Author: C.N.R. Rao
Publisher: Springer Science & Business Media
ISBN: 1468418750
Category : Science
Languages : en
Pages : 630
Book Description
The three natural streams of present-day chemistry are Structure, Dynamics and Synthesis and all these three elements are essential for the study of materials, particularly in the solid state. The solid state provides challenging opportunities for illustrating and applying principles of chemistry to systems of academic interest and technological importance. There are several practising solid state chemists in universities and research laboratories, but the subject has not yet become part of the formal training program in chemistry. Being one of the new frontiers of chemistry, Solid State Chemistry has a tremendous future and undoubtedly demands the active involvement of many more chemists. A Winter School in Solid State Chemistry was organized at the Indian Institute of Technology, Kanpur, to promote this area and to develop curricular material. Solid State Chemistry being lighly interdisciplinary in nature, the lecturers and participants at the Winter School had widely different backgrounds and interests. It was my great desire that the lecture material from the Winter School should become available to a larger body of students, teachers and research workers interested in the solid state and hence this volume.
Modern Aspects of Solid State Chemistry
Author: C.N.R. Rao
Publisher: Springer Science & Business Media
ISBN: 1468418750
Category : Science
Languages : en
Pages : 630
Book Description
The three natural streams of present-day chemistry are Structure, Dynamics and Synthesis and all these three elements are essential for the study of materials, particularly in the solid state. The solid state provides challenging opportunities for illustrating and applying principles of chemistry to systems of academic interest and technological importance. There are several practising solid state chemists in universities and research laboratories, but the subject has not yet become part of the formal training program in chemistry. Being one of the new frontiers of chemistry, Solid State Chemistry has a tremendous future and undoubtedly demands the active involvement of many more chemists. A Winter School in Solid State Chemistry was organized at the Indian Institute of Technology, Kanpur, to promote this area and to develop curricular material. Solid State Chemistry being lighly interdisciplinary in nature, the lecturers and participants at the Winter School had widely different backgrounds and interests. It was my great desire that the lecture material from the Winter School should become available to a larger body of students, teachers and research workers interested in the solid state and hence this volume.
Publisher: Springer Science & Business Media
ISBN: 1468418750
Category : Science
Languages : en
Pages : 630
Book Description
The three natural streams of present-day chemistry are Structure, Dynamics and Synthesis and all these three elements are essential for the study of materials, particularly in the solid state. The solid state provides challenging opportunities for illustrating and applying principles of chemistry to systems of academic interest and technological importance. There are several practising solid state chemists in universities and research laboratories, but the subject has not yet become part of the formal training program in chemistry. Being one of the new frontiers of chemistry, Solid State Chemistry has a tremendous future and undoubtedly demands the active involvement of many more chemists. A Winter School in Solid State Chemistry was organized at the Indian Institute of Technology, Kanpur, to promote this area and to develop curricular material. Solid State Chemistry being lighly interdisciplinary in nature, the lecturers and participants at the Winter School had widely different backgrounds and interests. It was my great desire that the lecture material from the Winter School should become available to a larger body of students, teachers and research workers interested in the solid state and hence this volume.
The Vitreous State
Author: Ivan S. Gutzow
Publisher: Springer Science & Business Media
ISBN: 3642346332
Category : Science
Languages : en
Pages : 566
Book Description
This book summarizes the experimental evidence and modern classical and theoretical approaches in understanding the vitreous state, from structural problems, over equilibrium and non-equilibrium thermodynamics, to statistical physics. Glasses, and especially silicate glasses, are only the best known representatives of this particular physical state of matter. Other typical representatives include organic polymer glasses, and many other easily vitrifying organic and inorganic substances, technically important materials, amidst them vitreous water and vitrified aqueous solutions, and also many metallic alloy systems. Some of these systems only form glasses under particular conditions, e.g. through ultra-rapid cooling. This book describes the properties and the formation of both every-day technical glasses and especially of such more exotic forms of vitreous matter. It is a unique source of knowledge and new ideas for materials scientists, engineers and researchers working on condensed matter. The new edition emphasizes latest experimental findings and modern theories, explaining the kinetics of glass formation, the relaxation and stabilization of glasses and their crystallization in terms of new models, derived from the framework of the thermodynamics of irreversible processes. It shows how the properties of common technical glasses, window glass, or the vitreous ice kernel of comets can be used to develop a new understanding of the existence of matter in various, unusual forms. The described theories can even find application for the description of lasers and interesting unusual processes in the universe.
