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Author: D. Gatteschi Publisher: Springer Science & Business Media ISBN: 9401132542 Category : Science Languages : en Pages : 413
Book Description
One of the major challenges of science in the last few years of the second millennium is learning how to design materials which can fulfill specific tasks. Ambitious as it may be, the possibilities of success are not ne~li~ble provided that all the different expertises merge to overcome the limits of eXIsting disciplines and forming new paradigms science. The NATO Advanced Research Workshop on "Magnetic Molecular Materials" was organized with the above considerations in mind in order to determine which are the most appropriate synthetic strategies, experimental techniques of investigation, and theoretical models which are needed in order to develop new classes of magnetic materials which are based on molecules rather than on metallic or ionic lattices. Why molecules? The answer may be obvious: molecular chemistry in principle fine can tune the structures and the properties of complex aggregates, and nature already provides a large number of molecular aggregates which can perform the most disparate functions. The contributions collected in this book provide a rather complete view of the current research accomplishments of magnetic molecular materials. There are several different synthetic approaches which are followed ranging from purely organic to inorganic materials. Some encouraging successes have already been achieved, even if the critical temperatures below which magnetic order is observed still are in the range requiring liquid helium.
Author: D. Gatteschi Publisher: Springer Science & Business Media ISBN: 9401132542 Category : Science Languages : en Pages : 413
Book Description
One of the major challenges of science in the last few years of the second millennium is learning how to design materials which can fulfill specific tasks. Ambitious as it may be, the possibilities of success are not ne~li~ble provided that all the different expertises merge to overcome the limits of eXIsting disciplines and forming new paradigms science. The NATO Advanced Research Workshop on "Magnetic Molecular Materials" was organized with the above considerations in mind in order to determine which are the most appropriate synthetic strategies, experimental techniques of investigation, and theoretical models which are needed in order to develop new classes of magnetic materials which are based on molecules rather than on metallic or ionic lattices. Why molecules? The answer may be obvious: molecular chemistry in principle fine can tune the structures and the properties of complex aggregates, and nature already provides a large number of molecular aggregates which can perform the most disparate functions. The contributions collected in this book provide a rather complete view of the current research accomplishments of magnetic molecular materials. There are several different synthetic approaches which are followed ranging from purely organic to inorganic materials. Some encouraging successes have already been achieved, even if the critical temperatures below which magnetic order is observed still are in the range requiring liquid helium.
Author: Coen de Graaf Publisher: Springer ISBN: 3319229516 Category : Science Languages : en Pages : 253
Book Description
This textbook is the second volume in the Theoretical Chemistry and Computational Modeling series and aims to explain the theoretical basis of magnetic interactions at a level that will be useful for master students in physical, inorganic and organic chemistry. The book gives a treatment of magnetic interactions in terms of the phenomenological spin Hamiltonians that have been such powerful tools for chemistry and physics in the past half century, starting from the simple Heisenberg and Ising Hamiltonians and ending with Hamiltonians that include biquadratic, cyclic or anisotropic exchange. On the other hand, it also explains how quantum chemical methods, reaching from simple mean field methods to accurate models that include the effects of electron correlation and spin-orbit coupling, can help to understand the magnetic properties. Connecting the two perspectives is an essential aspect of the book, since it leads to a deeper understanding of the relation between physical phenomena and basic properties. It also makes clear that in many cases one can derive magnetic coupling parameters not only from experiment, but also from accurate ab initio calculations. The book starts with introducing a selection of basic concepts and tools. Throughout the book the text is interlarded with exercises, stimulating the students to not only read but also verify the assertions and perform (parts of) the derivations by themselves. In addition, each chapter ends with a number of problems that can be used to check whether the material has been understood.
Author: Barbara Sieklucka Publisher: John Wiley & Sons ISBN: 3527339531 Category : Science Languages : en Pages : 508
Book Description
A comprehensive overview of this rapidly expanding interdisciplinary field of research. After a short introduction to the basics of magnetism and molecular magnetism, the text goes on to cover specific properties of molecular magnetic materials as well as their current and future applications. Design strategies for acquiring molecular magnetic materials with desired physical properties are discussed, as are such multifunctional materials as high Tc magnets, chiral and luminescent magnets, magnetic sponges as well as photo- and piezo-switching magnets. The result is an excellent resource for materials scientists, chemists, physicists and crystal engineers either entering or already working in the field.
Author: D. Arcon Publisher: Springer Science & Business Media ISBN: 3540416803 Category : Medical Languages : en Pages : 218
Book Description
Celebrating Volume 100: Thirty years ago Springer-Verlag together with a distinguished Board of Editors started the series Structure and Bonding. Initially the series was set up to publish reviews from different fields of modern inorganic chemistry, chemical physics and biochemistry, where the general subject of chemical bonding involves a metal and a small number of associated atoms. Three years ago the aims of the series was refined to span the entire periodic table and address structure and bonding issues wherever they may be relevant. Not only the traditional areas of chemical bonding will be dealt with but also nanostructres, molecular electronics, supramolecular structure, surfaces and clusters. With these aims in mind it is noteworthy that Volume 100 effectively reinforces and illustrates these ideals and is titled Pi-Electron Magnetism from Molecules to Magnetic Materials.
Author: Matteo Atzori Publisher: CRC Press ISBN: 1351233645 Category : Science Languages : en Pages : 351
Book Description
The field of molecular materials represents an exciting playground for the design, tailoring, and combination of chemical building blocks as carriers of physical properties and aims at the understanding and development of novel functional molecular devices. Within this extraordinarily widespread framework, the realization of materials with the desired functionalities can only be achieved through a rational design strategy based on a solid understanding of the chemical and physical features of each constituting building block. This book provides a general overview of molecular materials, discussing their key features in a simple and organic way by focusing more on basic concepts rather than on specialized descriptions, in order to supply the non-expert reader with the immediate fundamental tools and hints to understand and develop research in this field. With this view, it is a step-by-step guide toward the preparation of functional molecular materials, where the knowledge and understanding so far attained by the scientific community through the investigation of significant archetypical examples is deconstructed down to the fundamental basis and then presented in reverse, from the base to the top.
