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Molecular Relaxation in Liquids

Molecular Relaxation in Liquids PDF Author: Biman Bagchi
Publisher: Oxford University Press
ISBN: 0199863334
Category : Science
Languages : en
Pages : 331

Book Description
This book brings together many different relaxation phenomena in liquids under a common umbrella and provides a unified view of apparently diverse phenomena. It aligns recent experimental results obtained with modern techniques with recent theoretical developments. Such close interaction between experiment and theory in this area goes back to the works of Einstein, Smoluchowski, Kramers' and de Gennes. Development of ultrafast laser spectroscopy recently allowed study of various relaxation processes directly in the time domain, with time scales going down to picosecond (ps) and femtosecond (fs) time scales. This was a remarkable advance because many of the fundamental chemical processes occur precisely in this range and was inaccessible before the 1980s. Since then, an enormous wealth of information has been generated by many groups around the world, who have discovered many interesting phenomena that has fueled further growth in this field. As emphasized throughout the book, the seemingly different phenomena studied in this area are often closely related at a fundamental level. Biman Bagchi explains why relatively small although fairly sophisticated theoretical tools have been successful in explaining a wealth of experimental data at a semi-phenomenological level.

Molecular Relaxation in Liquids

Molecular Relaxation in Liquids PDF Author: Biman Bagchi
Publisher: Oxford University Press
ISBN: 0199863334
Category : Science
Languages : en
Pages : 331

Book Description
This book brings together many different relaxation phenomena in liquids under a common umbrella and provides a unified view of apparently diverse phenomena. It aligns recent experimental results obtained with modern techniques with recent theoretical developments. Such close interaction between experiment and theory in this area goes back to the works of Einstein, Smoluchowski, Kramers' and de Gennes. Development of ultrafast laser spectroscopy recently allowed study of various relaxation processes directly in the time domain, with time scales going down to picosecond (ps) and femtosecond (fs) time scales. This was a remarkable advance because many of the fundamental chemical processes occur precisely in this range and was inaccessible before the 1980s. Since then, an enormous wealth of information has been generated by many groups around the world, who have discovered many interesting phenomena that has fueled further growth in this field. As emphasized throughout the book, the seemingly different phenomena studied in this area are often closely related at a fundamental level. Biman Bagchi explains why relatively small although fairly sophisticated theoretical tools have been successful in explaining a wealth of experimental data at a semi-phenomenological level.

Molecular Basics of Liquids and Liquid-Based Materials

Molecular Basics of Liquids and Liquid-Based Materials PDF Author: Katsura Nishiyama
Publisher: Springer Nature
ISBN: 981165395X
Category : Science
Languages : en
Pages : 469

Book Description
This book sheds light on the molecular aspects of liquids and liquid-based materials such as organic or inorganic liquids, ionic liquids, proteins, biomaterials, and soft materials including gels. The reader discovers how the molecular basics of such systems are connected with their properties, dynamics, and functions. Once the use and application of liquids and liquid-based materials are understood, the book becomes a source of the latest, detailed knowledge of their structures, dynamics, and functions emerging from molecularity. The systems discussed in the book have structural dimensions varying from nanometers to millimeters, thus the precise estimation of structures and dynamics from experimental, theoretical, and simulation methods is of crucial importance. Outlines of the practical knowledge needed in research and development are helpfully included in the book.

Molecular Motions in Liquids

Molecular Motions in Liquids PDF Author: J. Lascombe
Publisher: Springer Science & Business Media
ISBN: 9401021775
Category : Science
Languages : en
Pages : 645

Book Description
When, in my capacity as President of the Societe de Chimie physique, I opened the 24th Annual Meeting of this Society, devoted this year to 'molecular motions in liquids', I was stirred by a particular emotion. This had two reasons, one general and the other rather personal. I would like to give an explanation in the Foreword to this volume of communications to the Meeting and their ensuing discussions. An essential characteristic of science is its international nature. It is like a symphony composed of contributions by all the countries playing together as an orchestra in unison. Just as a melody has different 'colours' when played by strings or woodwinds, so there exist similar 'colour' differences, subtle ones, between scientific contributions from different countries, rooted as they are in their own cultural history and liable to impoverish the ensemble if they should cease to participate. I have always had an impression of marked 'colour' differences prevailing among American, Russian, Japanese and European contributions, although within the latter group the timbre is very much the same. This is why I have dreamed of a European 'chamber orchestra' in addition to the great world orchestra.

