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Author: Kenji Yamamoto Publisher: ISBN: Category : Science Languages : en Pages : 288
Book Description
This new and important book presents recent advances in organometallic chemistry which is based on the reactions and use of a class of compounds (R-M) that contain a covalent bond between carbon and metal. They are prepared either by direct reaction of the metal with an organic compound or by replacement of a metal from another organometallic substance. Research in organometallic chemistry is also conducted in the areas of cluster synthesis, main-group derivatives in unusual oxidation states, organometallic polymers, unstable organometallic compounds and intermediates in matrices, structure determination of organometallic compounds in the solid state [X-ray diffraction] and gaseous states [electron diffraction], and mechanisms of reactions of transient silylenes and related species. In addition to the traditional metals and semimetals, elements such as selenium, lithium and magnesium are considered to form organometallic compounds, e.g. organomagnesium compounds MeMgI, iodo(methyl)magnesium and diethylmagnesium which are Grignard reagents an organo-lithium compound BuLi butyllithium; Organometallic compounds often find practical use as catalysts, the processing of petroleum products and the production of organic polymers.
Author: Kenji Yamamoto Publisher: ISBN: Category : Science Languages : en Pages : 288
Book Description
This new and important book presents recent advances in organometallic chemistry which is based on the reactions and use of a class of compounds (R-M) that contain a covalent bond between carbon and metal. They are prepared either by direct reaction of the metal with an organic compound or by replacement of a metal from another organometallic substance. Research in organometallic chemistry is also conducted in the areas of cluster synthesis, main-group derivatives in unusual oxidation states, organometallic polymers, unstable organometallic compounds and intermediates in matrices, structure determination of organometallic compounds in the solid state [X-ray diffraction] and gaseous states [electron diffraction], and mechanisms of reactions of transient silylenes and related species. In addition to the traditional metals and semimetals, elements such as selenium, lithium and magnesium are considered to form organometallic compounds, e.g. organomagnesium compounds MeMgI, iodo(methyl)magnesium and diethylmagnesium which are Grignard reagents an organo-lithium compound BuLi butyllithium; Organometallic compounds often find practical use as catalysts, the processing of petroleum products and the production of organic polymers.
Author: Marin A. Cato Publisher: Nova Publishers ISBN: 9781594548444 Category : Science Languages : en Pages : 242
Book Description
Organometallic chemistry is based on the reactions and use of a class of compounds (R-M) that contain a covalent bond between carbon and metal. They are prepared either by direct reaction of the metal with an organic compound or by replacement of a metal from another organometallic substance. Research in organometallic chemistry is also conducted in the areas of cluster synthesis, main-group derivatives in unusual oxidation states, organometallic polymers, unstable organometallic compounds and intermediates in matrices, structure determination of organometallic compounds in the solid state [X-ray diffraction] and gaseous states [electron diffraction], and mechanisms of reactions of transient silylenes and related species. In addition to the traditional metals and semimetals, elements such as selenium, lithium and magnesium are considered to form organometallic compounds, e.g. organomagnesium compounds MeMgI, iodo(methyl)magnesium and diethylmagnesium, which are Grignard reagents an organo-lithium compound BuLi butyllithium; Organometallic compounds often find practical use as catalysts, the processing of petroleum products and the production of organic polymers.
