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Author: Publisher: ISBN: Category : Languages : en Pages :
Book Description
Lean NOx trap catalysis has demonstrated the ability to reduce NOx emissions from lean natural gas reciprocating engines by>90%. The technology operates in a cyclic fashion where NOx is trapped on the catalyst during lean operation and released and reduced to N2 under rich exhaust conditions; the rich cleansing operation of the cycle is referred to as "regeneration" since the catalyst is reactivated for more NOx trapping. Natural gas combusted over partial oxidation catalysts in the exhaust can be used to obtain the rich exhaust conditions necessary for catalyst regeneration. Thus, the lean NOx trap technology is well suited for lean natural gas engine applications. One potential limitation of the lean NOx trap technology is sulfur poisoning. Sulfur compounds directly bond to the NOx trapping sites of the catalyst and render them ineffective; over time, the sulfur poisoning leads to degradation in overall NOx reduction performance. In order to mitigate the effects of sulfur poisoning, a process has been developed to restore catalyst activity after sulfur poisoning has occurred. The process is an aqueous-based wash process that removes the poisoned sorbate component of the catalyst. A new sorbate component is reapplied after removal of the poisoned sorbate. The process is low cost and does not involve reapplication of precious metal components of the catalyst. Experiments were conducted to investigate the feasibility of the washing process on a lean 8.3-liter natural gas engine on a dynamometer platform. The catalyst was rapidly sulfur poisoned with bottled SO2 gas; then, the catalyst sorbate was washed and reapplied and performance was re-evaluated. Results show that the sorbate reapplication process is effective at restoring lost performance due to sulfur poisoning. Specific details relative to the implementation of the process for large stationary natural gas engines will be discussed.
Author: Publisher: ISBN: Category : Languages : en Pages :
Book Description
Lean NOx trap catalysis has demonstrated the ability to reduce NOx emissions from lean natural gas reciprocating engines by>90%. The technology operates in a cyclic fashion where NOx is trapped on the catalyst during lean operation and released and reduced to N2 under rich exhaust conditions; the rich cleansing operation of the cycle is referred to as "regeneration" since the catalyst is reactivated for more NOx trapping. Natural gas combusted over partial oxidation catalysts in the exhaust can be used to obtain the rich exhaust conditions necessary for catalyst regeneration. Thus, the lean NOx trap technology is well suited for lean natural gas engine applications. One potential limitation of the lean NOx trap technology is sulfur poisoning. Sulfur compounds directly bond to the NOx trapping sites of the catalyst and render them ineffective; over time, the sulfur poisoning leads to degradation in overall NOx reduction performance. In order to mitigate the effects of sulfur poisoning, a process has been developed to restore catalyst activity after sulfur poisoning has occurred. The process is an aqueous-based wash process that removes the poisoned sorbate component of the catalyst. A new sorbate component is reapplied after removal of the poisoned sorbate. The process is low cost and does not involve reapplication of precious metal components of the catalyst. Experiments were conducted to investigate the feasibility of the washing process on a lean 8.3-liter natural gas engine on a dynamometer platform. The catalyst was rapidly sulfur poisoned with bottled SO2 gas; then, the catalyst sorbate was washed and reapplied and performance was re-evaluated. Results show that the sorbate reapplication process is effective at restoring lost performance due to sulfur poisoning. Specific details relative to the implementation of the process for large stationary natural gas engines will be discussed.
Author: W. Addy Majewski Publisher: SAE International ISBN: 1468605704 Category : Technology & Engineering Languages : en Pages : 1135
Book Description
Engineers, applied scientists, students, and individuals working to reduceemissions and advance diesel engine technology will find the secondedition of Diesel Emissions and Their Control to be an indispensablereference. Whether readers are at the outset of their learning journey orseeking to deepen their expertise, this comprehensive reference bookcaters to a wide audience.In this substantial update to the 2006 classic, the authors have expandedthe coverage of the latest emission technologies. With the industryevolving rapidly, the book ensures that readers are well-informed aboutthe most recent advances in commercial diesel engines, providing acompetitive edge in their respective fields. The second edition has alsostreamlined the content to focus on the most promising technologies.This book is rooted in the wealth of information available on DieselNet.com, where the “Technology Guide” papers offer in-depth insights. Eachchapter includes links to relevant online materials, granting readers accessto even more expertise and knowledge.The second edition is organized into six parts, providing a structuredjourney through every aspect of diesel engines and emissions control: Part I: A foundational exploration of the diesel engine, combustion, andessential subsystems. Part II: An in-depth look at emission characterization, health andenvironmental impacts, testing methods, and global regulations. Part III: A comprehensive overview of diesel fuels, covering petroleumdiesel, alternative fuels, and engine lubricants. Part IV: An exploration of engine efficiency and emission controltechnologies, from exhaust gas recirculation to engine control. Part V: The latest developments in diesel exhaust aftertreatment,encompassing catalyst technologies and particulate filters. Part VI: A historical journey through the evolution of dieselengine technology, with a focus on heavy-duty engines in the NorthAmerican market. (ISBN 9781468605693, ISBN 9781468605709, ISBN 9781468605716, DOI: 10.4271/9781468605709)
Author: Luca Lietti Publisher: Royal Society of Chemistry ISBN: 1788014758 Category : Science Languages : en Pages : 434
Book Description
Vehicle exhaust emissions, particularly from diesel cars, are considered to be a significant problem for the environment and human health. Lean NOx Trap (LNT) or NOx Storage/Reduction (NSR) technology is one of the current techniques used in the abatement of NOx from lean exhausts. Researchers are constantly searching for new inexpensive catalysts with high efficiency at low temperatures and negligible fuel penalties, to meet the challenges of this field. This book will be the first to comprehensively present the current research on this important area. Covering the technology used, from its development in the early 1990s up to the current state-of-the-art technologies and new legislation. Beginning with the fundamental aspects of the process, the discussion will cover the real application standard through to the detailed modelling of full scale catalysts. Scientists, academic and industrial researchers, engineers working in the automotive sector and technicians working on emission control will find this book an invaluable resource.
