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Author: Publisher: Springer Science & Business Media ISBN: 3662073749 Category : Science Languages : en Pages : 530
Book Description
The present volume describes all organogallium compounds, i.e., compounds containing at least one gallium-carbon bond. It covers the literature completely.to the end of 1984 and includes many references to the literature up to the end of 1985. The organic chemistry of gallium is largely dominated by compounds of the types GaR3 (Chapter 1), GaR X _ (Chapters 2 to 12), and M[GaRnX4_nl (M = cation, Chapter 13), where X n 3 n stands for a non-carbon atom or any organic or organometallic group bonded to gallium through a non-carbon atom. The arrangement of GaR X - and M[GaRnX"_nlcompounds by n 3 n the kind of Ga-X bond is evident from the table of contents on pp. XI to XIV. The extensive use of pyrazolyl-containing organogallium anions as polydentate donor ligands in transition metal compounds resulted in a particularly voluminous chapter on anions with Ga-N bonds (13.6). The volume is concluded by a few low-valence organogallium compounds (Chapter 14) that (I) atom and an aromatic ligand in an TJe fashion. exhibit bonding interaction between a gallium Due to a free coordination site at the Ga atom, neutral compounds form many adducts with Lewis bases (symbol D). These adducts are described along with the parent substances either in a subsection of the respective chapter or in a common table at the end of the table.
Author: Publisher: Springer Science & Business Media ISBN: 3662073749 Category : Science Languages : en Pages : 530
Book Description
The present volume describes all organogallium compounds, i.e., compounds containing at least one gallium-carbon bond. It covers the literature completely.to the end of 1984 and includes many references to the literature up to the end of 1985. The organic chemistry of gallium is largely dominated by compounds of the types GaR3 (Chapter 1), GaR X _ (Chapters 2 to 12), and M[GaRnX4_nl (M = cation, Chapter 13), where X n 3 n stands for a non-carbon atom or any organic or organometallic group bonded to gallium through a non-carbon atom. The arrangement of GaR X - and M[GaRnX"_nlcompounds by n 3 n the kind of Ga-X bond is evident from the table of contents on pp. XI to XIV. The extensive use of pyrazolyl-containing organogallium anions as polydentate donor ligands in transition metal compounds resulted in a particularly voluminous chapter on anions with Ga-N bonds (13.6). The volume is concluded by a few low-valence organogallium compounds (Chapter 14) that (I) atom and an aromatic ligand in an TJe fashion. exhibit bonding interaction between a gallium Due to a free coordination site at the Ga atom, neutral compounds form many adducts with Lewis bases (symbol D). These adducts are described along with the parent substances either in a subsection of the respective chapter or in a common table at the end of the table.
Author: Edgar Rudolph Publisher: Springer ISBN: Category : Science Languages : en Pages : 536
Book Description
The present volume describes all organogallium compounds, i.e., compounds containing at least one gallium-carbon bond. It covers the literature completely.to the end of 1984 and includes many references to the literature up to the end of 1985. The organic chemistry of gallium is largely dominated by compounds of the types GaR3 (Chapter 1), GaR X _ (Chapters 2 to 12), and M[GaRnX4_nl (M = cation, Chapter 13), where X n 3 n stands for a non-carbon atom or any organic or organometallic group bonded to gallium through a non-carbon atom. The arrangement of GaR X - and M[GaRnX"_nlcompounds by n 3 n the kind of Ga-X bond is evident from the table of contents on pp. XI to XIV. The extensive use of pyrazolyl-containing organogallium anions as polydentate donor ligands in transition metal compounds resulted in a particularly voluminous chapter on anions with Ga-N bonds (13.6). The volume is concluded by a few low-valence organogallium compounds (Chapter 14) that (I) atom and an aromatic ligand in an TJe fashion. exhibit bonding interaction between a gallium Due to a free coordination site at the Ga atom, neutral compounds form many adducts with Lewis bases (symbol D). These adducts are described along with the parent substances either in a subsection of the respective chapter or in a common table at the end of the table.
Author: A.J. Downs Publisher: Springer Science & Business Media ISBN: 9780751401035 Category : Science Languages : en Pages : 552
Book Description
Boron has all the best tunes. That may well be the first impression of the Group 13 elements. The chemical literature fosters the impression not only in the primary journals, but also in asteady outflowofbooks focussing more or less closely on boron and its compounds. The same preoccupation with boron is apparent in the coverage received by the Group 13 elements in the comprehensive and regularly updated volume of the Gmelin Handbook. Yet such an imbalance cannot be explained by any inherent lack ofvariety, interest or consequence in the 'heavier elements. Aluminium is the most abundant metal in the earth's crust; in the industrialised world the metal is second only to iron in its usage, and its compounds can justifiably be said to touch our lives daily - to the potential detriment of those and other lives, some would argue. From being chemical curios, gallium and indium have now gained considerably prominence as sources of compound semiconductors like gallium arsenide and indium antimonide. Nor is there any want ofincident in the chemistriesofthe heavier Group 13 elements. In their redox, coordination and structural properties, there is to be found music indeed, notable not always for its harmony but invariably for its richness and variety. Thisbook seeks to redress the balance with a definitive, wide-rangingand up-to-date review of the chemistry of the Group 13 metals aluminium, gallium, indium and thallium.
