Catalysis by Polymer-Immobilized Metal Complexes PDF Download

Author: Anatoly D. Pomogailo
Publisher: CRC Press
ISBN: 1000124711
Category : Science
Languages : en
Pages : 424

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Book Description
Deals with a new and promising field developed during the last two decades on the boundary between homogeneous and heterogeneous catalysis. This book presents general information on catalysis for a wide range of organic reactions, e.g., hydrogenation and oxidation reactions, and polymerization transformations. Special attention is paid to electro- and photochemical stimulation of catalytic processes in the presence of immobilized metal complexes. Other topics covered are the quantitative data on the comparison of catalyses by mobile and immobilized metal complexes; main factors affecting the activity of these catalytic systems and methods of optimizing their control; and specific problems of catalysis by fixed complexes (e.g., ligand exchange and electron transfer in metal polymer systems, macromolecular effects and polyfunctional catalysis).

Author: Eishun Tsuchida
Publisher: John Wiley & Sons
ISBN: 9783527301355
Category : Science
Languages : en
Pages : 304

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Book Description
The IUPAC 8th International Symposium on Macromolecule-Metal Complexes (MMC-8 Tokyo) was held at the International Conference Center of Waseda University, Tokyo in September 1999. Topic areas presented included several basic and applied topics in the field of advanced MMC such as preparation, characterization and fundamental aspects, macromolecules for advanced technologies including the sub-topics of electron- and ion conductors, separation, adsorption, transport of gas molecules, electronic-, magnetic-, photonic properties, catalysis and photocatalysis, liquid crystals, and biological-, medical- and environmental use.

Author: E. Gaigneaux
Publisher: Elsevier
ISBN: 0080540740
Category : Technology & Engineering
Languages : en
Pages : 1150

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Book Description
It has become a tradition that every four years, the Université Catholique de Louvain and the Katholieke Universiteit Leuven jointly organize a symposium devoted to the scientific bases for the preparation of heterogeneous catalysts. These meetings bring together researchers from academia and industry and offer a forum for discussions on the chemistry involved in the preparation of industrial heterogeneous catalysts. This volume containing the Proceedings of the 8th International Symposium on Scientific Bases for the Preparation of Heterogeneous Catalysts consists of papers summarizing most of the 139 oral communications and posters selected by the international scientific committee, composed of 27 experts in the field of catalyst preparation, holding an industrial or academia appointment.The contributions focus on the aspects of catalyst preparation. The main topics are: new approaches in catalyst preparation; advanced preparations of nanoporous and mesoporous catalysts; catalysts preparation for special performances and purposes; catalysts for environmental purposes; and molecular catalysis. Emphasis is put on the role that catalysis can play as an essential element of sustainable development.

Author: Walter Kaminsky
Publisher: Springer Science & Business Media
ISBN: 3642832768
Category : Science
Languages : en
Pages : 443

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Book Description
More than 30 years after the discovery of transition metals and organometal lics as catalysts for olefin polymerization these catalysts did not have lost their fascination. Since 1953 when Karl Ziegler has discovered the catalytic polymerization of ethylene leading to plastically formable polymers which are mechanically stable up to temperatures of about 100°C, synthetic polymers and rubbers have made their way right into private houses. This discovery has been a main impetus for the fast growing production of plastics. The stereoselective poly merization of propylene and other long-chain a-olefins first detected by Giulio Natta leads to an even broadened field of applications. Another enforcing factor were the developments of Standard Oil of Indiana and Phillipps Petroleum Company who engaged in the polymerization of a-olefins supported molybdenum, cobalt and later on chromium catalysts which clearly indicates the wide variety of suitable systems. This kind of research acknowledged merit when in 1963 the Nobel prize of chemistry was awarded to Ziegler and Natta. Although to a great extent there is a technical application for these catalysts, up to now the nature of the active centres and many reaction mechanisms are not completely known.