Novel Approaches to the Structure and Dynamics of Liquids: Experiments, Theories and Simulations

Novel Approaches to the Structure and Dynamics of Liquids: Experiments, Theories and Simulations PDF Author: Jannis Samios
Publisher: Springer Science & Business Media
ISBN: 1402023847
Category : Science
Languages : en
Pages : 548

Book Description
The unique behavior of the "liquid state", together with the richness of phenomena that are observed, render liquids particularly interesting for the scientific community. Note that the most important reactions in chemical and biological systems take place in solutions and liquid-like environments. Additionally, liquids are utilized for numerous industrial applications. It is for these reasons that the understanding of their properties at the molecular level is of foremost interest in many fields of science and engineering. What can be said with certainty is that both the experimental and theoretical studies of the liquid state have a long and rich history, so that one might suppose this to be essentially a solved problem. It should be emphasized, however, that although, for more than a century, the overall scientific effort has led to a considerable progress, our understanding of the properties of the liquid systems is still incomplete and there is still more to be explored. Basic reason for this is the "many body" character of the particle interactions in liquids and the lack of long-range order, which introduce in liquid state theory and existing simulation techniques a number of conceptual and technical problems that require specific approaches. Also, many of the elementary processes that take place in liquids, including molecular translational, rotational and vibrational motions (Trans. -Rot. -Vib. coupling), structural relaxation, energy dissipation and especially chemical changes in reactive systems occur at different and/or extremely short timescales.

Dielectric and Related Molecular Processes

Dielectric and Related Molecular Processes PDF Author: Mansel Davies
Publisher: Royal Society of Chemistry
ISBN: 184755590X
Category : Science
Languages : en
Pages : 272

Book Description
Specialist Periodical Reports provide systematic and detailed review coverage of progress in the major areas of chemical research. Written by experts in their specialist fields the series creates a unique service for the active research chemist, supplying regular critical in-depth accounts of progress in particular areas of chemistry. For over 80 years the Royal Society of Chemistry and its predecessor, the Chemical Society, have been publishing reports charting developments in chemistry, which originally took the form of Annual Reports. However, by 1967 the whole spectrum of chemistry could no longer be contained within one volume and the series Specialist Periodical Reports was born. The Annual Reports themselves still existed but were divided into two, and subsequently three, volumes covering Inorganic, Organic and Physical Chemistry. For more general coverage of the highlights in chemistry they remain a 'must'. Since that time the SPR series has altered according to the fluctuating degree of activity in various fields of chemistry. Some titles have remained unchanged, while others have altered their emphasis along with their titles; some have been combined under a new name whereas others have had to be discontinued.

Molecular Liquids

Molecular Liquids PDF Author: A.J. Barnes
Publisher: Springer Science & Business Media
ISBN: 9400964633
Category : Science
Languages : en
Pages : 594

Book Description
This ASI was planned to make a major contribution to the teaching of the principles and methods used in liquid phase ~esearch and to encourage the setting up of collaborative projects, as advocated by the European Molecular Liquids Group (secretary: Dr J. Yarwood, University of Durham, U. K. ). During the past five years considerable progress has been made in studying molecular liquids. The undoubted advantages of international collaboration led to the formation of the European Molecular Liquids Group (EMLG) in July 1981. The activities of the EMLG were widely disseminated in a special session of the European Congress on Molecular Spectroscopy (EUCMOS) held in September 1981 (for details, see J. Mol. Structure, 80 (1982) 375 - 421). Following the success of this meeting, it was thought that the aims and objectives of the E~G would be best served by the organisation of a broader-based gathering designed to attract those interested in the study of the structure, dynamics and interactions in the liquid state. Thanks to the generous support by the Scientific Affairs Division of NATO, it was possible to hold a NATO ASI on Molecular Liquids at the Italian Centre of Stanford University, Florence, Italy during June-July 1983. This book is based on the lectures presented at that meeting. The contents of this volume cover the three broad areas of current liquid phase research: (a) Analytical theory.