Author: Krystyna Kamienska-Trela Publisher: Royal Society of Chemistry ISBN: 1849732795 Category : Science Languages : en Pages : 553
Book Description
As a spectroscopic method, nuclear magnetic resonance (NMR) has seen spectacular growth, both as a technique and in its applications. Today's applications of NMR span a wide range of scientific disciplines, from physics to biology to medicine. Each volume of Nuclear Magnetic Resonance comprises a combination of annual and biennial reports which together provide comprehensive coverage of the literature on this topic. This Specialist Periodical Report reflects the growing volume of published work involving NMR techniques and applications, in particular NMR of natural macromolecules, which is covered in two reports: NMR of Proteins and Nucleic Acids and NMR of Carbohydrates, Lipids and Membranes. In his foreword to the first volume, the then editor, Professor Robin Harris announced that the series would be a discussion on the phenomena of NMR and that articles will be critical surveys of the literature. This has certainly remained the case throughout the series, and in line with its predecessors, Volume 40 aims to provide a comprehensive coverage of the relevant NMR literature. For the current volume this relates to publications appearing between June 2009 and May 2010 (the nominal period of coverage in volume 1 was July 1970 to June 1971). Compared to the previous volume there are some new members of the reporting team. Theoretical Aspects of Spin-Spin Couplings are covered by J. Jazwinski, while E. Swiezewska and J.W3⁄4jcik provide an account of NMR of Carbohydrates, Lipids and Membranes.
Author: M Green Publisher: Royal Society of Chemistry ISBN: 1847554172 Category : Science Languages : en Pages : 566
Book Description
Organometallic chemistry is an interdisciplinary science which continues to grow at a rapid pace. Although there is continued interest in synthetic and structural studies the last decade has seen a growing interest in the potential of organometallic chemistry to provide answers to problems in catalysis synthetic organic chemistry and also in the development of new materials. This Specialist Periodical Report aims to reflect these current interests reviewing progress in theoretical organometallic chemistry, main group chemistry, the lanthanides and all aspects of transition metal chemistry. Specialist Periodical Reports provide systematic and detailed review coverage of progress in the major areas of chemical research. Written by experts in their specialist fields the series creates a unique service for the active research chemist, supplying regular critical in-depth accounts of progress in particular areas of chemistry. For over 80 years the Royal Society of Chemistry and its predecessor, the Chemical Society, have been publishing reports charting developments in chemistry, which originally took the form of Annual Reports. However, by 1967 the whole spectrum of chemistry could no longer be contained within one volume and the series Specialist Periodical Reports was born. The Annual Reports themselves still existed but were divided into two, and subsequently three, volumes covering Inorganic, Organic and Physical Chemistry. For more general coverage of the highlights in chemistry they remain a 'must'. Since that time the SPR series has altered according to the fluctuating degree of activity in various fields of chemistry. Some titles have remained unchanged, while others have altered their emphasis along with their titles; some have been combined under a new name whereas others have had to be discontinued. The current list of Specialist Periodical Reports can be seen on the inside flap of this volume.
Author: E W Abel Publisher: Royal Society of Chemistry ISBN: 1847554067 Category : Science Languages : en Pages : 494
Book Description
Organometallic chemistry is an interdisciplinary science which continues to grow at a rapid pace. Although there is continued interest in synthetic and structural studies the last decade has seen a growing interest in the potential of organometallic chemistry to provide answers to problems in catalysis synthetic organic chemistry and also in the development of new materials. This Specialist Periodical Report aims to reflect these current interests reviewing progress in theoretical organometallic chemistry, main group chemistry, the lanthanides and all aspects of transition metal chemistry. Specialist Periodical Reports provide systematic and detailed review coverage of progress in the major areas of chemical research. Written by experts in their specialist fields the series creates a unique service for the active research chemist, supplying regular critical in-depth accounts of progress in particular areas of chemistry. For over 80 years the Royal Society of Chemistry and its predecessor, the Chemical Society, have been publishing reports charting developments in chemistry, which originally took the form of Annual Reports. However, by 1967 the whole spectrum of chemistry could no longer be contained within one volume and the series Specialist Periodical Reports was born. The Annual Reports themselves still existed but were divided into two, and subsequently three, volumes covering Inorganic, Organic and Physical Chemistry. For more general coverage of the highlights in chemistry they remain a 'must'. Since that time the SPR series has altered according to the fluctuating degree of activity in various fields of chemistry. Some titles have remained unchanged, while others have altered their emphasis along with their titles; some have been combined under a new name whereas others have had to be discontinued. The current list of Specialist Periodical Reports can be seen on the inside flap of this volume.
