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Novel Methods of Organic Electrochemical Device Nanofabrication and Characterization

Novel Methods of Organic Electrochemical Device Nanofabrication and Characterization PDF Author: Mark Yaakov Tuchman
Publisher:
ISBN:
Category :
Languages : en
Pages :

Book Description
Recent advances in the development of organic mixed ionic/electronic conductors (OMIECs) have paved the way for novel applications that harness these materials' ability to effectively transduce ionic fluxes into electronic signals, such as in the fields of biosensors and neural interfaces. With the modulation taking place throughout the bulk of the material, such organic electrochemical devices offer a volumetric advantage over their inorganic counterparts, with high-transconductance operation feasible even at low operating voltages. This unique mode of operation may be exploited by a wide variety of applications, some yet unexplored. However, while some classes of organic semiconductors have seen tremendous success in market realization, such as the multi-billion-dollar OLED industry, integration of OMIEC semiconducting polymers systems into traditional fabrication processes remains a difficult technological challenge. In this work, I lay out novel strategies to allow for the nanofabrication of previously unattainable organic electrochemical devices, as well as the characterization thereof. The first part of this dissertation provides an introductory background to both organic electrochemical materials and devices, as well as nanofabrication, with a third chapter discussing the work done to bridge the gap between the two. In the second part, I turn to focus on specific applications of nanofabricated organic electrochemical devices, first exploring the properties of an organic electrochemical transistor (OECT) comprised of a lithographically patterned semiconducting polymer and a non-aqueous electrolyte. The remainder of the dissertation focuses on utilizing OMIEC materials for acceleration of artificial neural networks, discussing the characterization and fabrication strategies developed for realizing submicron-scale, MHz addressable, fully encapsulated organic ECRAM devices.

Novel Methods of Organic Electrochemical Device Nanofabrication and Characterization

Novel Methods of Organic Electrochemical Device Nanofabrication and Characterization PDF Author: Mark Yaakov Tuchman
Publisher:
ISBN:
Category :
Languages : en
Pages :

Book Description
Recent advances in the development of organic mixed ionic/electronic conductors (OMIECs) have paved the way for novel applications that harness these materials' ability to effectively transduce ionic fluxes into electronic signals, such as in the fields of biosensors and neural interfaces. With the modulation taking place throughout the bulk of the material, such organic electrochemical devices offer a volumetric advantage over their inorganic counterparts, with high-transconductance operation feasible even at low operating voltages. This unique mode of operation may be exploited by a wide variety of applications, some yet unexplored. However, while some classes of organic semiconductors have seen tremendous success in market realization, such as the multi-billion-dollar OLED industry, integration of OMIEC semiconducting polymers systems into traditional fabrication processes remains a difficult technological challenge. In this work, I lay out novel strategies to allow for the nanofabrication of previously unattainable organic electrochemical devices, as well as the characterization thereof. The first part of this dissertation provides an introductory background to both organic electrochemical materials and devices, as well as nanofabrication, with a third chapter discussing the work done to bridge the gap between the two. In the second part, I turn to focus on specific applications of nanofabricated organic electrochemical devices, first exploring the properties of an organic electrochemical transistor (OECT) comprised of a lithographically patterned semiconducting polymer and a non-aqueous electrolyte. The remainder of the dissertation focuses on utilizing OMIEC materials for acceleration of artificial neural networks, discussing the characterization and fabrication strategies developed for realizing submicron-scale, MHz addressable, fully encapsulated organic ECRAM devices.

Micro-Nano Electrochemical Systems and Fabrication Techniques Handbook

Micro-Nano Electrochemical Systems and Fabrication Techniques Handbook PDF Author: Eve Versuh
Publisher:
ISBN: 9781632383273
Category :
Languages : en
Pages : 0

Book Description
This book is a collection of researches by various experts who share their analysis of current trends and future implications of micro-nano electrochemical systems. MEMS technology is progressively influencing and improving our quality of life. Simultaneously, progress in nanotechnology and nanomaterials has accelerated the growth of NEMS. This book consists of an analysis of modern technologies and their forthcoming developments. It focuses on the recent progress in devices and production procedures in the field of these miniaturized electromechanical structures. This book presents information about design, production and packaging; as well as solutions in these aspects for targeted functions. This book aims to help experts and students who are engaged in this field.

