Author: V. Bortolani
Publisher: Springer Science & Business Media
ISBN: 1468487779
Category : Science
Languages : en
Pages : 693
Book Description
There is considerable interest, both fundamental and technological, in the way atoms and molecules interact with solid surfaces. Thus the description of heterogeneous catalysis and other surface reactions requires a detailed understand ing of molecule-surface interactions. The primary aim of this volume is to provide fairly broad coverage of atoms and molecules in interaction with a variety of solid surfaces at a level suitable for graduate students and research workers in condensed matter physics, chemical physics, and materials science. The book is intended for experimental workers with interests in basic theory and concepts and had its origins in a Spring College held at the International Centre for Theoretical Physics, Miramare, Trieste. Valuable background reading can be found in the graduate-Ievel introduction to the physics of solid surfaces by ZangwilI(1) and in the earlier works by Garcia Moliner and F1ores(2) and Somorjai.(3) For specifically molecule-surface interac tions, additional background can be found in Rhodin and Ertl(4) and March.(S) V. Bortolani N. H. March M. P. Tosi References 1. A. Zangwill, Physics at Surfaces, Cambridge University Press, Cambridge (1988). 2. F. Garcia-Moliner and F. Flores, Introduction to the Theory of Solid Surfaces, Cambridge University Press, Cambridge (1979). 3. G. A. Somorjai, Chemistry in Two Dimensions: Surfaces, Cornell University Press, Ithaca, New York (1981). 4. T. N. Rhodin and G. Erd, The Nature of the Surface Chemical Bond, North-Holland, Amsterdam (1979). 5. N. H. March, Chemical Bonds outside Metal Surfaces, Plenum Press, New York (1986).
Interaction of Atoms and Molecules with Solid Surfaces
Research in Progress
Research in Progress
Author: United States. Army Research Office
Publisher:
ISBN:
Category : Military research
Languages : en
Pages : 316
Book Description
Vols. for 1977- consist of two parts: Chemistry, biological sciences, engineering sciences, metallurgy and materials science (issued in the spring); and Physics, electronics, mathematics, geosciences (issued in the fall).
Publisher:
ISBN:
Category : Military research
Languages : en
Pages : 316
Book Description
Vols. for 1977- consist of two parts: Chemistry, biological sciences, engineering sciences, metallurgy and materials science (issued in the spring); and Physics, electronics, mathematics, geosciences (issued in the fall).
Steric Effects in the Chemisorption of Vibrationally Excited Methane on Nickel
Author: Bruce L. Yoder
Publisher: Springer Science & Business Media
ISBN: 3642276784
Category : Science
Languages : en
Pages : 185
Book Description
Bruce Yoder’s thesis outlines his investigation of the dissociative chemisorption of methane (CH4) on a nickel single crystal. In this work Bruce uses a molecular beam and infrared laser techniques to prepare methane in excited rovibrational states. The excited methane molecules are aligned relative to the target nickel surface. Bruce describes the discovery and exploration of a previously unknown steric effect in the dissociation reaction between a vibrationally excited methane molecule and a nickel crystal. From these studies we see that methane molecules are up to twice as reactive when the vibration is aligned parallel rather than perpendicular to the surface. This discovery will help guide the development of detailed predictive models of methane chemisorption, which in turn may lead to better catalysts for the synthesis of several industrially relevant chemicals, including hydrogen fuel from natural gas.
Publisher: Springer Science & Business Media
ISBN: 3642276784
Category : Science
Languages : en
Pages : 185
Book Description
Bruce Yoder’s thesis outlines his investigation of the dissociative chemisorption of methane (CH4) on a nickel single crystal. In this work Bruce uses a molecular beam and infrared laser techniques to prepare methane in excited rovibrational states. The excited methane molecules are aligned relative to the target nickel surface. Bruce describes the discovery and exploration of a previously unknown steric effect in the dissociation reaction between a vibrationally excited methane molecule and a nickel crystal. From these studies we see that methane molecules are up to twice as reactive when the vibration is aligned parallel rather than perpendicular to the surface. This discovery will help guide the development of detailed predictive models of methane chemisorption, which in turn may lead to better catalysts for the synthesis of several industrially relevant chemicals, including hydrogen fuel from natural gas.
