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Author: Publisher: ISBN: Category : Languages : en Pages : 21
Book Description
The objective is to overcome the restrictions of non-oxidative methane pyrolysis and oxidative coupling of methane by transferring hydrogen across a selective inorganic membrane between methane and air streams, without simultaneous transport of hydrocarbon reactants or products. This will make the overall reaction system exothermic, remove the thermodynamic barrier to high conversion, and eliminate the formation of carbon oxides. Our approach is to couple C-H bond activation and hydrogen removal by passage of hydrogen atoms through a dense ceramic membrane. In our membrane reactor, catalytic methane pyrolysis produces C2+ hydrogen carbons and aromatics on the one side of the membrane and hydrogen is removed through an oxide film and combusted with air on the opposite side. This process leads to a net reaction with the stoichiometry and thermodynamic properties of oxidative coupling, but without contact between the carbon atoms and oxygen species.
Author: Publisher: ISBN: Category : Languages : en Pages : 21
Book Description
The objective is to overcome the restrictions of non-oxidative methane pyrolysis and oxidative coupling of methane by transferring hydrogen across a selective inorganic membrane between methane and air streams, without simultaneous transport of hydrocarbon reactants or products. This will make the overall reaction system exothermic, remove the thermodynamic barrier to high conversion, and eliminate the formation of carbon oxides. Our approach is to couple C-H bond activation and hydrogen removal by passage of hydrogen atoms through a dense ceramic membrane. In our membrane reactor, catalytic methane pyrolysis produces C2+ hydrogen carbons and aromatics on the one side of the membrane and hydrogen is removed through an oxide film and combusted with air on the opposite side. This process leads to a net reaction with the stoichiometry and thermodynamic properties of oxidative coupling, but without contact between the carbon atoms and oxygen species.
Author: Wolf Publisher: Springer Science & Business Media ISBN: 9401574499 Category : Technology & Engineering Languages : en Pages : 556
Book Description
A reasonable case could be made that the scientific interest in catalytic oxidation was the basis for the recognition of the phenomenon of catalysis. Davy, in his attempt in 1817 to understand the science associated with the safety lamp he had invented a few years earlier, undertook a series of studies that led him to make the observation that a jet of gas, primarily methane, would cause a platinum wire to continue to glow even though the flame was extinguished and there was no visible flame. Dobereiner reported in 1823 the results of a similar investigation and observed that spongy platina would cause the ignition of a stream of hydrogen in air. Based on this observation Dobereiner invented the first lighter. His lighter employed hydrogen (generated from zinc and sulfuric acid) which passed over finely divided platinum and which ignited the gas. Thousands of these lighters were used over a number of years. Dobereiner refused to file a patent for his lighter, commenting that "I love science more than money." Davy thought the action of platinum was the result of heat while Dobereiner believed the ~ffect ~as a manifestation of electricity. Faraday became interested in the subject and published a paper on it in 1834; he concluded that the cause for this reaction was similar to other reactions.
Author: Eduardo E. Wolf Publisher: Springer ISBN: Category : Science Languages : en Pages : 566
Book Description
A reasonable case could be made that the scientific interest in catalytic oxidation was the basis for the recognition of the phenomenon of catalysis. Davy, in his attempt in 1817 to understand the science associated with the safety lamp he had invented a few years earlier, undertook a series of studies that led him to make the observation that a jet of gas, primarily methane, would cause a platinum wire to continue to glow even though the flame was extinguished and there was no visible flame. Dobereiner reported in 1823 the results of a similar investigation and observed that spongy platina would cause the ignition of a stream of hydrogen in air. Based on this observation Dobereiner invented the first lighter. His lighter employed hydrogen (generated from zinc and sulfuric acid) which passed over finely divided platinum and which ignited the gas. Thousands of these lighters were used over a number of years. Dobereiner refused to file a patent for his lighter, commenting that "I love science more than money." Davy thought the action of platinum was the result of heat while Dobereiner believed the ~ffect ~as a manifestation of electricity. Faraday became interested in the subject and published a paper on it in 1834; he concluded that the cause for this reaction was similar to other reactions.
Author: A. Parmaliana Publisher: Elsevier ISBN: 0080537308 Category : Technology & Engineering Languages : en Pages : 1005
Book Description
On January 1988, the ascertained and economically accessible reserves of Natural Gas (NG) amounted to over 144,000 billion cubic meters worldwide, corresponding to 124 billion tons of oil equivalents (comparable with the liquid oil reserves, which are estimated to be 138 billion TOE). It is hypothesized that the volume of NG reserve will continue to grow at the same rate of the last decade. Forecasts on production indicate a potential increase from about 2,000 billion cubic meters in 1990 to not more than 3,300 billion cubic meters in 2010, even in a high economic development scenario. NG consumption represents only one half of oil: 1.9 billion TOE/y as compared to 3.5 of oil. Consequently, in the future gas will exceed oil as a carbon atom source. In the future the potential for getting energetic vectors or petrochemicals from NG will continue to grow. The topics covered in Natural Gas Conversion V reflect the large global R&D effort to look for new and economic ways of NG exploitation. These range from the direct conversion of methane and light paraffins to the indirect conversion through synthesis gas to fuels and chemicals. Particularly underlined and visible are the technologies already commercially viable. These proceedings prove that mature and technologically feasible processes for natural gas conversion are already available and that new and improved catalytic approaches are currently developing, the validity and feasibility of which will soon be documented. This is an exciting area of modern catalysis, which will certainly open novel and rewarding perspectives for the chemical, energy and petrochemical industries.
Author: A. Holmen Publisher: Elsevier ISBN: 0080879179 Category : Science Languages : en Pages : 585
Book Description
These proceedings reflect the extensive fundamental and applied research efforts that are currently being made on the conversion of gas, in particular on the direct conversion of methane. The Symposium in Oslo focused on the following topics: Direct conversion of methane, Fischer-Tropsch chemistry, methanol conversion and natural gas conversion processes. The main aim was to present the state-of-the-art and progress currently being made within each of these areas. The book contains the papers presented and includes plenary lectures, short communications and posters. The papers will be of interest to scientists and engineers working in the field of gas conversion, transportation fuels, primary petrochemicals and catalysis.
Author: D.M. Bibby Publisher: Elsevier ISBN: 0080960707 Category : Technology & Engineering Languages : en Pages : 759
Book Description
This proceedings volume comprises the invited plenary lectures, contributed and poster papers presented at a symposium organised to mark the successful inauguration of the world's first commercial plant for production of gasoline from natural gas, based on the Mobil methanol-to-gasoline process. The objectives of the Symposium were to present both fundamental research and engineering aspects of the development and commercialization of gas-to-gasoline processes. These include steam reforming, methanol synthesis and methanol-to-gasoline. Possible alternative processes e.g. MOGD, Fischer-Tropsch synthesis of hydrocarbons, and the direct conversion of methane to higher hydrocarbons were also considered.The papers in this volume provide a valuable and extremely wide-ranging overview of current research into the various options for natural gas conversion, giving a detailed description of the gas-to-gasoline process and plant. Together, they represent a unique combination of fundamental surface chemistry catalyst characterization, reaction chemistry and engineering scale-up and commercialization.
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Author: Wolf
Author: Michael O'Neal Nutt
Author: Borry Richard Wilson
Author: Eduardo E. Wolf
Author: Vladimir Galvita
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Author: A. Parmaliana
Author: A. Holmen
Author: D.M. Bibby