Author: Armando J. L. Pombeiro Publisher: John Wiley & Sons ISBN: 1118742893 Category : Science Languages : en Pages : 848
Book Description
A contemporary compilation of recent achievements in organometallic chemistry The prestigious International Conference on Organometallic Chemistry (ICOMC) was launched in 1963, providing a forum for researchers from around the world to share their findings and explore new paths to advance our knowledge and application of organometallic chemistry. The 25th ICOMC, held in Lisbon in 2012, gathered more than 1,200 participants from 54 countries. This volume celebrates the 25th Silver Edition and the 50th Gold Year of the ICOMC. Featuring contributions from invited 25th ICOMC speakers, Advances in Organometallic Chemistry and Catalysis highlights recent achievements and new and emerging areas of research in the field. Its seven sections cover: Activation and Functionalization of Carbon Single Bonds and Small Molecules Organometallic Synthesis and Catalysis Organometallic Polymerization Catalysis Organometallic Polymers and Materials Organometallic Chemistry and Sustainable Energy Bioorganometallic Chemistry Organometallic Electrochemistry Chapters discuss fundamental underlying concepts, offer illustrative examples and cases, and explore future avenues for continued research. Readers will discover basic principles and properties of organometallic compounds, reaction mechanisms, and detailed descriptions of current applications. Collectively, these chapters underscore the versatility, richness, and potential of modern organometallic chemistry, including its interrelationships with other scientific disciplines. All the contributions are extensively referenced, providing a gateway to the most important original research papers and reviews in organometallic chemistry. Presenting a contemporary understanding of organometallic chemistry and its many applications, Advances in Organometallic Chemistry and Catalysis is recommended for all researchers in the field, from students to advanced investigators.
Author: Thomas J. Colacot Publisher: John Wiley & Sons ISBN: 3527345175 Category : Science Languages : en Pages : 336
Book Description
Showcases the important role of organometallic chemistry in industrial applications and includes practical examples and case studies This comprehensive book takes a practical approach to how organometallic chemistry is being used in industrial applications. It uniquely offers numerous, real-world examples and case studies that aid working R&D researchers as well as Ph.D. and postdoc students preparing to ace interviews in order to enter the workforce. Edited by two world-leading and established industrial chemists, the book covers flow chemistry (catalytic and non-catalytic organometallic chemistry), various cross-coupling reactions (C-C, C-N, and C-B) in classical batch chemistry, conjugate addition reactions, metathesis, and C-H arylation and achiral hydrogenation reactions. Beginning with an overview of the many industrial milestones within the field over the years, Organometallic Chemistry in Industry: A Practical Approach provides chapters covering: the design, development, and execution of a continuous flow enabled API manufacturing route; continuous manufacturing as an enabling technology for low temperature organometallic chemistry; the development of a nickel-catalyzed enantioselective Mizoroki-Heck coupling; and the development of iron-catalyzed Kumada cross-coupling for the large scale production of Aliskiren intermediates. The book also examines aspects of homogeneous hydrogenation from industrial research; the latest industrial uses of olefin metathesis; and more. -Includes rare industrial case studies difficult to find in current literature -Helps readers successfully carry out their own reactions -Covers topics like flow chemistry, cross-coupling reactions, and dehydrative decarbonylation -Features a foreword by Nobel Laureate R. H. Grubbs -A perfect resource for every R&D researcher in industry -Useful for PhD students and postdocs: excellent preparation for a job interview Organometallic Chemistry in Industry: A Practical Approach is an excellent resource for all chemists, including those working in the pharmaceutical industry and organometallics.
Author: Karl Kirchner Publisher: Springer Science & Business Media ISBN: 9783211835999 Category : Science Languages : en Pages : 184
Book Description
From the beginning of chemistry as an exact (natural) science - almost 200 years ago - there was a more or less distinct differentiation between its various branches such as organic, inorganic, physical, analytical, or biochemistry. With the increasing insight into the connections and governing laws it soon became obvious, however, that such a clear separation could be regarded as more or less obsolete; within almost any field of chemical research one has to deal with most of the branches mentioned. Especially organic and inorganic chemistry are significant examples for this statement, overlapping considerably within the important field of organome tallic chemistry. This regime of chemistry started its advance with the discovery of dimethylzinc 150 years ago, had a highlight with the introduction of Grignard reagents around 1900, developed further with the start of lithium organyls in 1925 and literally exploded after the discovery of the first transition metal cyclopenta dienyl complex ferrocene half a century ago. The chronological sequence of the important steps, i. e. 1850 (Zn) - 1900 (Mg) - 1925 (Li) - 1950 (Fe), seems rather remarkable. The increasing group of metallocenes is not only of high theoretical and, due to the potential chirality of its members, stereochemical interest, but offers also a wide variety of extremely useful catalysts, especially for stereoselective reactions. The Austrian Chemical Society took this development into account by organizing the Twelfth International Conference on Organometallic Chemistry held in Vienna in 1985.
