Author: Andrew James McGettrick
Publisher:
ISBN:
Category :
Languages : en
Pages : 0

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Author: Gordon S. Humphries
Publisher:
ISBN:
Category :
Languages : en
Pages : 0

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In-situ optical techniques offer one of the most attractive options for measuring species concentration and spatial distribution profiles in reacting environments, such as flames. The generally non-intrusive nature and spatial resolution of these techniques are now preferred over on extractive sampling, followed by analysis using techniques such as gas chromatography. In this thesis two laser absorption measurement techniques are applied to measure the soot distribution, and acetylene concentration profiles in a flat-flame burner. The in-situ measurement of the distribution of particulate matter in flames is a key step in understanding the mechanism of its formation. Most in-situ measurement systems for this purpose are based on laser induced incandescence where particles are heated using high power laser sources and the increased incandescence emission of the soot particles is detected. However as the soot cools by heat transfer to the surrounding gas, following laser heating, the pressure of the gas is increased creating an acoustic effect. Photoacoustic detection has been applied to quantify low concentrations of particulate matter in ambient air but there have been few applications of photoacoustic detection to the in-situ measurement of particulate matter formation in combustion processes. A novel simple approach using a modulated continuous wave diode laser is presented in this thesis. The measurements taken using this new technique are compared to measurements of the visible emission from the flame, and previous soot distribution measurements using laser induced incandescence. Absorption spectroscopy using near-infrared tunable diode lasers has been applied to measure species in several harsh environments such as aero-engine exhaust plumes, flames, and other industrial processes. Simple single pass absorption techniques are not always suitable for this purpose due to the low absorption of the target species, either due to low concentration or weak absorption line-strength at high temperatures. One method to increase the sensitivity of such techniques is by using cavity enhanced methods which increase the effective path length of the laser through the absorbing medium. One such cavity enhanced method is Cavity Ring-Down Spectroscopy (CRDS). CRDS uses a cavity constructed of highly reflecting mirrors, laser light is then coupled into this cavity and absorption measurements can be evaluated from the decay rate of light from the cavity. The design and, novel application of continuous wave CRDS to measure the concentration profile of acetylene in the flat-flame burner is presented. Difficulties in deriving an absolute acetylene concentration from the measured ringdown times were encountered due to the large number of interfering features. Serveral fitting and extraction techniques are applied and compared to attempt to overcome these difficulties.

Author: Yoshihiro Deguchi
Publisher: Taylor & Francis
ISBN: 1439853398
Category : Science
Languages : en
Pages : 301

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Book Description
Tighter regulations of harmful substances such as NOx, CO, heavy metals, particles, emissions from commercial plants and automobiles reflect a growing demand for lowering the anthropogenic burdens on the environment. It is equally important to monitor controlling factors to improve the operation of industrial machinery and plants. Among the many me

Author:
Publisher:
ISBN:
Category : Dissertations, Academic
Languages : en
Pages : 676

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Theses on any subject submitted by the academic libraries in the UK and Ireland.

Author: Toni Laurila
Publisher:
ISBN: 9789521514807
Category :
Languages : en
Pages : 59

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Author: Marc Gareth Sharma
Publisher:
ISBN:
Category :
Languages : en
Pages : 156

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Author:
Publisher:
ISBN:
Category :
Languages : en
Pages : 110

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Book Description
This program constructed and demonstrated an apparatus for the development of laser diagnostics for the gas phase molecules involved in semiconductor fabrication techniques, particularly the organometallic chemical vapor deposition of compound semiconductors like gallium arsenide. Work in this apparatus, a flow tube with mirrors for long path tunable infrared diode laser absorption and electrodes for a radio frequency glow discharge, culminated in observations designed to assess the importance of arsenic hydride radicals in the decomposition of organoarsenic compounds. Preliminary observations of fluorocarbon and methane plasmas produced observations of several species which could be compared with models and other observations and which added to knowledge of these systems with their important applications in silicon etching an diamond deposition. The program also resulted in band strength measurements for the methyl and difluorocarbene radicals, using tunable diode laser, dye laser, and fast flow reactor techniques.

