Optical Polarization of Molecules

Optical Polarization of Molecules PDF Author: Marcis Auzinsh
Publisher: Cambridge University Press
ISBN: 0521443466
Category : Science
Languages : en
Pages : 326

Book Description
This book explains the theory and methods by which gas molecules can be polarized by light, a subject of considerable importance for what it tells us about the electronic structure of molecules and properties of chemical reactions. Starting with a brief review of molecular angular momentum, the text goes on to consider resonant absorption, fluorescence, photodissociation and photoionization, as well as collisions and static fields. A variety of macroscopic effects are considered, among them angular distribution and the polarization of emitted light, ground state depopulation, laser-induced dichroism, the effect of collisions and external magnetic and electric field effects. Most examples in the book are for diatomic molecules, but symmetric-top polyatomic molecules are also included. The book concludes with a short appendix of essential formulae, tables for vector calculus, spherical functions, Wigner rotation matrices, Clebsch-Gordan coefficients, and methods for expansion over irreducible tensors.

On the Distribution of Optical Polarization in Molecules

On the Distribution of Optical Polarization in Molecules PDF Author: P. A. Galwas
Publisher:
ISBN:
Category :
Languages : en
Pages : 0

Book Description


Nonlinear Optical Polarization Analysis in Chemistry and Biology

Nonlinear Optical Polarization Analysis in Chemistry and Biology PDF Author: Garth J. Simpson
Publisher: Cambridge University Press
ISBN: 1316797198
Category : Technology & Engineering
Languages : en
Pages : 499

Book Description
This rigorous yet accessible guide presents a molecular-based description of nonlinear optical polarization analysis of chemical and biological assemblies. It includes discussion of the most common nonlinear optical microscopy and interfacial measurements used for quantitative analysis, specifically second harmonic generation (SHG), two-photon excited fluorescence (2PEF), vibrational sum frequency generation (SFG), and coherent anti-Stokes Raman spectroscopy/stimulated Raman spectroscopy (CARS/SRS). A linear algebra mathematical framework is developed, allowing step-wise systematic connections to be made between the observable measurements and the molecular response. Effects considered include local field corrections, the molecular orientation distribution, rotations between the molecular frame, the local frame and the laboratory frame, and simplifications from molecular and macromolecular symmetry. Specific examples are provided throughout the book, working from the common and relatively simple case studies through to the most general scenarios.

Polarized Light in Optics and Spectroscopy

Polarized Light in Optics and Spectroscopy PDF Author: David S. Kliger
Publisher: Elsevier
ISBN: 0080571042
Category : Science
Languages : en
Pages : 315

Book Description
This comprehensive introduction to polarized light provides students and researchers with the background and the specialized knowledge needed to fully utilize polarized light. It provides a basic introduction to the interaction of light with matter for those unfamiliar with photochemistry and photophysics. An in-depth discussion of polarizing optics is also given. Different analytical techniques are introduced and compared and introductions to the use of polarized light in various forms of spectroscopy are provided. Starts at a basic level and develops tools for research problems Discusses practical devices for controlling polarized light Compares the Jones, Mueller, and Poincaré sphere methods of analysis

Optically Polarized Atoms

Optically Polarized Atoms PDF Author: Marcis Auzinsh
Publisher: Oxford University Press
ISBN: 0199565120
Category : Language Arts & Disciplines
Languages : en
Pages : 389

Book Description
An accessible textbook for students and practitioners of Atomic, Molecular, and Optical Physics. It will be useful for scientists working with lasers. The book comes with an extensive freely downloadable software package and many colourful and animated illustrations. Additional materials are available for instructors.

Vectorial Optical Fields

Vectorial Optical Fields PDF Author: Qiwen Zhan
Publisher: World Scientific
ISBN: 981444989X
Category : Science
Languages : en
Pages : 293

Book Description
Polarization is a vector nature of light that plays an important role in optical science and engineering. While existing textbook treatments of light assume beams with spatially homogeneous polarization, there is an increasing interest in vectorial optical fields with spatially engineered states of polarization. New effects and phenomena have been predicted and observed for light beams with these unconventional polarization states. This edited review volume aims to provide a comprehensive overview and summarize the latest developments in this important emerging field of optics. This book will cover the fundamentals including mathematical and physical descriptions, experimental generation, manipulation, focusing, propagation, and the applications of the engineered vectorial optical fields in focal field engineering, plasmonic focusing and optical antenna, single molecular imaging, optical tweezers/trapping, as well as optical measurements and instrumentations.

