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Nonlinear Phenomena in Flows of Viscoelastic Polymer Fluids

Nonlinear Phenomena in Flows of Viscoelastic Polymer Fluids PDF Author: A.I. Leonov
Publisher: Springer Science & Business Media
ISBN: 9401112584
Category : Technology & Engineering
Languages : en
Pages : 492

Book Description
This monograph presents theoretical and experimental studies of flows of elastic liquids. Falling into this category are particularly the melts and concentrated solutions of such flexible-chain polymers as polyethylene, polyisobutylene and polypropylene, all of which are widely used in polymer processing. These polydisperse polymers vary greatly, from batch to batch, in their mechanical properties and 20% variation in a property is believed to be good enough. l 7 All recent books - devoted to the rheology of polymers do not answer the question of which constitutive equations should be used for solving the fluid mechanic problems of polymer processing in the usual case of an appreciable nonlinear region of deformation where nonlinear effects of shear and extensional elasticity are very important. Viscoelastic constitut ive equations cited commonly (see, e.g. Refs 5 and 6) do not describe simultaneously even the simplest cases of deformations, viz. simple shear and uniaxial extension. Moreover, some of them are internally inconsist ent and sometimes display highly unstable behaviour in simple flows without any fundamental reasons. Even more respected molecular ap free from these defects.

Nonlinear Phenomena in Flows of Viscoelastic Polymer Fluids

Nonlinear Phenomena in Flows of Viscoelastic Polymer Fluids PDF Author: A.I. Leonov
Publisher: Springer Science & Business Media
ISBN: 9401112584
Category : Technology & Engineering
Languages : en
Pages : 492

Book Description
This monograph presents theoretical and experimental studies of flows of elastic liquids. Falling into this category are particularly the melts and concentrated solutions of such flexible-chain polymers as polyethylene, polyisobutylene and polypropylene, all of which are widely used in polymer processing. These polydisperse polymers vary greatly, from batch to batch, in their mechanical properties and 20% variation in a property is believed to be good enough. l 7 All recent books - devoted to the rheology of polymers do not answer the question of which constitutive equations should be used for solving the fluid mechanic problems of polymer processing in the usual case of an appreciable nonlinear region of deformation where nonlinear effects of shear and extensional elasticity are very important. Viscoelastic constitut ive equations cited commonly (see, e.g. Refs 5 and 6) do not describe simultaneously even the simplest cases of deformations, viz. simple shear and uniaxial extension. Moreover, some of them are internally inconsist ent and sometimes display highly unstable behaviour in simple flows without any fundamental reasons. Even more respected molecular ap free from these defects.

Nonlinear Phenomena in Flows of Viscoelastic Polymer Fluids

Nonlinear Phenomena in Flows of Viscoelastic Polymer Fluids PDF Author: A I Leonov
Publisher:
ISBN: 9789401112598
Category :
Languages : en
Pages : 496

Book Description


Nonlinear Phenomena in Flows of Viscoelastic Polymer Fluids

Nonlinear Phenomena in Flows of Viscoelastic Polymer Fluids PDF Author: A.I. Leonov
Publisher: Springer
ISBN: 9780412582004
Category : Technology & Engineering
Languages : en
Pages : 475

Book Description
This monograph presents theoretical and experimental studies of flows of elastic liquids. Falling into this category are particularly the melts and concentrated solutions of such flexible-chain polymers as polyethylene, polyisobutylene and polypropylene, all of which are widely used in polymer processing. These polydisperse polymers vary greatly, from batch to batch, in their mechanical properties and 20% variation in a property is believed to be good enough. l 7 All recent books - devoted to the rheology of polymers do not answer the question of which constitutive equations should be used for solving the fluid mechanic problems of polymer processing in the usual case of an appreciable nonlinear region of deformation where nonlinear effects of shear and extensional elasticity are very important. Viscoelastic constitut ive equations cited commonly (see, e.g. Refs 5 and 6) do not describe simultaneously even the simplest cases of deformations, viz. simple shear and uniaxial extension. Moreover, some of them are internally inconsist ent and sometimes display highly unstable behaviour in simple flows without any fundamental reasons. Even more respected molecular ap free from these defects.

Polymer Processing Instabilities

Polymer Processing Instabilities PDF Author: Savvas G. Hatzikiriakos
Publisher: CRC Press
ISBN: 142003068X
Category : Science
Languages : en
Pages : 484

Book Description
Polymer Processing Instabilities: Control and Understanding offers a practical understanding of the various flows that occur during the processing of polymer melts. The book pays particular attention to flow instabilities that affect the rate of production and the methods used to prevent and eliminate flow instabilities in order to increase product

Modeling and Simulation in Polymers

Modeling and Simulation in Polymers PDF Author: Purushottam D. Gujrati
Publisher: John Wiley & Sons
ISBN: 9783527630264
Category : Technology & Engineering
Languages : en
Pages : 564

Book Description
Filling a gap in the literature and all set to become the standard in this field, this monograph begins with a look at computational viscoelastic fluid mechanics and studies of turbulent flows of dilute polymer solutions. It then goes on discuss simulations of nanocomposites, polymerization kinetics, computational approaches for polymers and modeling polyelectrolytes. Further sections deal with tire optimization, irreversible phenomena in polymers, the hydrodynamics of artificial and bacterial flagella as well as modeling and simulation in liquid crystals. The result is invaluable reading for polymer and theoretical chemists, chemists in industry, materials scientists and plastics technologists.