Author: Publisher: ISBN: Category : Languages : en Pages : 8
Book Description
This bench reactor study investigates the impact of gaseous sulfur on the NOx reduction activity of Cu-chabazite SCR (Cu-CHA) catalysts at SO2 concentrations representative of marine diesel engine exhaust. After two hours of 500 ppm SO2 exposure at 250 and 400 °C in the simulated diesel exhaust gases, the NOx reduction activity of the sulfated Cu-CHA SCR catalysts is severely degraded at evaluation temperatures below 250 °C; however, above 250 °C the impact of sulfur exposure is minimal. EPMA shows that sulfur is located throughout the washcoat and along the entire length of the sulfated samples. Interestingly, BET measurements reveal that the sulfated samples have a 20% decrease in surface area. Moreover, the sulfated samples show a decrease in NOx/nitrate absorption during NO exposure in a DRIFTS reactor which suggests that Cu sites in the catalyst are blocked by the presence of sulfur. SO2 exposure also results in an increase in NH3 storage capacity, possibly due to the formation of ammonium sulfate species in the sulfated samples. In all cases, lean thermal treatments as low as 500 °C reverse the effects of sulfur exposure and restore the NOx reduction activity of the Cu-CHA catalyst to that of the fresh condition.
Author: Publisher: ISBN: Category : Languages : en Pages :
Book Description
The removal of SO2 from exhaust gas streams is a crucial step for a commercial application of NOx Storage-Reduction Catalyst in automobile industry. For SOx-storage Metal organic framework materials (MOF) complex nanostructured oxides were prepared, characterised and evaluated. BaCl2 impregnated MOF materials and nanostructured complex metal oxides showed the most promising storage properties. The reaction at the surface and the transport in the bulk phase was investigated by in situ IR and X-rayabsorptionspectroscopy applying modern chemometric methods. The best materials were able to bind SOx strongly on the surface with an additional fast transport into the bulk phase. Noblemetalfree sorbents showed especially under cycling oxidizing and reducing conditions a strongly enhanced performance compared to the Pt containing samples.
Author: Karen McCombie Publisher: ISBN: 9781407117867 Category : Ally (Fictitious character : McCombie) Languages : en Pages : 208
Book Description
Ally knows her super-efficient big sis Linn finds their chaotic family a bit ... exasperating. But when Linn falls for Q, the tearaway lead singer in a local band, all her sensible ways go out of the window. Everyone else can see that Q's a creep, but does Ally have the courage to burst Linn's heart-shaped bubble?
Author: Karl Laden Publisher: CRC Press ISBN: 1482224054 Category : Medical Languages : en Pages : 421
Book Description
Provides a review of the most recent advances in the science and technology of controlling odour and wetness. This edition includes two new chapters on antiperspirant and deodorant formulations; two new chapters on relevant patent technologies of recent years; discussions on the chemistry of aluminium/zirconium antiperspirant salts; and a modernize
Author: Robin D. Rogers Publisher: Amer Chemical Society ISBN: 9780841238565 Category : Science Languages : en Pages : 599
Book Description
Annotation FollowingIonic Liquids: Industrial Applications to Green Chemistry, SS #818, by the same editors, this book focuses on exciting new developments in ionic liquids.
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Author: W. Addy Majewski
Author: Luca Lietti
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Author: Karen McCombie
Author: Karl Laden
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Author: Robert L. Rietschel
Author: Robin D. Rogers