Author: Akshai Kumar Publisher: Elsevier ISBN: 0128220929 Category : Science Languages : en Pages : 245
Book Description
Pincer-Metal Complexes: Applications in Catalytic Dehydrogenation Chemistry provides an overview of pincer-metal catalytic systems that transform hydrocarbons and their derivatives from an synthetic and mechanistic point-of-view. This book provides thorough coverage of the operating mechanisms and dehydrogenation catalyst compatibility in both functionalized and unfunctionalized hydrocarbon systems. In addition, it includes success stories of pincer-metal systems, as well as current and future challenges. The book is an ideal reference for researchers practicing synthetic organic chemistry, inorganic chemistry, organometallic chemistry and catalysis in academia and industry. In recent years there has been a surge in the research on hydrocarbon dehydrogenation catalytic systems that are compatible with polar substituents. This helps facilitate formulation of tandem processes that are not limited to hydrocarbon transformation but also to hydrocarbon functionalization in a single pot. - Covers applications of pincer-metal complexes in organic transformations - Includes pincer-group 8 and 9 metal complexes for alkane dehydrogenations - Features a discussion of pincer-metal complexes for the dehydrogenation of functionalized hydrocarbons and electro-catalytic transformations
Author: Marcel Gielen Publisher: John Wiley & Sons ISBN: Category : Science Languages : en Pages : 408
Book Description
This new series offers leading contributions by well known chemists reviewing the state-of-the-art of this wide research area. Physical Organometallic Chemistry aims to develop new insights and to promote novel interest and investigations applicable to organometallic chemistry. NMR spectroscopy has had a considerable impact on many fields of chemistry, although it has served organometallic chemistry mainly on a routine level. In a collection of reviews, leading chemists provide an insight into the scope of applications and uncover the potential of this technique for organometallic chemists. Advanced Applications of NMR to Organometallic Chemistry; Illustrates how recent 1D and 2D and specialized multinuclear applications can solve specific problems encountered by organometallic chemists Surveys modern NMR techniques in organometallic chemistry Includes metal NMR related techniques Focuses on the advent of solid state NMR in organometallic chemistry This book will prove invaluable to the NMR spectroscopist and organometallic chemists and will also be of interest to all organic, inorganic and physical chemists Contents: Selective Excitation and Selective Detection in 29Si NMR; Two-dimensional 13C, Metal Nuclei Correlation; Two-dimensional 1H-119Sn Proton Detected Correlation Spectroscopy in Coordination Chemistry of Hypervalent Organotin Compounds; Indirect Nuclear 119Sn-X Spin-Spin Coupling; Solid State NMR Applications in Organotin and Organolead Chemistry; Solid State NMR Investigations of Metal Carbonyl Complexes; High Pressure NMR in Organometallic Chemistry; Multinuclear NMR Spectroscopy in Supercritical Fluids; High Resolution 6,7Li NMR of Organolithium Compounds; Metal NMR of Organovanadium, -Niobium and -Tantalum Compounds; NMR of Metallic Nuclei in Clusters; 171Yb NMR Spectroscopy.
Author: Nathan J Patmore Publisher: Royal Society of Chemistry ISBN: 1788010671 Category : Science Languages : en Pages : 210
Book Description
With the increase in volume, velocity and variety of information, researchers can find it difficult to keep up to date with the literature in their field. Providing an invaluable resource, this volume contains analysed, evaluated and distilled information on the latest in organometallic chemistry research and emerging fields. The reviews range in scope and include π-coordinated arene metal complexes and catalysis by arene exchange, rylenes as chromophores in catalysts for CO2 photoreduction, metal nodes and metal sites in metal–organic frameworks, developments in molecular precursors for CVD and ALD, and multiphoton luminescence processes in f-element containing compounds.
Author: Kenji Yamamoto
Author: Kenji Yamamoto
Author: Marin A. Cato
Author: Francis Gordon Albert Stone
Author: 
Author: Armando J. L. Pombeiro
Author: Thomas J. Colacot
Author: Karl Kirchner
Author: Akshai Kumar
Author: Marcel Gielen
Author: Nathan J Patmore