Lubricant Additives

Lubricant Additives PDF Author: Leslie R. Rudnick
Publisher: CRC Press
ISBN: 1351646966
Category : Science
Languages : en
Pages : 1652

Book Description
This indispensable book describes lubricant additives, their synthesis, chemistry, and mode of action. All important areas of application are covered, detailing which lubricants are needed for a particular application. Laboratory and field performance data for each application is provided and the design of cost-effective, environmentally friendly technologies is fully explored. This edition includes new chapters on chlorohydrocarbons, foaming chemistry and physics, antifoams for nonaqueous lubricants, hydrogenated styrene–diene viscosity modifiers, alkylated aromatics, and the impact of REACh and GHS on the lubricant industry.

Polymer Melt Fracture

Polymer Melt Fracture PDF Author: Rudy Koopmans
Publisher: CRC Press
ISBN: 1420018280
Category : Science
Languages : en
Pages : 344

Book Description
The continually growing plastics market consists of more than 250 million tons of product annually, making the recurring problem of polymer melt fracture an acute issue in the extrusion of these materials. Presenting a pictorial library of the different forms of melt fracture and real industrial extrusion melt fracture phenomena, Polymer Melt Fract

Mathematical Analysis of Viscoelastic Flows

Mathematical Analysis of Viscoelastic Flows PDF Author: Michael Renardy
Publisher: SIAM
ISBN: 0898714575
Category : Mathematics
Languages : en
Pages : 110

Book Description
This monograph is based on a series of lectures presented at the 1999 NSF-CBMS Regional Research Conference on Mathematical Analysis of Viscoelastic Flows. It begins with an introduction to phenomena observed in viscoelastic flows, the formulation of mathematical equations to model such flows, and the behavior of various models in simple flows. It also discusses the asymptotics of the high Weissenberg limit, the analysis of flow instabilities, the equations of viscoelastic flows, jets and filaments and their breakup, as well as several other topics.

Viscoelastic Properties of Polymers

Viscoelastic Properties of Polymers PDF Author: John D. Ferry
Publisher: John Wiley & Sons
ISBN: 9780471048947
Category : Technology & Engineering
Languages : en
Pages : 676

Book Description
Viscoelastic behavior reflects the combined viscous and elastic responses, under mechanical stress, of materials which are intermediate between liquids and solids in character. Polymers the basic materials of the rubber and plastic industries and important to the textile, petroleum, automobile, paper, and pharmaceutical industries as well exhibit viscoelasticity to a pronounced degree. Their viscoelastic properties determine the mechanical performance of the final products of these industries, and also the success of processing methods at intermediate stages of production. Viscoelastic Properties of Polymers examines, in detail, the effects of the many variables on which the basic viscoelastic properties depend. These include temperature, pressure, and time; polymer chemical composition, molecular weight and weight distribution, branching and crystallinity; dilution with solvents or plasticizers; and mixture with other materials to form composite systems. With guidance by molecular theory, the dependence of viscoelastic properties on these variables can be simplified by introducing certain ancillary concepts such as the fractional free volume, the monomeric friction coefficient, and the spacing between entanglement loci, to provide a qualitative understanding and in many cases a quantitative prediction of how to achieve desired results. The phenomenological theory of viscoelasticity which permits interrelation of the results of different types of experiments is presented first, with many useful approximation procedures for calculations given. A wide variety of experimental methods is then described, with critical evaluation of their applicability to polymeric materials of different consistencies and in different regions of the time scale (or, for oscillating deformations, the frequency scale). A review of the present state of molecular theory follows, so that viscoelasticity can be related to the motions of flexible polymer molecules and their entanglements and network junctions. The dependence of viscoestic properties on temperature and pressure, and its descriptions using reduced variables, are discussed in detail. Several chapters are then devoted to the dependence of viscoelastic properties on chemical composition, molecular weight, presence of diluents, and other features, for several characteristic classes of polymer materials. Finally, a few examples are given to illustrate the many potential applications of these principles to practical problems in the processing and use of rubbers, plastics, and fibers, and in the control of vibration and noise. The third edition has been brought up to date to reflect the important developments, in a decade of exceptionally active research, which have led to a wider use of polymers, and a wider recognition of the importance and range of application of viscoelastic properties. Additional data have been incorporated, and the book s chapters on dilute solutions, theory of undiluted polymers, plateau and terminal zones, cross-linked polymers, and concentrated solutions have been extensively rewritten to take into account new theories and new experimental results. Technical managers and research workers in the wide range of industries in which polymers play an important role will find that the book provides basic information for practical applications, and graduate students in chemistry and engineering will find, in its illustrations with real data and real numbers, an accessible introduction to the principles of viscoelasticity.

Transfer Phenomena in Fluid and Heat Flows VIII

Transfer Phenomena in Fluid and Heat Flows VIII PDF Author: Stanislav Kolisnychenko
Publisher: Trans Tech Publications Ltd
ISBN: 3035730539
Category : Technology & Engineering
Languages : en
Pages : 264

Book Description
This volume of the journal “Defect and Diffusion Forum” presents to readers the next 8th special issue from the series “Transfer Phenomena in Fluid and Heat Flows” which contains articles covering theoretical and practical aspects of modeling and numerical investigation of the diffusive convection and magnetohydromagnetic mixed convective flows, heat transfer phenomena in different media and engineering objects, solving other engineering problems related to heat and mass transfer phenomena.