Publisher: Springer Science & Business Media
ISBN: 3642346332
Category : Science
Languages : en
Pages : 566
Book Description
This book summarizes the experimental evidence and modern classical and theoretical approaches in understanding the vitreous state, from structural problems, over equilibrium and non-equilibrium thermodynamics, to statistical physics. Glasses, and especially silicate glasses, are only the best known representatives of this particular physical state of matter. Other typical representatives include organic polymer glasses, and many other easily vitrifying organic and inorganic substances, technically important materials, amidst them vitreous water and vitrified aqueous solutions, and also many metallic alloy systems. Some of these systems only form glasses under particular conditions, e.g. through ultra-rapid cooling. This book describes the properties and the formation of both every-day technical glasses and especially of such more exotic forms of vitreous matter. It is a unique source of knowledge and new ideas for materials scientists, engineers and researchers working on condensed matter. The new edition emphasizes latest experimental findings and modern theories, explaining the kinetics of glass formation, the relaxation and stabilization of glasses and their crystallization in terms of new models, derived from the framework of the thermodynamics of irreversible processes. It shows how the properties of common technical glasses, window glass, or the vitreous ice kernel of comets can be used to develop a new understanding of the existence of matter in various, unusual forms. The described theories can even find application for the description of lasers and interesting unusual processes in the universe.
The Physics of Glassy Polymers
Author: R. N. Haward
Publisher: Springer Science & Business Media
ISBN: 9401023557
Category : Science
Languages : en
Pages : 635
Book Description
This work sets out to provide an up-to-date account of the physical properties and structure of polymers in the glassy state. Properties measured above the glass transition temperature are therefore included only in so far as is necessary for the treatment of the glass transition process. This approach to the subject therefore excludes any detailed account of rubber elasticity or melt rheology or of the structure and conformation of the long chain molecule in solution, although knowledge derived from this field is assumed where required. Major emphasis is placed on structural and mechanical properties, although a number of other physical properties are included. Naturally the different authors contributing to the book write mainly from their own particular points of view and where there are several widely accepted theoretical approaches to a subject, these are sometimes provided in different chapters which will necessarily overlap to a significant extent. For example, the main theoretical presentation on the subject of glass transition is given in Chapter 1. This is supplemented by accounts of the free volume theory in Chapter 3 and in the Introduction, and a short account of the work of Gibbs and DiMarzio, also in Chapter 3. Similarly, there is material on solvent cracking in Chapters 7 and 9, though the two workers approach the subject from opposite directions. Every effort has therefore been made to encourage cross-referencing between different chapters.
Publisher: Springer Science & Business Media
ISBN: 9401023557
Category : Science
Languages : en
Pages : 635
Book Description
This work sets out to provide an up-to-date account of the physical properties and structure of polymers in the glassy state. Properties measured above the glass transition temperature are therefore included only in so far as is necessary for the treatment of the glass transition process. This approach to the subject therefore excludes any detailed account of rubber elasticity or melt rheology or of the structure and conformation of the long chain molecule in solution, although knowledge derived from this field is assumed where required. Major emphasis is placed on structural and mechanical properties, although a number of other physical properties are included. Naturally the different authors contributing to the book write mainly from their own particular points of view and where there are several widely accepted theoretical approaches to a subject, these are sometimes provided in different chapters which will necessarily overlap to a significant extent. For example, the main theoretical presentation on the subject of glass transition is given in Chapter 1. This is supplemented by accounts of the free volume theory in Chapter 3 and in the Introduction, and a short account of the work of Gibbs and DiMarzio, also in Chapter 3. Similarly, there is material on solvent cracking in Chapters 7 and 9, though the two workers approach the subject from opposite directions. Every effort has therefore been made to encourage cross-referencing between different chapters.
Glasses and the Vitreous State
Author: Jerzy Zarzycki
Publisher: Cambridge University Press
ISBN: 9780521355827
Category : Technology & Engineering
Languages : en
Pages : 548
Book Description
This book provides an up-to-date and comprehensive coverage of the properties of glasses as materials and of the vitreous state in general. The broad coverage of the book includes a study of the methods of studying the structure, glass classification, and electrical, optical, thermal and mechanical properties of glasses.