Molecule Surface Interactions, Volume 76
Author: K. P. Lawley
Publisher: John Wiley & Sons
ISBN: 0470141867
Category : Science
Languages : en
Pages : 398
Book Description
This text is the first of a two-volume work on molecule surface interactions addressing topics in chemical physics, surface science, physical chemistry, materials science, and electronics and semiconductor manufacture. As with the other titles in the Advances in Chemical Physics series, the chapters are written by an international group of contributors and cover a wide range of important issues in the field.
Publisher: John Wiley & Sons
ISBN: 0470141867
Category : Science
Languages : en
Pages : 398
Book Description
This text is the first of a two-volume work on molecule surface interactions addressing topics in chemical physics, surface science, physical chemistry, materials science, and electronics and semiconductor manufacture. As with the other titles in the Advances in Chemical Physics series, the chapters are written by an international group of contributors and cover a wide range of important issues in the field.
Elementary Physicochemical Processes on Solid Surfaces
Author: V.P. Zhdanov
Publisher: Springer Science & Business Media
ISBN: 148992373X
Category : Science
Languages : en
Pages : 324
Book Description
vi industrial process or a class of catalysts forms the basis of other books, with information on: fundamental science of the topic, the use of the pro cess or catalysts, and engineering aspects. Single topics in catalysis are also treated in the series, with books giving the theory of the underlying science, and relating it to catalytic practice. We believe that this approach is giving a collection of volumes that is of value to both academic and industrial workers. The series editors welcome comments on the series and suggestions of topics for future volumes. Martyn Twigg Michael Spencer Billingham and Cardiff Contents Introduction . . . . . . . . . . . . . . . . . . . . . . . . . . .. . . . 1 . . . . . . . . Chapter 1. Vibrational Relaxation of Adsorbed Particles . . . .. . 5 1.1. General Approach to Describing Vibrational Relaxation ..... 5 1.2. Phonon Mechanism of Relaxation .................... 8 1.2.1. Relationship between the Simple Perturbation Theory and the Adiabatic Approximation .. . . . . . . . . . .. . . 9 . 1.2.2. One-Mode Approximation .................. . .. 11 1.2.3. Relaxation Caused by Correlation Potential Proportional to Displacement of Adsorbed Particle from Equilibrium ........................... 12 1.2.4. Relaxation Caused by Correlation Potential Proportional to Displacement of Surface Atom from Equilibrium ........................... 14 1.2.5. Results and Discussion ....................... 15 1.3. Vibrational Relaxation via Interaction with Conduction Electrons . . . . . . . . . . . . . . . . . . . . . . . . . .. . . 18 . . . . . . . . . 1.3.1. Dipole Approximation ......... '.' . . . . . . . . .. . . 18 .
Publisher: Springer Science & Business Media
ISBN: 148992373X
Category : Science
Languages : en
Pages : 324
Book Description
vi industrial process or a class of catalysts forms the basis of other books, with information on: fundamental science of the topic, the use of the pro cess or catalysts, and engineering aspects. Single topics in catalysis are also treated in the series, with books giving the theory of the underlying science, and relating it to catalytic practice. We believe that this approach is giving a collection of volumes that is of value to both academic and industrial workers. The series editors welcome comments on the series and suggestions of topics for future volumes. Martyn Twigg Michael Spencer Billingham and Cardiff Contents Introduction . . . . . . . . . . . . . . . . . . . . . . . . . . .. . . . 1 . . . . . . . . Chapter 1. Vibrational Relaxation of Adsorbed Particles . . . .. . 5 1.1. General Approach to Describing Vibrational Relaxation ..... 5 1.2. Phonon Mechanism of Relaxation .................... 8 1.2.1. Relationship between the Simple Perturbation Theory and the Adiabatic Approximation .. . . . . . . . . . .. . . 9 . 1.2.2. One-Mode Approximation .................. . .. 11 1.2.3. Relaxation Caused by Correlation Potential Proportional to Displacement of Adsorbed Particle from Equilibrium ........................... 12 1.2.4. Relaxation Caused by Correlation Potential Proportional to Displacement of Surface Atom from Equilibrium ........................... 14 1.2.5. Results and Discussion ....................... 15 1.3. Vibrational Relaxation via Interaction with Conduction Electrons . . . . . . . . . . . . . . . . . . . . . . . . . .. . . 18 . . . . . . . . . 1.3.1. Dipole Approximation ......... '.' . . . . . . . . .. . . 18 .
