Author: Mark E. NoblePublisher:
ISBN:
Category : Molybdenum compounds
Languages : en
Pages : 360
Book Description
Nitrido- and Imido-complexes of Molybdenum(V)
Author: Mark E. NoblePublisher:
ISBN:
Category : Molybdenum compounds
Languages : en
Pages : 360
Book Description
Imido Complexes of Molybdenum and Osmium
Author: Jennifer Robbins WolfPublisher:
ISBN:
Category :
Languages : en
Pages : 214
Book Description
Metal-Ligand Multiple Bonds
Author: William A. NugentPublisher: Wiley-Interscience
ISBN:
Category : Science
Languages : en
Pages : 360
Book Description
The only comprehensive one-volume text/reference on metal-ligand multiple bonds. Stresses the unified nature of the field and includes handy new tabulations of data. The flow within each subtopic is oxygen to nitrogen to carbon. Coverage is up-to-date--virtually every subtopic leads to interesting questions for future research. Presents information otherwise scattered through hundreds of publications.
Synthesis, Characterization and Reactivity of Molybdenum and Tungsten Imido Complexes of Relevance to Alkene Dimerization
Author: Further Studies of the Synthesis and Reactivity of Molybdenum-imido Compounds
Author: Joseph Eric PelatiPublisher:
ISBN:
Category : Imidoesters
Languages : en
Pages : 312
Book Description
Structural and Reactivity Studies of Bis(imido) Complexes of Molybdenum
Author: Therese Anne CoffeyAlkyne and Imido Molybdenum Complexes and Their Relationship to Nitrogenase
Author: Eric Arn MaataPublisher:
ISBN:
Category : Molybdenum
Languages : en
Pages : 416
Book Description
Activating Unreactive Substrates
Author: Carsten BolmPublisher: John Wiley & Sons
ISBN: 352762547X
Category : Science
Languages : en
Pages : 481
Book Description
The use of secondary interactions for the activation of non-reactive substrates constitutes a new and modern approach in catalysis. This first comprehensive treatment of this important research field covers the entire field and reveals the links between the various chemical disciplines. It thus adopts an interdisciplinary approach, making it of interest to the whole chemical community. A must for organic, inorganic, catalytic and complex chemists, as well as those working with/on organometallics.
Ligand Variation in Molybdenum Imido Alkylidene Complexes
Author: Alejandro Gaston LichtscheidlPublisher:
ISBN:
Category :
Languages : en
Pages : 222
Book Description
Chapter 1. A general introduction is given. Chapter 2. The biscarboxylate species, Mo(NR)(CHCMe 2Ph)(O 2CPh3)2 (R = 2,6-i-Pr2C6H3, 2,6- Me2C6H3, 2-t-BuC 6H4, or 1 -adamantyl) are compared to newly synthesized bis(terphenylcarboxylate) species, Mo(NR)(CHCMe 2Ph)(O 2CTer)2 (Ter = 2,6-diphenyl-4- methylphenyl or 2,6-diphenyl-4-methoxyphenyl). Preparation of bis(terphenylcarboxylate) species was accomplished through protonolysis of Mo(NR)(CHCMe2R')(Me2Pyr)2 with two equivalents of TerCO2H and one of them was characterized through X-ray crystallography. Photolysis experiments of many of the biscarboxylate complexes led to rate constants for the converstion of anti to syn species, which are much slower than bisalkoxide species. Trimethylphosphine adducts of selected triphenylacetate complexes have been isolated and studied in solution. Protonolysis of Mo(NAr)(CHCMe 2R')(Me 2Pyr)2 (Ar = 2,6-i-Pr 2C6H3) with one equivalent of TerCO2H led to the isolation of a handful of monocarboxylate species, Mo(NAr)(CHCMe 2Ph)(O 2CAr')(Me2Pyr). An X-ray structure of one of them was also characterized. Several of the bis(triphenylacetate) complexes and all of the monocarboxylates are active initiators for the regioselective polymerization of diethyl dipropargylmalonate (DEPDM). In the case of the latter compounds, activity towards olefins is also observed and briefly mentioned.
Advances in Inorganic Chemistry
Author: Rudi van EldikPublisher: Academic Press
ISBN: 0080963080
Category : Science
Languages : en
Pages : 668
Book Description
The Advances in Inorganic Chemistry series present timely and informative summaries of the current progress in a variety of subject areas within inorganic chemistry, ranging from bio-inorganic to solid state studies. This acclaimed serial features reviews written by experts in the field and serves as an indispensable reference to advanced researchers. Each volume contains an index, and each chapter is fully referenced. - Features comprehensive reviews on the latest developments - Includes contributions from leading experts in the field - Serves as an indispensable reference to advanced researchers