MULTISCALE INVESTIGATION OF DROPWISE CONDENSATION ON A SMOOTH HYDROPHILIC SURFACE PDF Download

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Languages : en
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Abstract : The objective of this work is to identify the fundamental mechanism of dropwise condensation on a smooth solid surface by probing the solid-vapor interface during phase-change to evaluate the existence and structure of the thin film and the initial nucleus that develop during condensation. In this work, an automated Surface Plasmon Resonance imaging (SPRi) instrument with the ability to perform imaging in intensity modulation and angular modulation is developed. The SPRi instrument is used to probe (in three dimensions) the adsorbed film that forms on the substrate during dropwise condensation. SPRi with a lateral resolution of ~ 4-10 μm, thickness resolution of 0.1-1nm, and temporal resolution of 200-10,000 frames per second can measure water films that are monolayer to multilayer in thickness. The governing mechanism of dropwise condensation is investigated in detail for stable dropwise condensation on a smooth hydrophilic substrate. The study shows nucleation is the first step in dropwise condensation and no film greater than a monolayer exists between droplets during stable dropwise condensation. Our result confirms previous experimental works in support of nucleation theory as the mechanism of dropwise condensation. Our observation of unstable dropwise condensation of steam on a smooth hydrophilic surface shows presence of a several nanometers thick water film between droplets during dropwise condensation. This data matches with previous experimental work in support of film rupture theory. In summary, our results indicate nucleation theory or film rupture theory may be valid for special experimental settings. And, neither of these two theories are a comprehensive theory than can explain the physics of dropwise condensation.

Author: Yajing Zhao (S.M.)
Publisher:
ISBN:
Category :
Languages : en
Pages : 62

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Condensation is a ubiquitous process often observed in nature and our daily lives. The large amount of latent heat released during the condensation process has been harnessed in many industrial processes such as power generation, building heating and cooling, desalination, dew harvesting, thermal management, and refrigeration. Condensation has two modes: dropwise mode and filmwise mode. Although it has been known for decades that dropwise condensation outperforms filmwise condensation in heat transfer owing to the droplet shedding effects which can efficiently reduce thermal resistance, filmwise condensation still dominates industrial applications currently due to the high costs, low robustness and technical challenges of manufacturing dropwise coatings. During water condensation, dropwise mode can be readily promoted with thin hydrophobic coatings. Superhydrophobic surfaces made out of hydrophobic coatings on micro-or-nano-engineered surfaces have shown further heat transfer enhancement in dropwise condensation of water; however, the applications of these micro- or nanoscale structured surface designs have been restricted by the high manufacturing expenses and short range of subcooling limit. Recent studies have shown that the combination of millimeter sized geometric features and plain hydrophobic coatings can effectively manipulate droplet distribution of water condensate, which provides opportunities to locally facilitate dropwise condensation at relatively low manufacturing expenses as compared to those delicate micro- and nano-structured hydrophobic surfaces. Low surface tension fluids such as hydrocarbons pose a unique challenge to achieving dropwise condensation, because common hydrophobic coatings are not capable of repelling low surface tension fluids. Recent development in lubricant infused surfaces (LIS) offers promising solutions to achieving dropwise condensation of low surface tension fluids by replacing the solid-condensate interface in conventional hydrophobic coatings with a smooth lubricant-condensate interface. However, only a few experimental studies have applied LIS to promoting dropwise condensation of low surface tension fluids (y as low as 15 mN/m). In this work, we investigated dropwise condensation of both water (y ~ 72 mN/m) and a low surface tension fluid, namely butane (y - 13 mN/m) on structured surfaces. For water condensation, we studied the effects of millimeter sized geometric structures on dropwise condensation heat transfer under two different environments: pure vapor and an air-vapor mixture. Our experimental results show that, although convex structures enable faster droplet growth in an air-vapor mixture, the same structures impose the opposite effect during pure vapor condensation, hindering droplet growth. We developed a numerical model for each case to predict the heat flux distribution along the structured surface, and the model shows good agreement with experimental results. This work demonstrates that the effects of geometric features on dropwise condensation are not invariable but rather dependent on the scenario of resistances to heat and mass transfer in the system. For butane condensation, based on a design guideline we recently developed for lubricant infused surfaces, we successfully designed an energy-favorable combination of lubricant and structured solid substrate, which was further demonstrated to promote dropwise condensation of butane. The fundamental understanding of dropwise condensation of water and low surface tension fluids on structured surfaces developed in this study provides useful guidelines for condensation applications including power generation, desalination, dew harvesting, and thermal management.