Author: Andreas Kirschning
Publisher: Springer Science & Business Media
ISBN: 9783540209157
Category : Science
Languages : en
Pages : 354

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Book Description
R. Haag, S. Roller: Polymeric Supports for the Immobilisation of Catalysts .- J. Horn, F. Michalek, C.C. Tzschucke, W. Bannwarth: Non-Covalently Solid-Phase Bound Catalysts for Organic Synthesis .- Y. Uozumi: Recent Progress in Polymeric Palladium Catalysts for Organic Synthesis .- D.E. Bergbreiter, J. Li: Applications of Catalysts on Soluble Supports .- B. Desai, C.O. Kappe: Microwave-Assisted Synthesis Involving Immobilized Catalysts .- A. Kirschning, G. Jas: Applications of Immobilized Catalysts in Continuous Flow Processes .- N. End, K.-U. Schöning: Immobilized Catalysts in Industrial Research and Application .- N. End, K.-U. Schöning: Immobilized Biocatalysts in Industrial Research and Production

Author: Dieter Wöhrle
Publisher: Wiley-VCH
ISBN:
Category : Science
Languages : en
Pages : 700

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Book Description
Metals and metal complexes can form compounds with organic macromolecules that show amazing properties. As is so often the case, nature leads by example. Synthetically produced model compounds, such as phthalocyanines, porphyrines or metalloproteins, as well as metallorganic polymers have aroused much interest in materials science. Their special magnetic, electrochemical and photochemical properties open up new perspectives in microelectronics and sensors. This compact manual is aimed at all organic, inorganic, polymer and physical chemists as well as materials scientists looking for competent and detailed information on the current state of this interdisciplinary area of research. It covers all questions relating to the targeted design of metallic macromolecules, from proven synthesis methods right up to the latest strategies. It also treats major progress in the determination of their structures, the physical-chemical properties of promising compounds and their potential in microelectronics and sensors. Furthermore, the most important methods of synthesis and investigation are presented in detail in an experimental section, while a comprehensive collection of pertinent original literature round s off this unique reference on all matters relating to macromolecular metal complexes.

Author: Kalle Levon
Publisher: John Wiley & Sons
ISBN: 9783527304769
Category : Science
Languages : en
Pages : 206

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Book Description
The 9th IUPAC International Symposium on Macromolecule–Metal Complexes (MMC–9) was held at the Polytechnic University in Brooklyn, NY ; August 19–23,2001. The topics addressed included: – macromolecule–metal complexes in "green Chemistry" – polyelectrolytes and polymer batteries – electronic, magnetic and optical properties of macromolecule–metal complexes – biorelated complexes – physical properties The role of metal ions, complexes and clusters inmacromolecular systems was discussed wherein the polymer systems were either natural or synthetic (organic or inorganic). Plenary and selected lectures are presented in this volume of Macromolecular Symposia. This text is intended for scientists, engineers and other technical personnel who seek a current assessment of the rapidly growing field of macromolecule–metal complexes.

Author: Francesco Ciardelli
Publisher: Springer Science & Business Media
ISBN: 3642609864
Category : Technology & Engineering
Languages : en
Pages : 333

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Book Description
The first concise overview on the topic, spanning the spectrum from fundamentals to new application areas. The synthesis, kinetics and thermodynamics of these complexes are covered in detail, while much emphasis is placed on special properties such as gas transport, charge transport, catalysis and light-induced processes. Furthermore, the authors treat the actual working areas for new application methods. In all, a very helpful tool for polymer and materials scientists, as well as organic and physical chemists working in these fields.

Author: P.L. Soni
Publisher: CRC Press
ISBN: 1000404137
Category : Science
Languages : en
Pages : 403

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Book Description
This book covers all important nomenclature, theories of bonding and stereochemistry of coordination complexes. The authors have made an effort to inscribe the ideas knowledge, clearly and in an interesting way to benefit the readers. The complexities of Molecular Orbital theory have been explained in a very simple and easy manner. It also deals with transition and inner transition metals. Conceptually, all transition and inner transition elements form complexes which have definite geometry and show interesting properties. General and specific methods of preparation, physical and chemical properties of each element has been discussed at length. Group wise study of elements in d-block series have been explained. Important compounds, complexes and organometallic compounds of metals in different oxidation states have been given explicitly. Note: T&F does not sell or distribute the Hardback in India, Pakistan, Nepal, Bhutan, Bangladesh and Sri Lanka.

Author: Alaa S. Abd-El-Aziz
Publisher: John Wiley & Sons
ISBN: 0471773255
Category : Technology & Engineering
Languages : en
Pages : 252

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Book Description
This series provides a useful, applications-oriented forum for the next generation of macromolecules and materials. This volume, seventh in the series, covers nanoscale interactions of metal-containing polymers. Example chapters include: * Nanoscale Clusters and Molecular Orbital Interactions in Macromolecular-Metal Complexes * Metal Oxide Clusters as Building Blocks for Inorganic-Organic Hybrid Polymers