Novel Nanomaterials

Novel Nanomaterials PDF Author: Karthikeyan Krishnamoorthy
Publisher: BoD – Books on Demand
ISBN: 1838810250
Category : Technology & Engineering
Languages : en
Pages : 370

Book Description
This book discusses novel nanomaterials and their various aspects. Chapters provide detailed information on new preparation routes for novel nanomaterials and their applications in supercapacitors, nanogenerators, removal of industrial pollutants, biosensors, self-cleaning coatings, aquatic robotics, and the construction industry.

Novel Fabrication and Characterization Methods for Conducting Polymer Nanostructures and Microstructures

Novel Fabrication and Characterization Methods for Conducting Polymer Nanostructures and Microstructures PDF Author: Cosmin Laslau
Publisher:
ISBN:
Category : Conducting polymers
Languages : en
Pages : 156

Book Description
"To develop devices based on conducting polymers for the benefit of humanity - such as, for example, artificial muscles and lab-on-a-chip diagnostics - we require the ability to reliably fabricate and understand these materials at the micro and nano scales. In this thesis I present research towards that goal, by developing novel experimental techniques for the fabrication and characterization of poly(3,4-ethylenedioxythiophene) (PEDOT) and polyaniline (PANI), two prominent conducting polymers. Many of the strategies presented herein are based on miniaturized pipettes driven by scanning ion conductance microscopy (SICM), with some complementary techniques also explored. I begin this thesis work by describing the construction of a low-cost SICM, and its further development to include novel modifications that enable its application to conducting polymers. One of these is the first SICM-based measurement of the ion flux that underpins PEDOT actuation, an important issue in artificial muscles and micropumps. Another is the first electrochemical fabrication of microscale PEDOT and PANI structures and arrays. This approach is then extended to map the activity of the resulting microstructures using modified SICM-based protocols. For example, it is demonstrated that pipette-defined cyclic voltammetry can yield highly localized characterization of microstructures, an important topic for biosensor applications. Indeed, this technique is demonstrated herein for the characterization of a PEDOT nanowire based DNA sensor. Finally, complementary studies on PANI nanostructures are also presented. The first synchrotron radiation studies of PANI nanotube self-assembly is undertaken, revealing crystallinity at critical early stages of the reaction. Furthermore, focused ion beam and electron microscopy techniques are used to perform studies on the electrical properties on individual PANI nanostructures. Both of these have relevance for potential integration with the aforementioned SICM-based techniques. Altogether, these methodological innovations and resulting findings represent significant advances in the burgeoning field of pipette-localized conducting polymer fabrication and characterization. I conclude the thesis with implications discussed for future fundamental research and device applications".

Organic and Inorganic Nanostructures

Organic and Inorganic Nanostructures PDF Author: Alexei Nabok
Publisher: Artech House Publishers
ISBN:
Category : Science
Languages : en
Pages : 294

Book Description
Providing you with a comprehensive and up-to-date understanding of organic and inorganic nanostructures, this cutting-edge resource covers all aspects of this fast-growing area of nanotechnology. The book explores the technology, structure, and electrical and optical properties of organic/inorganic nanostructures, as well as their application in microelectronic, optoelectronic, and nano-electronic devices. This unique reference offers you practical insight into the selection and optimization of thin films and nanostructures for specific applications, the development of novel nano-electronic and sensing devices, and the optical characterization of a wide range of composite materials and nanostructures.

Design, Synthesis, Characterization and Development of Novel Organic Conducting Polymers with Technological Applications

Design, Synthesis, Characterization and Development of Novel Organic Conducting Polymers with Technological Applications PDF Author: David Aradilla Zapata
Publisher:
ISBN:
Category :
Languages : en
Pages : 551