Author: Sameer Khandekar
Publisher: Springer Nature
ISBN: 3030484610
Category : Science
Languages : en
Pages : 462

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This book is an expanded form of the monograph, Dropwise Condensation on Inclined Textured Surfaces, Springer, 2013, published earlier by the authors, wherein a mathematical model for dropwise condensation of pure vapor over inclined textured surfaces was presented, followed by simulations and comparison with experiments. The model factored in several details of the overall quasi-cyclic process but approximated those at the scale of individual drops. In the last five years, drop level dynamics over hydrophobic surfaces have been extensively studied. These results can now be incorporated in the dropwise condensation model. Dropwise condensation is an efficient route to heat transfer and is often encountered in major power generation applications. Drops are also formed during condensation in distillation devices that work with diverse fluids ranging from water to liquid metals. Design of such equipment requires careful understanding of the condensation cycle, starting from the birth of nuclei, followed by molecular clusters, direct growth of droplets, their coalescence, all the way to instability and fall-off of condensed drops. The model described here considers these individual steps of the condensation cycle. Additional discussions include drop shape determination under static conditions, a fundamental study of drop spreading in sessile and pendant configurations, and the details of the drop coalescence phenomena. These are subsequently incorporated in the condensation model and their consequences are examined. As the mathematical model is spread over multiple scales of length and time, a parallelization approach to simulation is presented. Special topics include three-phase contact line modeling, surface preparation techniques, fundamentals of evaporation and evaporation rates of a single liquid drop, and measurement of heat transfer coefficient during large-scale condensation of water vapor. We hope that this significantly expanded text meets the expectations of design engineers, analysts, and researchers working in areas related to phase-change phenomena and heat transfer.

Author: Sameer Khandekar
Publisher: Springer Science & Business Media
ISBN: 1461484472
Category : Science
Languages : en
Pages : 155

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Dropwise Condensation on Textured Surfaces presents a holistic framework for understanding dropwise condensation through mathematical modeling and meaningful experiments. The book presents a review of the subject required to build up models as well as to design experiments. Emphasis is placed on the effect of physical and chemical texturing and their effect on the bulk transport phenomena. Application of the model to metal vapor condensation is of special interest. The unique behavior of liquid metals, with their low Prandtl number and high surface tension, is also discussed. The model predicts instantaneous drop size distribution for a given level of substrate subcooling and derives local as well as spatio-temporally averaged heat transfer rates and wall shear stress.

Author: Alex Wu
Publisher:
ISBN:
Category :
Languages : en
Pages :

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Author: Efstathios Michaelides
Publisher: CRC Press
ISBN: 1315354624
Category : Science
Languages : en
Pages : 1559

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The Multiphase Flow Handbook, Second Edition is a thoroughly updated and reorganized revision of the late Clayton Crowe’s work, and provides a detailed look at the basic concepts and the wide range of applications in this important area of thermal/fluids engineering. Revised by the new editors, Efstathios E. (Stathis) Michaelides and John D. Schwarzkopf, the new Second Edition begins with two chapters covering fundamental concepts and methods that pertain to all the types and applications of multiphase flow. The remaining chapters cover the applications and engineering systems that are relevant to all the types of multiphase flow and heat transfer. The twenty-one chapters and several sections of the book include the basic science as well as the contemporary engineering and technological applications of multiphase flow in a comprehensive way that is easy to follow and be understood. The editors created a common set of nomenclature that is used throughout the book, allowing readers to easily compare fundamental theory with currently developing concepts and applications. With contributed chapters from sixty-two leading experts around the world, the Multiphase Flow Handbook, Second Edition is an essential reference for all researchers, academics and engineers working with complex thermal and fluid systems.

