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Author: Publisher: ISBN: Category : Languages : en Pages :
Book Description
In initial operation of a new flowsheet for recovery of highly irradiated enriched uranium by solvent extraction with 7.5 vol percent tri-n-butyl phosphate, valence adjustment of plutonium and neptunium with ferrous sulfamate was ineffective; plutonium was not rejected as desired, and neptunium was partially lost to waste. Laboratory studies demonstrated that ferrous sulfamate, added to both the aqueous feed solution and the aqueous scrub stream in the first stage (IAS), was largely destroyed during the relatively long time between preparation and use of these solutions. Radiolysis destroyed the ferrous ion in the feed in a few hours, and nitric acid oxidized much of the ferrous ion in the scrub solution. To achieve the desired neptunium-plutonium separation in plant operation, the process flowsheet was modified as follows: ferrous sulfamate is added to the IAS stream immediately before it enters the mixer-settler, and ferrous fulfamate is not added to the feed solution where it would be destroyed by radiolysis.
Author: Publisher: ISBN: Category : Languages : en Pages :
Book Description
In initial operation of a new flowsheet for recovery of highly irradiated enriched uranium by solvent extraction with 7.5 vol percent tri-n-butyl phosphate, valence adjustment of plutonium and neptunium with ferrous sulfamate was ineffective; plutonium was not rejected as desired, and neptunium was partially lost to waste. Laboratory studies demonstrated that ferrous sulfamate, added to both the aqueous feed solution and the aqueous scrub stream in the first stage (IAS), was largely destroyed during the relatively long time between preparation and use of these solutions. Radiolysis destroyed the ferrous ion in the feed in a few hours, and nitric acid oxidized much of the ferrous ion in the scrub solution. To achieve the desired neptunium-plutonium separation in plant operation, the process flowsheet was modified as follows: ferrous sulfamate is added to the IAS stream immediately before it enters the mixer-settler, and ferrous fulfamate is not added to the feed solution where it would be destroyed by radiolysis.
Author: United States. Energy Research and Development Administration. Technical Information Center Publisher: ISBN: Category : Force and energy Languages : en Pages : 588
Author: R. Guillaumont Publisher: ISBN: Category : Science Languages : en Pages : 976
Book Description
This volume is part of the series on "Chemical Thermodynamics", published under the aegis of the OECD Nuclear Energy Agency, and updates and expands the thermodynamic data on inorganic compounds and complexes of uranium, neptunium, plutonium, americium and technetium contained in the previous volumes of the series. A review team, composed of seven internationally recognized experts, has critically reviewed during five years all the scientific literature containing chemical thermodynamic information for the above mentioned systems that has appeared since the publication of the earlier volumes. The results of this critical review carried out following the Guidelines of the OECD NEA Thermochemical Database Project have been documented in the present volume, which contains new tables of selected values for formation and reaction thermodynamical properties and an extensive bibliography.
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Author: William John Maeck
Author: Wallace W. Schulz
Author: United States. Energy Research and Development Administration
Author: C. L. Schuske
Author: United States. Energy Research and Development Administration. Technical Information Center
Author: T. J. Connolly
Author: R. Guillaumont
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