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Molecular Structure and Reactivity of Silica-supported Metal Oxide Catalysts

Molecular Structure and Reactivity of Silica-supported Metal Oxide Catalysts PDF Author: Edward L. Lee
Publisher:
ISBN: 9780549277521
Category :
Languages : en
Pages : 289

Book Description
SiO2-supported metal oxide catalysts find a wide range of industrial applications, including oxidation, isomerization, metathesis, and polymerization reactions. Unfortunately, the fundamental understanding of these catalysts based on the structure---reactivity relationship is still lacking and not well understood. Therefore, resolving the molecular structure and the relationship with the catalytic reactivity is the motivation of this investigation.

Molecular Structure and Reactivity of Silica-supported Metal Oxide Catalysts

Molecular Structure and Reactivity of Silica-supported Metal Oxide Catalysts PDF Author: Edward L. Lee
Publisher:
ISBN: 9780549277521
Category :
Languages : en
Pages : 289

Book Description
SiO2-supported metal oxide catalysts find a wide range of industrial applications, including oxidation, isomerization, metathesis, and polymerization reactions. Unfortunately, the fundamental understanding of these catalysts based on the structure---reactivity relationship is still lacking and not well understood. Therefore, resolving the molecular structure and the relationship with the catalytic reactivity is the motivation of this investigation.

Metal Oxide Catalysis, 2 Volume Set

Metal Oxide Catalysis, 2 Volume Set PDF Author: S. David Jackson
Publisher: John Wiley & Sons
ISBN: 9783527318155
Category : Science
Languages : en
Pages : 916

Book Description
With its two-volume structure, this handbook and ready reference allows for comprehensive coverage of both characterization and applications, while uniform editing throughout ensures that the structure remains consistent. The result is an up-to-date review of metal oxides in catalysis. The first volume covers a range of techniques that are used to characterize oxides, with each chapter written by an expert in the field. Volume 2 goes on to cover the use of metal oxides in catalytic reactions. For all chemists and engineers working in the field of heterogeneous catalysis.

Molecular Structure-reactivity Relationships for Supported Molybdenum Oxide Catalysts

Molecular Structure-reactivity Relationships for Supported Molybdenum Oxide Catalysts PDF Author: Hangchun Hu
Publisher:
ISBN:
Category : Catalysts
Languages : en
Pages : 444

Book Description


Surface Organometallic Chemistry: Molecular Approaches to Surface Catalysis

Surface Organometallic Chemistry: Molecular Approaches to Surface Catalysis PDF Author: Jean-Marie Basset
Publisher: Springer Science & Business Media
ISBN: 9400929714
Category : Science
Languages : en
Pages : 340

Book Description
Surface organometallic chemistry is a new field bringing together researchers from organometallic, inorganic, and surface chemistry and catalysis. Topics ranging from reaction mechanisms to catalyst preparation are considered from a molecular basis, according to which the "active site" on a catalyst surface has a supra-molecular character. This. the first book on the subject, is the outcome of a NATO Workshop held in Le Rouret. France, in May. 1986. It is our hope that the following chapters and the concluding summary of recommendations for research may help to provide a definition of surface organometallic chemistry. Besides catalysis. the central theme of the Workshop, four main topics are considered: 1) Reactions of organometallics with surfaces of metal oxides, metals. and zeolites; 2) Molecular models of surfaces, metal oxides, and metals; 3) Molecular approaches to the mechanisms of surface reactions; 4) Synthesis and modification of zeolites and related microporous solids. Most surface organometallic chemistry has been carried out on amorphous high-surf ace-area metal oxides such as silica. alumina. magnesia, and titania. The first chapter. contributed by KNOZINGER. gives a short summary of the structure and reactivity of metal oxide surfaces. Most of our understanding of these surfaces is based on acid base and redox chemistry; this chemistry has developed from X-ray and spectroscopic data, and much has been inferred from the structures and reactivities of adsorbed organic probe molecules. There are major opportunities for extending this understanding by use of well-defined (single crystal) oxide surfaces and organometallic probe molecules.

Supported Metals in Catalysis

Supported Metals in Catalysis PDF Author: James Arthur Anderson
Publisher: World Scientific
ISBN: 184816677X
Category : Science
Languages : en
Pages : 581

Book Description
With contributions from experts in supported metal catalysis, from both the industry and academia, this book presents the latest developments in characterization and application of supported metals in heterogeneous catalysis. In addition to a thorough and updated coverage of the traditional aspects of heterogeneous catalysis such as preparation, characterization and use in well-established technologies such as Naphtha reforming, the book also includes emerging areas where supported metal catalysis will make significant contributions in future developments, such as fuel cells and fine chemicals synthesis. The second edition of Supported Metals in Catalysis comes complete with new and updated chapters containing important summaries of research in a rapidly evolving field. Very few other books deal with this highly pertinent subject matter, and as such, it is a must-have for anyone working in the field of heterogeneous catalysis.