Scientific and Technical Aerospace Reports
Reactions at Solid Surfaces
Author: Gerhard Ertl
Publisher: John Wiley & Sons
ISBN: 9780470535288
Category : Science
Languages : en
Pages : 150
Book Description
Expanding on the ideas first presented in Gerhard Ertl's acclaimed Baker Lectures at Cornell University, Reactions at Solid Surfaces comprises an authoritative, self-contained, book-length introduction to surface reactions for both professional chemists and students alike. Outlining our present understanding of the fundamental processes underlying reactions at solid surfaces, the book provides the reader with a complete view of how chemistry works at surfaces, and how to understand and probe the dynamics of surface reactions. Comparing traditional surface probes with more modern ones, and bringing together various disciplines in a cohesive manner, Gerhard Ertl's Reactions at Solid Surfaces serves well as a primary text for graduate students in introductory surface science or chemistry, as well as a self-teaching resource for professionals in surface science, chemical engineering, or nanoscience.
Publisher: John Wiley & Sons
ISBN: 9780470535288
Category : Science
Languages : en
Pages : 150
Book Description
Expanding on the ideas first presented in Gerhard Ertl's acclaimed Baker Lectures at Cornell University, Reactions at Solid Surfaces comprises an authoritative, self-contained, book-length introduction to surface reactions for both professional chemists and students alike. Outlining our present understanding of the fundamental processes underlying reactions at solid surfaces, the book provides the reader with a complete view of how chemistry works at surfaces, and how to understand and probe the dynamics of surface reactions. Comparing traditional surface probes with more modern ones, and bringing together various disciplines in a cohesive manner, Gerhard Ertl's Reactions at Solid Surfaces serves well as a primary text for graduate students in introductory surface science or chemistry, as well as a self-teaching resource for professionals in surface science, chemical engineering, or nanoscience.
Charged Particle and Photon Interactions with Matter
Author: A. Mozumder
Publisher: CRC Press
ISBN: 9780203913284
Category : Science
Languages : en
Pages : 888
Book Description
Charged Particle and Photon Interactions with Matter offers in-depth perspectives on phenomena of ionization and excitation induced by charged particle and photon interactions with matter in vivo and in vitro. This reference probes concepts not only in radiation and photochemistry, but also in radiation physics, radiation biochemistry, and radiatio
Publisher: CRC Press
ISBN: 9780203913284
Category : Science
Languages : en
Pages : 888
Book Description
Charged Particle and Photon Interactions with Matter offers in-depth perspectives on phenomena of ionization and excitation induced by charged particle and photon interactions with matter in vivo and in vitro. This reference probes concepts not only in radiation and photochemistry, but also in radiation physics, radiation biochemistry, and radiatio
Current Trends of Surface Science and Catalysis
Author: Jeong Young Park
Publisher: Springer Science & Business Media
ISBN: 1461487420
Category : Science
Languages : en
Pages : 265
Book Description
This unique book covers the latest surface science studies on model catalysts, including single crystals, non-colloidal nanocatalysts, and nanoparticles in various forms with the control of size, shape and composition. This book addresses the issue of bridging “materials and pressure gaps” and also discusses the important issue of metal-oxide interface and hot electron flows in heterogeneous catalysis. The current development of in-situ surface techniques that is relevant to bridging “pressure gaps” is also highlighted.
Publisher: Springer Science & Business Media
ISBN: 1461487420
Category : Science
Languages : en
Pages : 265
Book Description
This unique book covers the latest surface science studies on model catalysts, including single crystals, non-colloidal nanocatalysts, and nanoparticles in various forms with the control of size, shape and composition. This book addresses the issue of bridging “materials and pressure gaps” and also discusses the important issue of metal-oxide interface and hot electron flows in heterogeneous catalysis. The current development of in-situ surface techniques that is relevant to bridging “pressure gaps” is also highlighted.