Author: Rex StoessigerPublisher:
ISBN:
Category : Molecular orbitals
Languages : en
Pages : 118
Book Description
Molecular Orbital Calculations for Transition Metal Complexes, Infrared Studies of Some Fluorozirconates
Author: Rex StoessigerPublisher:
ISBN:
Category : Molecular orbitals
Languages : en
Pages : 118
Book Description
Molecular Orbitals of Transition Metal Complexes
Author: Yves JeanPublisher: Oxford University Press
ISBN: 0198530935
Category : Science
Languages : en
Pages : 288
Book Description
This book starts with the most elementary ideas of molecular orbital theory and leads the reader progressively to an understanding of the electronic structure, geometry and, in some cases, reactivity of transition metal complexes. The qualitative orbital approach, based on simple notions such as symmetry, overlap and electronegativity, is the focus of the presentation and a substantial part of the book is associated with the mechanics of the assembly of molecular orbital diagrams. The first chapter recalls the basis for electron counting in transition metal complexes. The main ligand fields (octahedral, square planar, tetrahedral, etc.) are studied in the second chapter and the structure of the "d block" is used to trace the relationships between the electronic structure and the geometry of the complexes. The third chapter studies the change in analysis when the ligands have pi-type interactions with the metal. All these ideas are then used in the fourth chapter to study a series of selected applications of varying complexity (e.g. structure and reactivity). The fifth chapter deals with the "isolobal analogy" which points out the resemblance between the molecular orbitals of inorganic and organic species and provides a bridge between these two subfields of chemistry. The last chapter is devoted to a presentation of basic Group Theory with applications to some of the complexes studied in the earlier chapters.
Molecular Orbital Studies of Some Transition Metal Complexes
Author: Michael A. McGinnMolecular Orbital Calculations for Transition Metal Complexes Containing Pi-acceptor Ligands
Author: Roger L. DeKockPublisher:
ISBN:
Category : Ligand field theory
Languages : en
Pages : 606
Book Description
Molecular Orbital Studies of Bonding, Structures, and Reactions of Organometallic and Inorganic Complexes of Transition Metals
Author: Nenad M. KostićPublisher:
ISBN:
Category : Molecular orbitals
Languages : en
Pages : 340
Book Description
Molecular Orbital Calculations for Octahedral Transition Metal Complexes of CO, CN- and N2
Author: Kenneth George CaultonPublisher:
ISBN:
Category : Complex compounds
Languages : en
Pages : 246
Book Description
Semi-rigorous Molecular Orbital Calculation of Transition Metal Complexes
Author: Harutun G. KarianPublisher:
ISBN:
Category : Molecular orbitals
Languages : en
Pages : 168
Book Description
Synthetic Studies and Molecular Orbital Calculations in Early Transition Metal Organodimetallic and Trinuclear Cluster Chemistries
Author: Jeffrey James LuciA Molecular Orbital Study of Some Transitional Metal Complexes
Author: George Henry MurphyInfrared Spectroscopy of Transition Metal-Molecular Interactions in the Gas Phase
Author: Publisher:
ISBN:
Category :
Languages : en
Pages : 16
Book Description
Transition metal-molecular complexes produced in a molecular beam are mass-selected and studied with infrared laser photodissociation spectroscopy. Metal complexes with carbon monoxide, carbon dioxide, nitrogen, water, acetylene or benzene are studied for a variety of metals. The number and intensity of infrared active bands are compared to the predictions of density functional theory calculations to derive structures, spin states and coordination numbers in these systems. These studied provide new insights into subtle details of metal-molecular interactions important in heterogeneous catalysis, metal-ligand bonding and metal ion solvation.