Publisher: Cambridge University Press
ISBN: 9780521355827
Category : Technology & Engineering
Languages : en
Pages : 548
Book Description
This book provides an up-to-date and comprehensive coverage of the properties of glasses as materials and of the vitreous state in general. The broad coverage of the book includes a study of the methods of studying the structure, glass classification, and electrical, optical, thermal and mechanical properties of glasses.
Introduction to Glass Science
Author: L. Pye
Publisher: Springer Science & Business Media
ISBN: 1475703287
Category : Technology & Engineering
Languages : en
Pages : 718
Book Description
Glass technologists are fascinated by glass; explora tion as well as application of glass is expanding and the influx of documentation is bewildering. There were about 200 papers on just semi conduction in glasses in 1970 and one has to scan about 200 papers a month to sense the pulse of glass science. Yet there are many in industry and education in science or engineering who require or wish to have coher ent, comprehensive and contemporary information on this exciting material "glass. " The Tutorial Symposium offered as an Introduction to Glass Science in Alfred represents an earnest attempt to ful fill this need. It has been designed to provide both broad and technical instruction for participants and readers who are not specialists. Glass is not only a material but a condition of matter: the vitreous state. The topic, there fore, is introduced by a careful consideration of the nature of glass, or the vitreous state. The universality of the vitreous state is now generally recognized: not just a few, but very many structures can be obtained without appreciable crystallization. There is no restricted family of struc tures characteristic of glass formation: as long as crys tallization is avoided, every liquid will solidify to a non crystalline sUbstance. Structural analysis in each case is now to be postulated and has become increasingly successful. The Alfred "Introduction to Glass Science" offers a repre sentative overview of methods and results.
Publisher: Springer Science & Business Media
ISBN: 1475703287
Category : Technology & Engineering
Languages : en
Pages : 718
Book Description
Glass technologists are fascinated by glass; explora tion as well as application of glass is expanding and the influx of documentation is bewildering. There were about 200 papers on just semi conduction in glasses in 1970 and one has to scan about 200 papers a month to sense the pulse of glass science. Yet there are many in industry and education in science or engineering who require or wish to have coher ent, comprehensive and contemporary information on this exciting material "glass. " The Tutorial Symposium offered as an Introduction to Glass Science in Alfred represents an earnest attempt to ful fill this need. It has been designed to provide both broad and technical instruction for participants and readers who are not specialists. Glass is not only a material but a condition of matter: the vitreous state. The topic, there fore, is introduced by a careful consideration of the nature of glass, or the vitreous state. The universality of the vitreous state is now generally recognized: not just a few, but very many structures can be obtained without appreciable crystallization. There is no restricted family of struc tures characteristic of glass formation: as long as crys tallization is avoided, every liquid will solidify to a non crystalline sUbstance. Structural analysis in each case is now to be postulated and has become increasingly successful. The Alfred "Introduction to Glass Science" offers a repre sentative overview of methods and results.
Encyclopedia of Glass Science, Technology, History, and Culture Two Volume Set
Author: Pascal Richet
Publisher: John Wiley & Sons
ISBN: 1118799399
Category : Technology & Engineering
Languages : en
Pages : 1568
Book Description
This Encyclopedia begins with an introduction summarizing itsscope and content. Glassmaking; Structure of Glass, GlassPhysics,Transport Properties, Chemistry of Glass, Glass and Light,Inorganic Glass Families, Organic Glasses, Glass and theEnvironment, Historical and Economical Aspect of Glassmaking,History of Glass, Glass and Art, and outlinepossible newdevelopments and uses as presented by the best known people in thefield (C.A. Angell, for example). Sections and chapters arearranged in a logical order to ensure overall consistency and avoiduseless repetitions. All sections are introduced by a briefintroduction and attractive illustration. Newly investigatedtopics will be addresses, with the goal of ensuring that thisEncyclopedia remains a reference work for years to come.
Publisher: John Wiley & Sons
ISBN: 1118799399
Category : Technology & Engineering
Languages : en
Pages : 1568
Book Description
This Encyclopedia begins with an introduction summarizing itsscope and content. Glassmaking; Structure of Glass, GlassPhysics,Transport Properties, Chemistry of Glass, Glass and Light,Inorganic Glass Families, Organic Glasses, Glass and theEnvironment, Historical and Economical Aspect of Glassmaking,History of Glass, Glass and Art, and outlinepossible newdevelopments and uses as presented by the best known people in thefield (C.A. Angell, for example). Sections and chapters arearranged in a logical order to ensure overall consistency and avoiduseless repetitions. All sections are introduced by a briefintroduction and attractive illustration. Newly investigatedtopics will be addresses, with the goal of ensuring that thisEncyclopedia remains a reference work for years to come.