Water in Biological and Chemical Processes

Water in Biological and Chemical Processes PDF Author: Biman Bagchi
Publisher: Cambridge University Press
ISBN: 1107037298
Category : Medical
Languages : en
Pages : 383

Book Description
A unified overview of the dynamical properties of water and its unique and diverse role in biological and chemical processes.

Binary Polar Liquids

Binary Polar Liquids PDF Author: Suresh C. Mehrotra
Publisher: Elsevier
ISBN: 012813254X
Category : Science
Languages : en
Pages : 478

Book Description
Binary Polar Liquids: Structural and Dynamic Characterization Using Spectroscopic Methods provides liquid state physical chemists and physicists with practical theoretical models based on a wealth of robust data that describe the dielectric properties of dipolar materials in a systematic manner. In many applications, reference measurements using dielectric permittivity data are required. Over the past three decades, the author has compiled and analyzed permittivity research data and relaxation times for various polar liquids and their mixtures. The resulting structural data - as determined from various models - is critically evaluated, arming scientists with a complete characterization of the spectra of water-containing mixtures. - Includes theoretical models that describe dielectric properties of dipolar materials - Features reference measurements using dielectric permittivity data - Describes the experimental techniques and procedures to extract the permittivity spectra and determination of different molecular parameters - Provides a critical evaluation and analysis of research data compiled and consolidated over more than 30 years

Handbook of Liquid Crystals, 8 Volume Set

Handbook of Liquid Crystals, 8 Volume Set PDF Author: John W. Goodby
Publisher: John Wiley & Sons
ISBN: 3527327738
Category : Technology & Engineering
Languages : en
Pages : 5240

Book Description
Much more than a slight revision, this second edition of the successful "Handbook of Liquid Crystals" is completely restructured and streamlined, with updated as well as completely new topics, 100% more content and a new team of editors and authors. As such, it fills the gap for a definitive, single source reference for all those working in the field of organized fluids and will set the standard for the next decade. The Handbook's new structure facilitates navigation and combines the presentation of the content by topic and by liquid-crystal type: A fundamentals volume sets the stage for an understanding of the liquid crystal state of matter, while individual volumes cover the main types and forms, with a final volume bringing together the diverse liquid crystal phases through their applications. This unrivaled, all-embracing coverage represents the undiluted knowledge on liquid crystals, making the Handbook a must-have wherever liquid crystals are investigated, produced or used, and in institutions where their science and technology is taught. Also available electronically on Wiley Online Library, www.wileyonlinelibrary.com/ref/holc Volume 1: Fundamentals of Liquid Crystals Volume 2: Physical Properties and Phase Behavior of Liquid Crystals Volume 3: Nematic and Chiral Nematic Liquid Crystals Volume 4: Smectic and Columnar Liquid Crystals Volume 5: Non-Conventional Liquid Crystals Volume 6: Nanostructured and Amphiphilic Liquid Crystals Volume 7: Supermolecular and Polymeric Liquid Crystals Volume 8: Applications of Liquid Crystals

Nuclear Magnetic Resonance of Liquid Crystals

Nuclear Magnetic Resonance of Liquid Crystals PDF Author: Ronald Y. Dong
Publisher: Springer Science & Business Media
ISBN: 146121954X
Category : Science
Languages : en
Pages : 320

Book Description
Intended for researchers and students in physics, chemistry and materials science, this book provides the necessary background information and sufficient mathematical and physical detail to study the current research literature. The book begins with a survey of liquid crystal phases and field effects, together with an introduction to the basic physics of nuclear magnetic resonance. It then discusses orientational ordering and molecular field theories for various liquid crystal molecules and nmr studies of uniaxial and biaxial phases. Subsequent chapters consider spin relaxation processes and rotational, translational, and internal molecular dynamics of liquid crystals. The final chapter discusses two-dimensional and multiple- quantum nmr spectroscopies and their application in elucidating liquid crystal properties. This second edition, updated throughout, incorporates many new references and includes new mathematical appendices.