Author: Ionel Haiduc Publisher: Walter de Gruyter GmbH & Co KG ISBN: 3110695278 Category : Science Languages : en Pages : 443
Book Description
This book provides the reader with a comprehensive introduction to the topic of organometallic chemistry. With an easy to follow structure covering both non-transition metals and transition metals as well as the applications of organometallic reagents in organic synthesis, this book is a must-have for the organometallic chemist. Thematic overview of organometallic compounds of transition and non-transition metals. Covers structures as well as applications.
Author: A. P. Hagen Publisher: John Wiley & Sons ISBN: 0470145455 Category : Science Languages : en Pages : 541
Book Description
For the first time the discipline of modern inorganic chemistry has been systematized according to a plan constructed by a council of editorial advisors and consultants, among them three Nobel laureates (E.O. Fischer, H. Taube and G. Wilkinson). Rather than producing a collection of unrelated review articles, the series creates a framework which reflects the creative potential of this scientific discipline. Thus, it stimulates future development by identifiying areas which are fruitful for further research. The work is indexed in a unique way by a structured system which maximizes its usefulness to the reader. It augments the organization of the work by providing additional routes of access for specific compounds, reactions and other topics.
Author: Simon Aldridge Publisher: John Wiley & Sons ISBN: 0470976683 Category : Science Languages : en Pages : 990
Book Description
The last two decades have seen a renaissance in interest in the chemistry of the main group elements. In particular research on the metals of group 13 (aluminium, gallium, indium and thallium) has led to the synthesis and isolation of some very novel and unusual molecules, with implications for organometallic synthesis, new materials development, and with biological, medical and, environmental relevance. The Group 13 Metals Aluminium, Gallium, Indium and Thallium aims to cover new facts, developments and applications in the context of more general patterns of physical and chemical behaviour. Particular attention is paid to the main growth areas, including the chemistry of lower formal oxidation states, cluster chemistry, the investigation of solid oxides and hydroxides, advances in the formation of III-V and related compounds, the biological significance of Group 13 metal complexes, and the growing importance of the metals and their compounds in the mediation of organic reactions. Chapters cover: general features of the group 13 elements group 13 metals in the +3 oxidation state: simple inorganic compounds formal oxidation state +3: organometallic chemistry formal oxidation state +2: metal-metal bonded vs. mononuclear derivatives group 13 metals in the +1 oxidation state mixed or intermediate valence group 13 metal compounds aluminium and gallium clusters: metalloid clusters and their relation to the bulk phases, to naked clusters, and to nanoscaled materials simple and mixed metal oxides and hydroxides: solids with extended structures of different dimensionalities and porosities coordination and solution chemistry of the metals: biological, medical and, environmental relevance III-V and related semiconductor materials group 13 metal-mediated organic reactions The Group 13 Metals Aluminium, Gallium, Indium and Thallium provides a detailed, wide-ranging, and up-to-date review of the chemistry of this important group of metals. It will find a place on the bookshelves of practitioners, researchers and students working in inorganic, organometallic, and materials chemistry.
Author: I.W. Boyd Publisher: Elsevier ISBN: 0444596801 Category : Technology & Engineering Languages : en Pages : 552
Book Description
The contributions in this volume reflect not only the growing understanding of the underlying mechanisms controlling the various reactions in laser surface processing, but also the potential of several developing applications of direct processing. The most notable trend in the field currently is the technique of laser ablation, which is reported in almost a quarter of the papers in this volume. Whilst by no means a new phenomenon, attention has until recent years remained in the area of lithography and UV-sensitive materials. The growth in interest lies in the use of the technique to grow multi-component thin films and multi-layers. A number of papers on the topic of process diagnostics and in-situ measurements are also included. The theme of these annual meetings is centred around the physical and chemical modification of thin films and surfaces induced by the action of photon, ion, neutral, or electron beams in a variety of environments. Consequently these proceedings provide a comprehensive and unified presentation of the latest developments in this field.
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Author: 
Author: Edgar Rudolph
Author: A.J. Downs
Author: Krystyna Kamienska-Trela
Author: M Green
Author: E W Abel
Author: Ionel Haiduc
Author: A. P. Hagen
Author: Simon Aldridge
Author: I.W. Boyd