Glassy, Amorphous and Nano-Crystalline Materials
Author: Jaroslav Šesták
Publisher: Springer Science & Business Media
ISBN: 904812882X
Category : Technology & Engineering
Languages : en
Pages : 392
Book Description
Provides a summary of non-equilibrium glassy and amorphous structures and their macro- and microscopic thermal properties. The book contains a carefully selected works of fourteen internationally recognized scientists involving the advances of the physics and chemistry of the glassy and amorphous states.
Publisher: Springer Science & Business Media
ISBN: 904812882X
Category : Technology & Engineering
Languages : en
Pages : 392
Book Description
Provides a summary of non-equilibrium glassy and amorphous structures and their macro- and microscopic thermal properties. The book contains a carefully selected works of fourteen internationally recognized scientists involving the advances of the physics and chemistry of the glassy and amorphous states.
Journal of Research of the National Bureau of Standards
Author: United States. National Bureau of Standards
Publisher:
ISBN:
Category : Chemistry
Languages : en
Pages : 646
Book Description
Publisher:
ISBN:
Category : Chemistry
Languages : en
Pages : 646
Book Description
Viscoelastic Properties of Polymers
Author: John D. Ferry
Publisher: John Wiley & Sons
ISBN: 9780471048947
Category : Technology & Engineering
Languages : en
Pages : 676
Book Description
Viscoelastic behavior reflects the combined viscous and elastic responses, under mechanical stress, of materials which are intermediate between liquids and solids in character. Polymers the basic materials of the rubber and plastic industries and important to the textile, petroleum, automobile, paper, and pharmaceutical industries as well exhibit viscoelasticity to a pronounced degree. Their viscoelastic properties determine the mechanical performance of the final products of these industries, and also the success of processing methods at intermediate stages of production. Viscoelastic Properties of Polymers examines, in detail, the effects of the many variables on which the basic viscoelastic properties depend. These include temperature, pressure, and time; polymer chemical composition, molecular weight and weight distribution, branching and crystallinity; dilution with solvents or plasticizers; and mixture with other materials to form composite systems. With guidance by molecular theory, the dependence of viscoelastic properties on these variables can be simplified by introducing certain ancillary concepts such as the fractional free volume, the monomeric friction coefficient, and the spacing between entanglement loci, to provide a qualitative understanding and in many cases a quantitative prediction of how to achieve desired results. The phenomenological theory of viscoelasticity which permits interrelation of the results of different types of experiments is presented first, with many useful approximation procedures for calculations given. A wide variety of experimental methods is then described, with critical evaluation of their applicability to polymeric materials of different consistencies and in different regions of the time scale (or, for oscillating deformations, the frequency scale). A review of the present state of molecular theory follows, so that viscoelasticity can be related to the motions of flexible polymer molecules and their entanglements and network junctions. The dependence of viscoestic properties on temperature and pressure, and its descriptions using reduced variables, are discussed in detail. Several chapters are then devoted to the dependence of viscoelastic properties on chemical composition, molecular weight, presence of diluents, and other features, for several characteristic classes of polymer materials. Finally, a few examples are given to illustrate the many potential applications of these principles to practical problems in the processing and use of rubbers, plastics, and fibers, and in the control of vibration and noise. The third edition has been brought up to date to reflect the important developments, in a decade of exceptionally active research, which have led to a wider use of polymers, and a wider recognition of the importance and range of application of viscoelastic properties. Additional data have been incorporated, and the book s chapters on dilute solutions, theory of undiluted polymers, plateau and terminal zones, cross-linked polymers, and concentrated solutions have been extensively rewritten to take into account new theories and new experimental results. Technical managers and research workers in the wide range of industries in which polymers play an important role will find that the book provides basic information for practical applications, and graduate students in chemistry and engineering will find, in its illustrations with real data and real numbers, an accessible introduction to the principles of viscoelasticity.