Author: Marc Fourmigué Publisher: Springer Science & Business Media ISBN: 3642004083 Category : Science Languages : en Pages : 199
Book Description
For several years, the two parallel worlds of Molecular Conductors in one hand and Molecular Magnetism in the other have grown side by side, the former essentially based on radical organic molecules, the latter essentially based on the high spin properties of metal complexes. Over the last few years however, organometallic derivatives have started to play an increasingly important role in both worlds, and have in many ways contributed to open several passages between these two worlds. This volume recognizes this important emerging evolution of both research areas. It is not intended to give a comprehensive view of all possible organometallic materials, and polymers for example were not considered here. Rather we present a selection of the most recent research topics where organometallic derivatives were shown to play a crucial role in the setting of conducting and/or magnetic properties in crystalline materials. First, the role of organometallic anions in tet- thiafulvalenium-based molecular conductors is highlighted by Schlueter, while Kubo and Kato describe very recent ortho-metalated chelating ligands appended to the TTF core and their conducting salts. The combination of conducting and magnetic properties and the search for p–d interactions are analyzed in two comp- mentary contributions by Myazaki and Ouahab, while Valade focuses on the only class of metal bis(dithiolene) complexes to give rise to superconductive molecular materials, in association with organic as well as organometallic cations.
Author: Cristiano Benelli Publisher: John Wiley & Sons ISBN: 3527690565 Category : Science Languages : en Pages : 520
Book Description
This first introduction to the rapidly growing field of molecular magnetism is written with Masters and PhD students in mind, while postdocs and other newcomers will also find it an extremely useful guide. Adopting a clear didactic approach, the authors cover the fundamental concepts, providing many examples and give an overview of the most important techniques and key applications. Although the focus is one lanthanide ions, thus reflecting the current research in the field, the principles and the methods equally apply to other systems. The result is an excellent textbook from both a scientific and pedagogic point of view.
Author: Joel S. Miller Publisher: John Wiley & Sons ISBN: 3527604502 Category : Science Languages : en Pages : 395
Book Description
Combining the contemporary knowledge from widely scattered sources, this is a much-needed and comprehensive overview of the field. In maintaining a balance between theory and experiment, the book guides both advanced students and specialists to this research area. Topical reviews written by the foremost scientists explain recent trends and advances, focusing on the correlations between electronic structure and magnetic properties. The book spans recent trends in magnetism for molecules -- as well as inorganic-based materials, with an emphasis on new phenomena being explored from both experimental and theoretical viewpoints with the aim of understanding magnetism on the atomic scale. The volume helps readers evaluate their own experimental observations and serves as a basis for the design of new magnetic materials. Topics covered include: * Metallocenium Salts of Radical Anion Bis-(dichalcogenate) metalates * Chiral Molecule-Based Magnets * Cooperative Magnetic Behavior in Metal-Dicyanamide Complexes * Lanthanide Ions in Molecular Exchange Coupled Systems * Monte Carlo Simulation * Metallocene-Based Magnets * Magnetic Nanoporous Molecular Materials A unique reference work, indispensable for everyone concerned with the phenomena of magnetism.
Author: E. Coronado Publisher: Springer Science & Business Media ISBN: 9401723192 Category : Science Languages : en Pages : 595
Book Description
Molecular Magnetism: From Molecular Assemblies to the Devices reviews the state of the art in the area. It is organized in two parts, the first of which introduces the basic concepts, theories and physical techniques required for the investigation of the magnetic molecular materials, comparing them with those used in the study of classical magnetic materials. Here the reader will find: (i) a detailed discussion of the electronic processes involved in the magnetic interaction mechanisms of molecular systems, including electron delocalization and spin polarization effects; (ii) a presentation of the available theoretical models based on spin and Hubbard Hamiltonians; and (iii) a description of the specific physical investigative techniques used to characterize the materials. The second part presents the different classes of existing magnetic molecular materials, focusing on the possible synthetic strategies developed to date to assemble the molecular building blocks ranging from purely organic to inorganic materials, as well as on their physical properties and potential applications. These materials comprise inorganic and organic ferro- and ferrimagnets, high nuclearity organic molecules and magnetic and metallic clusters, spin crossover systems, charge transfer salts (including fulleride salts and organic conductors and superconductors), and organized soft media (magnetic liquid crystals and Langmuir-Blodgett films).
Author: Gerald F. Dionne Publisher: Springer Science & Business Media ISBN: 1441900543 Category : Technology & Engineering Languages : en Pages : 474
Book Description
Magnetic Oxides offers a cohesive up-to-date introduction to magnetism in oxides. Emphasizing the physics and chemistry of local molecular interactions essential to the magnetic design of small structures and thin films, this volume provides a detailed view of the building blocks for new magnetic oxide materials already advancing research and development of nano-scale technologies. Clearly written in a well-organized structure, readers will find a detailed description of the properties of magnetic oxides through the prism of local interactions as an alternative to collective electron concepts that are more applicable to metals and semiconductors. Researchers will find Magnetic Oxides a valuable reference.
Author: D. Gatteschi
Author: D. Gatteschi
Author: Coen de Graaf
Author: Barbara Sieklucka
Author: D. Arcon
Author: Matteo Atzori
Author: Marc Fourmigué
Author: Cristiano Benelli
Author: Joel S. Miller
Author: E. Coronado
Author: Gerald F. Dionne