Author: James R. P. Bain
Publisher:
ISBN:
Category :
Languages : en
Pages : 0

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Book Description
Tunable diode laser spectroscopy is a widely used technique for recovering quantitative gas information in a range of industrial applications. Established methods often use readily available, robust and low cost optoelectronic hardware in the near-infrared, with output wavelengths that coincide with the absorption spectra of several important gas species of interest, providing a versatile platform for gas analysis instrumentation. In this work the challenges associated with the recovery of gas information from harsh detection environments, particularly for aero engine diagnostics, are considered. For stand-alone instrumentation, calibration-free direct absorption measurements are highly advantageous yet calibrated techniques employing wavelength modulation spectroscopy are often favoured due to their significantly higher sensitivities. Recent developments have enabled calibration-free line shape recovery using lock-in amplifier detection of the residual amplitude modulation in wavelength modulated signals. These techniques have significant potential in harsh environments, but the overall sensitivity is limited by distortions to the recovered line shapes at high modulation amplitudes and by large background signals that saturate the detection electronics. In this thesis, solutions to these two problems are proposed, investigated and validated. A correction function is derived that is able to account for line shape distortions at arbitrarily high modulation indices. Application of the function depends upon knowledge of the experimental modulation index and two methods for extracting this information directly from the experimental signals are described. The full correction procedure has been experimentally validated. An investigation was made into the use of autobalanced photoreceivers, typically used for common mode noise cancellation, for direct absorption measurements and in a different configuration for nulling of the residual amplitude modulation (RAM) in wavelength modulation spectroscopy. Initial measurements suggest that removal of the background RAM can increase the lock-in detection sensitivity by over an order of magnitude. In addition an external amplitude modulator has been iv shown to be an effective method for producing sensitive absorption signals that are free of distortions, recoverable at frequencies that are outside the bandwidth of most environmental noise sources. A temperature sensor based on ratio thermometry of ambient water vapour absorption was designed and evaluated. The sensor is intended to provide accurate intake gas temperature information during aero engine ground testing when misting conditions prevent standard thermocouples from providing reliable data. Direct detection and second harmonic wavelength modulation spectroscopy experiments were undertaken in an environmental chamber, over the range 273-313K, to test the potential accuracy of the proposed system. Using a second harmonic peak height method, temperature information based on a calibration was able to recover temperature measurements with precision of ±0.4K however the overall accuracy suffered from a problematic calibration drift. Three engine test campaigns are described in which a range of recovery methods and potential optical system layouts are evaluated for the purposes of intake and exhaust mounted test bed sensor systems. The effects of extreme noise conditions were observed on a variety of measurements and favourable detection and modulation options were identified for the purpose of planning proposed future engine tests. Exhaust plume measurements of high temperature water vapour on the Rolls-Royce Environmentally Friendly Engine demonstrator established the viability of temperature and concentration measurements up to 850K.

Author: Aamir Farooq
Publisher:
ISBN:
Category :
Languages : en
Pages :

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Book Description
The development of diagnostics based on laser-absorption spectroscopy for combustion applications has been an important and active field of research over the past two decades due to the advantages of this non-intrusive optical sensing technique compared to traditional sampling-based sensing methods. Tunable diode laser (TDL) sensors, in particular, have shown the ability to provide in situ, time-resolved, line-of-sight measurements of temperature, gas species concentration, velocity, density, mass flux, and pressure in a variety of combustion environments. This thesis explores three new areas of TDL research: (a) extended near-infrared (NIR) diagnostics, (b) sensing under high-pressures, and (c) applications to chemical kinetics. Water vapor (H2O) and carbon dioxide (CO2) are attractive sensing targets for hydrocarbon-fueled systems as they are primary combustion products and their concentrations can be interpretrated to indicate combustion progress and efficiency. Both these gases have absorption spectra in the infrared (IR) region. Most previous TDL absorption sensors were designed to exploit robust telecommunications diode lasers and optical fiber technology in the 1.3-1.6 [mu]m (NIR) wavelength region. Recent developments in semiconductor diode-laser technology have extended the range of continuous wave (CW) room-temperature single-mode diode lasers to 2.9 [mu]m, allowing access to stronger vibrational bands of H2O and CO2 in the extended-NIR region. The first combustion diagnostics in the extended-NIR wavelength were demonstrated as part of this thesis work. The sensors were designed by selecting optimal transitions and then measuring the pertinent spectroscopic parameters in controlled laboratory environements. These sensors were then tested in the combustion environments of a flat flame and shock tube to validate their performance. These new sensors provide enhanced sensitivity and improved accuracy compared to previous TDL diagnostics. As part of this work, a novel diagnostic based on wavelength modulation spectroscopy (WMS) of CO2 was developed to make precise measurements of temperature behind reflected shock waves. This temperature diagnostic achieved an unprecedented uncertainty of

Author:
Publisher:
ISBN:
Category :
Languages : en
Pages :

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Book Description
Methods for generating tunable monochromatic infrared radiation are tabulated. Techniques used in tunable semiconductor diode laser spectroscopy are discussed. Spectra of SF6 and OsO4 are discussed, including references to photodissociation and laser isotope separation. 4 figures, 3 tables, 80 references. (DLC).