Multiplets of Transition-Metal Ions in Crystals PDF Download
Are you looking for read ebook online? Search for your book and save it on your Kindle device, PC, phones or tablets. Download Multiplets of Transition-Metal Ions in Crystals PDF full book. Access full book title Multiplets of Transition-Metal Ions in Crystals by Satoru Sugano. Download full books in PDF and EPUB format.
Author: Satoru Sugano Publisher: Elsevier ISBN: 0323154794 Category : Science Languages : en Pages : 348
Book Description
Multiplets of Transition-Metal Ions in Crystals provides information pertinent to ligand field theory. This book discusses the fundamentals of quantum mechanics and the theory of atomic spectra. Comprised of 10 chapters, this book starts with an overview of the qualitative nature of the splitting of the energy level as well as the angular behavior of the wavefunctions. This text then examines the problem of obtaining the energy eigenvalues and eigenstates of the two-electron systems, in which two electrons are accommodated in the t2g and eg shells in a variety of ways. Other chapters discuss the ligand-field potential, which is invariant to any symmetry operation in the group to which symmetry of the system belongs. This book discusses as well the approximate method of expressing molecular orbitals (MO) by a suitable linear combination of atomic orbitals (AO). The final chapter discusses the MO in molecules and the self-consistent field theory of Hartree–Fock. This book is a valuable resource for research physicists, chemists, electronic engineers, and graduate students.
Author: Satoru Sugano Publisher: Elsevier ISBN: 0323154794 Category : Science Languages : en Pages : 348
Book Description
Multiplets of Transition-Metal Ions in Crystals provides information pertinent to ligand field theory. This book discusses the fundamentals of quantum mechanics and the theory of atomic spectra. Comprised of 10 chapters, this book starts with an overview of the qualitative nature of the splitting of the energy level as well as the angular behavior of the wavefunctions. This text then examines the problem of obtaining the energy eigenvalues and eigenstates of the two-electron systems, in which two electrons are accommodated in the t2g and eg shells in a variety of ways. Other chapters discuss the ligand-field potential, which is invariant to any symmetry operation in the group to which symmetry of the system belongs. This book discusses as well the approximate method of expressing molecular orbitals (MO) by a suitable linear combination of atomic orbitals (AO). The final chapter discusses the MO in molecules and the self-consistent field theory of Hartree–Fock. This book is a valuable resource for research physicists, chemists, electronic engineers, and graduate students.
Author: E. König Publisher: Springer Science & Business Media ISBN: 1461330033 Category : Science Languages : en Pages : 560
Book Description
I.- 1. Introduction.- 2. Conventional Magnetism Diagrams and Their Limitations. Present State of the Art.- 3. Tensor Operator Algebra for Point Groups.- 3.1. Tensor Operators and the Wigner-Eckart Theorem.- 3.2. 3-? and 6-? Symbols.- 3.3. Tensor Operators in Subgroups of SO(3).- 3.4. Kronecker and Scalar Products of Tensor Operators.- 3.5. Tensor Operators of the Ligand Field.- 4. The Weak-Field Method.- 4.1. The Hamiltonian, States, and Wave Functions.- 4.2. The Various Coefficients.- 4.3. Matrix Elements.- 4.4. Calculation of Magnetic Susceptibility.- 5. The Intermediate-Field Method.- 5.1.
Author: Mikhail G. Brik Publisher: CRC Press ISBN: 1000000737 Category : Science Languages : en Pages : 462
Book Description
This book describes in detail the main concepts of theoretical spectroscopy of transition metal and rare-earth ions. It shows how the energy levels of different electron configurations are formed and calculated for the ions in a free state and in crystals, how group theory can help in solving main spectroscopic problems, and how the modern DFT-based methods of calculations of electronic structure can be combined with the semi-empirical crystal field models. The style of presentation makes the book helpful for a wide audience ranging from graduate students to experienced researchers. Performance of optical materials crucially depends on the impurity ions intentionally introduced into the crystalline host materials. The color of these materials, their emission and absorption spectra can be understood by analyzing the relations between the electronic properties of impurity ions and host crystal structure, which constitutes the main content of this book. It describes in detail the main concepts of theoretical spectroscopy of transition metal and rare earth ions.