Metal Oxides

Metal Oxides PDF Author: J.L.G. Fierro
Publisher: CRC Press
ISBN: 142002812X
Category : Science
Languages : en
Pages : 808

Book Description
The chemistry of metals has traditionally been more understood than that of its oxides. As catalytic applications continue to grow in a variety of disciplines, Metal Oxides: Chemistry and Applications offers a timely account of transition-metal oxides (TMO), one of the most important classes of metal oxides, in the context of catalysis. The

Metal Oxides in Heterogeneous Catalysis

Metal Oxides in Heterogeneous Catalysis PDF Author: Jacques C. Vedrine
Publisher: Elsevier
ISBN: 0128116323
Category : Technology & Engineering
Languages : en
Pages : 620

Book Description
Metal Oxides in Heterogeneous Catalysis is an overview of the past, present and future of heterogeneous catalysis using metal oxides catalysts. The book presents the historical, theoretical, and practical aspects of metal oxide-based heterogeneous catalysis. Metal Oxides in Heterogeneous Catalysis deals with fundamental information on heterogeneous catalysis, including reaction mechanisms and kinetics approaches.There is also a focus on the classification of metal oxides used as catalysts, preparation methods and touches on zeolites, mesoporous materials and Metal-organic frameworks (MOFs) in catalysis. It will touch on acid or base-type reactions, selective (partial) and total oxidation reactions, and enzymatic type reactions The book also touches heavily on the biomass applications of metal oxide catalysts and environmentally related/depollution reactions such as COVs elimination, DeNOx, and DeSOx. Finally, the book also deals with future trends and prospects in metal oxide-based heterogeneous catalysis. - Presents case studies in each chapter that provide a focus on the industrial applications - Includes fundamentals, key theories and practical applications of metal oxide-based heterogeneous catalysis in one comprehensive resource - Edited, and contributed, by leading experts who provide perspectives on synthesis, characterization and applications

Catalyst Preparation

Catalyst Preparation PDF Author: John Regalbuto
Publisher: CRC Press
ISBN: 1420006509
Category : Science
Languages : en
Pages : 490

Book Description
This text explores the optimization of catalytic materials through traditional and novel methods of catalyst preparation, characterization, and monitoring for oxides, supported metals, zeolites, and heteropolyacids. It focuses on the synthesis of bulk materials and of heterogeneous materials, particularly at the nanoscale. The final chapters examine pretreatment, drying, finishing effects, and future applications involving catalyst preparation and the technological advances necessary for continued progress. Topics also include heat and mass transfer limitations, computation methods for predicting properties, and catalyst monitoring on laboratory and industrial scales.

Design of Heterogeneous Catalysts

Design of Heterogeneous Catalysts PDF Author: Umit S. Ozkan
Publisher: John Wiley & Sons
ISBN: 352762533X
Category : Science
Languages : en
Pages : 340

Book Description
This long-awaited reference source is the first book to focus on this important and hot topic. As such, it provides examples from a wide array of fields where catalyst design has been based on new insights and understanding, presenting such modern and important topics as self-assembly, nature-inspired catalysis, nano-scale architecture of surfaces and theoretical methods. With its inclusion of all the useful and powerful tools for the rational design of catalysts, this is a true "must have" book for every researcher in the field.

Characterization of Solid Materials and Heterogeneous Catalysts

Characterization of Solid Materials and Heterogeneous Catalysts PDF Author: Michel Che
Publisher: John Wiley & Sons
ISBN: 3527645330
Category : Technology & Engineering
Languages : en
Pages : 1313

Book Description
This two-volume book provides an overview of physical techniques used to characterize the structure of solid materials, on the one hand, and to investigate the reactivity of their surface, on the other. Therefore this book is a must-have for anyone working in fields related to surface reactivity. Among the latter, and because of its most important industrial impact, catalysis has been used as the directing thread of the book. After the preface and a general introduction to physical techniques by M. Che and J.C. Vedrine, two overviews on physical techniques are presented by G. Ertl and Sir J.M. Thomas for investigating model catalysts and porous catalysts, respectively. The book is organized into four parts: Molecular/Local Spectroscopies, Macroscopic Techniques, Characterization of the Fluid Phase (Gas and/ or Liquid), and Advanced Characterization. Each chapter focuses upon the following important themes: overview of the technique, most important parameters to interpret the experimental data, practical details, applications of the technique, particularly during chemical processes, with its advantages and disadvantages, conclusions.