Book Description
In this thesis, a series of novel organic conducting polymers have been synthesized using alternative methods based on electrochemical techniques, which have allowed to broaden the knowledge in the field of the characterization by means of topological, spectroscopic, electrochemical and structural techniques. Among the variety of synthesis techniques of conducting polymers, layer-by-layer (LbL) has been one of the most important to build multilayered systems. Thus, in this thesis the LbL has shown to be an excellent procedure to explore new applications in the field of energy storage using conducting polymers. On the other hand, recently, the influence of new sustituents on functionalized conducting polymers has been proved to modify the structural, optical and physical properties of conducting polymers. Within this context, synthesis of novel functionalized conducting polymers bearing strong electron-withdrawing sustituents such as cyano group or halide atoms have been widely studied and characterized throughout this thesis. The presence of these substituents have emerged as promising candidates in the field of chemical sensors and electrochromic devices. Although the functionality of polymers or the development of new techniques are excellent procedures to synthesize and to develop new properties on the field of conducting polymers, it is worth mentioning that the substrate plays a crucial role on the electrochemical field. Accordingly, the substrates can also modify and change the properties of conducting polymers during the electropolymerization process. In this way, different substrates were employed in this work with the aim of achieving new applications in the field of corrosion inhibitors and as supercapacitors. Supercapacitors as energy storage device has been an outstanding application during this thesis. Thus, the field of nanotechnology has taken an important part in this thesis through development and design of promising hybrid nanocomposites based on conducting polymers and clay with technological applications and interesting optoelectronic properties. The contribution of theoretical techniques based on quantum mechanical calculations have allowed to predict some electronic and structural properties of conjugated polymers, which could be corroborated experimentally. The quantum mechanics is a useful tool to check experimental results and to understand mechanisms not fully understood at experimental level. Therefore, theoretical calculations have provided promising information to obtain new insights in the field of conducting polymers.

New Nanotechnology Research

New Nanotechnology Research PDF Author: John P. Reece
Publisher: Nova Publishers
ISBN: 9781600212130
Category : Technology & Engineering
Languages : en
Pages : 260

Book Description
Nanotechnology is a 'catch-all' description of activities at the level of atoms and molecules that have applications in the real world. A manometer is a billionth of a meter, about 1/80,000 of the diameter of a human hair, or 10 times the diameter of a hydrogen atom. Nanotechnology is now used in precision engineering, new materials development as well as in electronics; electromechanical systems as well as mainstream biomedical applications in areas such as gene therapy, drug delivery and novel drug discovery techniques. This book presents the latest research in this frontier field.

The New Frontiers of Organic and Composite Nanotechnology

The New Frontiers of Organic and Composite Nanotechnology PDF Author: Victor Erokhin
Publisher: Elsevier
ISBN: 0080554075
Category : Technology & Engineering
Languages : en
Pages : 505

Book Description
The New Frontiers of Organic and Composite Nanotechnology is an attempt to illustrate current status of modern nanotechnology. The book is divided into 3 main sections, introduction and conclusion. The introduction describes general questions of the problem and main lines of the research activities. In the first section methods of the nanostructures construction are described. Second section is dedicated to the Structure-property relationship. Special attention is paid to the description of the most powerful experimental methods and tools used in nanotechnology, such as probe microscopies, spectroscopied, and scattering methods, including the utilization of synchrotron radiation facilities. The third section describes the applications of nanotechnology in electronics, biotechnology and diagnostics. Conclusion part presents a summary of the status of works in this area and gives some perspectives of the further development. Reference to practically all original works with essential results, that resulted in the development of nanotechnology Coherent group of well-known authors in the field of nanotechnology Book spans topics applicable for both the didactic and research

In-situ Characterization Techniques for Nanomaterials

In-situ Characterization Techniques for Nanomaterials PDF Author: Challa S.S.R. Kumar
Publisher: Springer
ISBN: 3662563223
Category : Technology & Engineering
Languages : en
Pages : 458

Book Description
Seventh volume of a 40 volume series on nanoscience and nanotechnology, edited by the renowned scientist Challa S.S.R. Kumar. This handbook gives a comprehensive overview about In-situ Characterization Techniques for Nanomaterials. Modern applications and state-of-the-art techniques are covered and make this volume an essential reading for research scientists in academia and industry.

Scientific and Technical Aerospace Reports

Scientific and Technical Aerospace Reports PDF Author:
Publisher:
ISBN:
Category : Aeronautics
Languages : en
Pages : 892

Book Description