Author: Nicolae M. Avram Publisher: Springer Science & Business Media ISBN: 3642308384 Category : Science Languages : en Pages : 278
Book Description
"Optical Properties of 3d-Ions in Crystals: Spectroscopy and Crystal Field Analysis" discusses spectral, vibronic and magnetic properties of 3d-ions in a wide range of crystals, used as active media for solid state lasers and potential candidates for this role. Crystal field calculations (including first-principles calculations of energy levels and absorption spectra) and their comparison with experimental spectra, the Jahn-Teller effect, analysis of vibronic spectra, materials science applications are systematically presented. The book is intended for researchers and graduate students in crystal spectroscopy, materials science and optical applications. Dr. N.M. Avram is an Emeritus Professor at the Physics Department, West University of Timisoara, Romania; Dr. M.G. Brik is a Professor at the Institute of Physics, University of Tartu, Estonia.
Author: Alexander Kaminskii Publisher: CRC Press ISBN: 1000102831 Category : Technology & Engineering Languages : en Pages : 592
Book Description
By the end of the 1970s, crystalline lasers were widely used in science, engineering, medicine, and technology. The types of lasers used have continued to grow in number to include newly discovered crystalline hosts, previously known compounds generating at other spectral wavelengths, and broadband tunable stimulated emission. This has led to the creation of an extremely promising new generation of crystalline lasers that are both highly efficient and more reliable. The major part of this book is devoted to describing multilevel operating laser schemes for stimulated emission excitation in insulating crystals doped with lanthanide ions. The first part of Crystalline Lasers deals with the history of the physics and spectroscopy of insulating laser crystals. The chapters in the second part of the book present results from the study of Stark-energy levels of generating ions in laser crystals and their radiative and nonradiative intermanifold transition characteristics. This section includes extensive tabular data and reference information. Popular and novel operating schemes of crystalline lasers are covered in Part 3. In the chapters in the fourth part of the book, the newest technologies in the physics and engineering of crystalline lasers are considered. The results of investigations into laser action under selective excitations, miniature crystalline lasers, and the properties of nonlinear activated laser crystals are presented and analyzed. Crystalline Lasers summarizes and reviews the results of many years of research and studies of activator ions and multilevel operating laser schemes, and discusses exciting prospects of using these systems to create new types of crystalline lasers. This book will be of use to laser scientists and engineers, physicists, and chemical engineers.
Author: Gabriele Centi Publisher: Springer Science & Business Media ISBN: 9401007829 Category : Science Languages : en Pages : 331
Book Description
Atomically dispersed metal cations and small polyatomic cationic structures co-ordinated to the surface of porous matrices exhibit different properties from the same cationic species contained in a bulk oxide or supported on amorphous carriers. This subject is treated to an extensive review, showing how an understanding of it is essential to the development of a new generation of solid catalysts. There are also exciting opportunities to shape the catalytic properties of the transition metal cations in microporous and mesoporous matrices. The book covers both theoretical and experimental aspects, including the distribution of framework Al atoms in Si-rich zeolites, distribution and siting of charge-exchanged metal cations, electronic, adsorptive and catalytic properties of metal cations, and correlation of metal cation structure and siting with catalytic activity.
Author: Satoru Sugano
Author: Satoru Sugano
Author: Yukito Tanabe
Author: Satoru Sugano (Tanabe, Yukito, Kamimura, Hiroshi)![Multiplets of Transition-metal Ions in Crystals [by] Satoru Sugano, Yukito Tanabe [and] Hiroshi Kamimura PDF](https://books.google.com/books/content/images/frontcover/LO2CswEACAAJ?fife=w80-h100)
Author: Satoru Sugano
Author: E. König
Author: Mikhail G. Brik
Author: Nicolae M. Avram
Author: Arthur Elliott Salwin
Author: Alexander Kaminskii
Author: Gabriele Centi