Electric-dipole Polarizabilities of Atoms, Molecules, and Clusters

Electric-dipole Polarizabilities of Atoms, Molecules, and Clusters PDF Author: Keith D. Bonin
Publisher: World Scientific
ISBN: 9789810224936
Category : Science
Languages : en
Pages : 274

Book Description
This book is an in-depth review of experiment and theory on electric-dipole polarizabilities. It is broad in scope, encompassing atomic, molecular, and cluster polarizabilities. Both static and dynamic polarizabilities are treated (in the absence of absorption) and a full tensor picture of the polarizability is used. Traditional experimental techniques for measuring electric polarizabilities are described in detail. Recently developed experimental methods, including light forces, position-sensitive time-of-flight deflection, and atom interferometry, are also extensively discussed. Theoretical techniques for calculating polarizabilities are reviewed, including a discussion on the use of Gaussian basis sets. Many important comparisons between theory and experiment are summarized in an extensive set of tables of polarizabilities of important atoms, molecules, and clusters. Applications of polarizabilities to many areas of chemistry and physics are described, including optics, chemical structure, interactions of gases and particles with surfaces, and the interaction of molecules with light. The emphasis is on a lucid presentation of the ideas and results with up-to-date discussions on important applications such as optical tweezers and nanostructure fabrication. This book provides an excellent overview of the importance of polarizabilities in understanding the physical, electronic, and optical properties of particles in a regime that goes from free atoms to condensed-phase clusters.

Introduction to Optics I

Introduction to Optics I PDF Author: Ksenia Dolgaleva
Publisher: Morgan & Claypool Publishers
ISBN: 1681739828
Category : Science
Languages : en
Pages : 113

Book Description
This book, Introduction to Optics I: Interaction of Light with Matter, is the first book in a series of four covering the introduction to optics and optical components. The author's targeted goal for this series is to provide clarity for the reader by addressing common difficulties encountered while trying to understand various optics concepts. This first book is organized and written in a way that is easy to follow, and is meant to be an excellent first book on optics, eventually leading the way for further study. Those with technical backgrounds as well as undergraduate students studying optics for the first time can benefit from this book series. The current book includes three chapters on light and its characteristics (Chapter 1), on matter from the standpoint of optics (Chapter 2), and on the interaction of light with matter (Chapter 3). Among the characteristics of light, the ones characterizing its speed, color, and strength are covered. The polarization of light will be covered in the next book of the series, where we discuss optical components. Chapter 2 discusses various atomic and molecular transitions activated by light (optical transitions). Different kinds of natural bulk material media are described: crystalline and amorphous, atomic and molecular, conductive and insulating. Chapter 3 on the interaction of light with matter describes naturally occurring phenomena such as absorption, dispersion, and nonlinear optical interactions. The discussion is provided for the natural bulk optical materials only. The interfaces between various materials will be covered in the next book on optical components. The following three books of the series are planned as follows. In the second book, we will focus on passive optical components such as lenses, mirrors, guided-wave, and polarization optical devices. In the third book, we will discuss laser sources and optical amplifiers. Finally, the fourth book in the series will cover optoelectronic devices, such as semiconductor light sources and detectors.

The Molecule as Meme

The Molecule as Meme PDF Author: Jeffrey Huw Williams
Publisher: Morgan & Claypool Publishers
ISBN: 1643272926
Category : Science
Languages : en
Pages : 146

Book Description
It was not until 1971 that the authority for defining scientific units, the General Conference of Weights and Measures got around to defining the unit that is the basis of chemistry (the mole, or the quantity of something). Yet for all this tardiness in putting the chemical sciences on a sound quantitative basis, chemistry is an old and venerable subject and one naturally asks the question, why? Well, the truth is that up until the mid-1920s, many physicists did not believe in the reality of molecules. Indeed, it was not until after the physics community had accepted Ernest Rutherford's 1913 solar-system-like model of the atom, and the quantum mechanical model of the coupling of electron spins in atoms that physicists started to take seriously the necessity of explaining the chemical changes that chemists had been observing, investigating and recording since the days of the alchemists.

Atoms, Molecules and Optical Physics 2

Atoms, Molecules and Optical Physics 2 PDF Author: Ingolf V. Hertel
Publisher: Springer
ISBN: 3642543138
Category : Science
Languages : en
Pages : 752

Book Description
This is the second volume of textbooks on atomic, molecular and optical physics, aiming at a comprehensive presentation of this highly productive branch of modern physics as an indispensable basis for many areas in physics and chemistry as well as in state of the art bio- and material-sciences. It primarily addresses advanced students (including PhD students), but in a number of selected subject areas the reader is lead up to the frontiers of present research. Thus even the active scientist is addressed. This volume 2 introduces lasers and quantum optics, while the main focus is on the structure of molecules and their spectroscopy, as well as on collision physics as the continuum counterpart to bound molecular states. The emphasis is always on the experiment and its interpretation, while the necessary theory is introduced from this perspective in a compact and occasionally somewhat heuristic manner, easy to follow even for beginners.