensive and controversial book will be of importance to policymakers and legislators, military and civilian planners, officials at the Department of Veterans Affairs, military historians, and researchers.
Author: N. Kharasch
Author: N. Kharasch
Author: Christopher T Walsh
Author: Eric Block
Author: Patrick Metzner
Author: Xuefeng Jiang
Author: S. Oae
Author: Francesco A. Devillanova
Author: Leo A. Paquette
Author: R. J. Cremlyn
Author: Institute of Medicine