Author: David Milton Anderson
Publisher:
ISBN:
Category : Amphiphiles
Languages : en
Pages :

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Condensation of water vapor is an everyday phenomenon which plays an important role in power generation schemes, desalination applications and high-heat flux cooling of power electronic devices. Continuous dropwise condensation is a desirable mode of condensation in which small, highly-spherical droplets regularly form and shed off the surface before a thick liquid is formed, thereby minimizing the thermal resistance to heat transfer across the condensate layer. While difficult to induce and sustain, dropwise condensation has been shown to achieve heat and mass transfer coefficients over an order of magnitude higher than its filmwise counterpart. Superhydrophobic surfaces have been extensively studied to promote dropwise condensation with mixed results; often surfaces that are superhydrophobic to deposited droplets formed in the gas phase above the surface do not retain this behavior with condensed droplets nucleated and grown on the surface. Recently, nanostructured superhydrophobic surfaces have been developed that are robust to vapor condensation; however, these surfaces still are not ideal for condensation heat transfer due to the high thermal resistance of the vapor layer trapped underneath the droplets and the reduced footprint of direct contact between the highly-spherical droplets and the underlying substrate. This work has two main objectives. First, a comprehensive free energy based thermodynamic model is developed to better understand why traditional superhydrophobic surfaces often lose their properties when exposed to condensed droplets. The model is first validated using data from the existing literature and then extended to analyze the suitability of amphiphilic (e.g. part hydrophobic and part hydrophilic) nanostructured surfaces for condensation applications. Secondly, one of the promising amphiphilic surfaces identified by the thermodynamic model is fabricated and tested to observe condensation dynamic behavior. Two complementary visualization techniques, environmental scanning electron microscopy (ESEM) and optical (light) microscopy, are used to probe the condensation behavior and compare the performance to that of a traditional superhydrophobic surface. Observations from the condensation experiments are used to propose a new mechanism of coalescence that governs the temporal droplet size distribution on the amphiphilic nanostructured surface and continually generates fresh sites for the droplet nucleation and growth cycle that is most efficient at heat transfer.

Author: Phuong Pham
Publisher: BoD – Books on Demand
ISBN: 1789851998
Category : Technology & Engineering
Languages : en
Pages : 295

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Surface sciences elucidate the physical and chemical aspects of the surfaces and interfaces of materials. Of great interest in this field are nanomaterials, which have recently experienced breakthroughs in synthesis and application. As such, this book presents some recent representative achievements in the field of surface science, including synthesis techniques, surface modifications, nanoparticle-based smart coatings, wettability of different surfaces, physics/chemistry characterizations, and growth kinetics of thin films. In addition, the book illustrates some of the important applications related to silicon, CVD graphene, graphene oxide, transition metal dichalcogenides, carbon nanotubes, carbon nanoparticles, transparent conducting oxide, and metal oxides.

Author: Kuok Kong Cheng
Publisher:
ISBN:
Category : Electronic books
Languages : en
Pages : 236

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Wettability of a solid surface with liquids could be tuned based on surface morphologies. This is significant in condensation heat transfer. Condensation is a critical heat transfer mechanism in industrial processes; Dropwise (DWC) and Filmwise (FWC) condensation processes are important and are focus of this study. There are few studies on surface morphology effect on wetting behavior of a solid in relation to condensation heat transfer. We conducted these studies to understand the phenomenon. Condensation heat transfer is affected by condensate droplets properties on the surface. Condensate drop sizes and mobility relationships are important to condensation heat transfer. Droplet sizes and mobility affect population density and condensation heat transfer coefficients directly. The goal of this study is to acquire the fundamental understanding of condensation heat transfer with relation to condensate droplet behavior. In order to achieve this goal, a liquid droplet wetting dynamic model was initially developed for predicting single drop behavior on different surfaces. Heat fluxes were then estimated by combining liquid droplet behavior models and heat transfer model. Condensation experiments were conducted to verify effectiveness of the model. Experimental results coupled with condensation models revealed relationships between wetting behaviors and condensation heat transfer. Contact angle hysteresis (CAH) remains low at both high and low droplet contact angle, i.e. whether the surface is hydrophilic or hydrophobic. CAH increases with degree of wetting, but coating thermal conductance also increases. Details of drop (DWC) and film-wise (FWC) condensation are presented.

Author: Kock-Yee Law
Publisher: Springer
ISBN: 3319252143
Category : Technology & Engineering
Languages : en
Pages : 169

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This book describes wetting fundamentals and reviews the standard protocol for contact angle measurements. The authors include a brief overview of applications of contact angle measurements in surface science and engineering. They also discuss recent advances and research trends in wetting fundamentals and include measurement techniques and data interpretation of contract angles.