Publisher: John Wiley & Sons
ISBN: 9780471048947
Category : Technology & Engineering
Languages : en
Pages : 676
Book Description
Viscoelastic behavior reflects the combined viscous and elastic responses, under mechanical stress, of materials which are intermediate between liquids and solids in character. Polymers the basic materials of the rubber and plastic industries and important to the textile, petroleum, automobile, paper, and pharmaceutical industries as well exhibit viscoelasticity to a pronounced degree. Their viscoelastic properties determine the mechanical performance of the final products of these industries, and also the success of processing methods at intermediate stages of production. Viscoelastic Properties of Polymers examines, in detail, the effects of the many variables on which the basic viscoelastic properties depend. These include temperature, pressure, and time; polymer chemical composition, molecular weight and weight distribution, branching and crystallinity; dilution with solvents or plasticizers; and mixture with other materials to form composite systems. With guidance by molecular theory, the dependence of viscoelastic properties on these variables can be simplified by introducing certain ancillary concepts such as the fractional free volume, the monomeric friction coefficient, and the spacing between entanglement loci, to provide a qualitative understanding and in many cases a quantitative prediction of how to achieve desired results. The phenomenological theory of viscoelasticity which permits interrelation of the results of different types of experiments is presented first, with many useful approximation procedures for calculations given. A wide variety of experimental methods is then described, with critical evaluation of their applicability to polymeric materials of different consistencies and in different regions of the time scale (or, for oscillating deformations, the frequency scale). A review of the present state of molecular theory follows, so that viscoelasticity can be related to the motions of flexible polymer molecules and their entanglements and network junctions. The dependence of viscoestic properties on temperature and pressure, and its descriptions using reduced variables, are discussed in detail. Several chapters are then devoted to the dependence of viscoelastic properties on chemical composition, molecular weight, presence of diluents, and other features, for several characteristic classes of polymer materials. Finally, a few examples are given to illustrate the many potential applications of these principles to practical problems in the processing and use of rubbers, plastics, and fibers, and in the control of vibration and noise. The third edition has been brought up to date to reflect the important developments, in a decade of exceptionally active research, which have led to a wider use of polymers, and a wider recognition of the importance and range of application of viscoelastic properties. Additional data have been incorporated, and the book s chapters on dilute solutions, theory of undiluted polymers, plateau and terminal zones, cross-linked polymers, and concentrated solutions have been extensively rewritten to take into account new theories and new experimental results. Technical managers and research workers in the wide range of industries in which polymers play an important role will find that the book provides basic information for practical applications, and graduate students in chemistry and engineering will find, in its illustrations with real data and real numbers, an accessible introduction to the principles of viscoelasticity.
Many-body Problem, The: An Encyclopedia Of Exactly Solved Models In One Dimension (3rd Printing With Revisions And Corrections)
Author: Daniel C Mattis
Publisher: World Scientific
ISBN: 9814505579
Category : Science
Languages : en
Pages : 992
Book Description
This book differs from its predecessor, Lieb & Mattis Mathematical Physics in One Dimension, in a number of important ways. Classic discoveries which once had to be omitted owing to lack of space — such as the seminal paper by Fermi, Pasta and Ulam on lack of ergodicity of the linear chain, or Bethe's original paper on the Bethe ansatz — can now be incorporated. Many applications which did not even exist in 1966 (some of which were originally spawned by the publication of Lieb & Mattis) are newly included. Among these, this new book contains critical surveys of a number of important developments: the exact solution of the Hubbard model, the concept of spinons, the Haldane gap in magnetic spin-one chains, bosonization and fermionization, solitions and the approach to thermodynamic equilibrium, quantum statistical mechanics, localization of normal modes and eigenstates in disordered chains, and a number of other contemporary concerns.
Publisher: World Scientific
ISBN: 9814505579
Category : Science
Languages : en
Pages : 992
Book Description
This book differs from its predecessor, Lieb & Mattis Mathematical Physics in One Dimension, in a number of important ways. Classic discoveries which once had to be omitted owing to lack of space — such as the seminal paper by Fermi, Pasta and Ulam on lack of ergodicity of the linear chain, or Bethe's original paper on the Bethe ansatz — can now be incorporated. Many applications which did not even exist in 1966 (some of which were originally spawned by the publication of Lieb & Mattis) are newly included. Among these, this new book contains critical surveys of a number of important developments: the exact solution of the Hubbard model, the concept of spinons, the Haldane gap in magnetic spin-one chains, bosonization and fermionization, solitions and the approach to thermodynamic equilibrium, quantum statistical mechanics, localization of normal modes and eigenstates in disordered chains, and a number of other contemporary concerns.