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Fundamental Problems in Porous Materials

Fundamental Problems in Porous Materials PDF Author: Zhanping Xu
Publisher:
ISBN: 9781321979534
Category :
Languages : en
Pages : 199

Book Description
Porous materials have attracted massive scientific and technological interest because of their extremely high surface-to-volume ratio, molecular tunability in construction, and surface-based applications. Through my PhD work, porous materials were engineered to meet the design in selective binding, self-healing, and energy damping. For example, crystalline MOFs with pore size spanning from a few angstroms to a couple of nanometers were chemically engineered to show 120 times more efficiency in binding of large molecules. In addition, we found building blocks released from those crystals can be further patched back through a healing process at ambient and low temperatures down to -56 °C. When building blocks are replaced with graphenes, ultra-flyweight aerogels with pore size larger than 100 nm were made to delay shock waves. More stable rigid porous metal with larger pores (~um) was also fabricated, and its performance and survivability are under investigation. Aside from experimental studies, we also successfully applied numerical simulations to study the mutual interaction between the nonplanar liquid-solid interface and colloidal particles during the freezing of the colloidal suspensions. Colloidal particles can be either rejected or engulfed by the evolving interface depending on the freezing speed and strength of interface-particle interaction. Our interactive simulation was achieved by programming both simulation module and visualization module on high performance GPU devices.

Fundamental Problems in Porous Materials

Fundamental Problems in Porous Materials PDF Author: Zhanping Xu
Publisher:
ISBN: 9781321979534
Category :
Languages : en
Pages : 199

Book Description
Porous materials have attracted massive scientific and technological interest because of their extremely high surface-to-volume ratio, molecular tunability in construction, and surface-based applications. Through my PhD work, porous materials were engineered to meet the design in selective binding, self-healing, and energy damping. For example, crystalline MOFs with pore size spanning from a few angstroms to a couple of nanometers were chemically engineered to show 120 times more efficiency in binding of large molecules. In addition, we found building blocks released from those crystals can be further patched back through a healing process at ambient and low temperatures down to -56 °C. When building blocks are replaced with graphenes, ultra-flyweight aerogels with pore size larger than 100 nm were made to delay shock waves. More stable rigid porous metal with larger pores (~um) was also fabricated, and its performance and survivability are under investigation. Aside from experimental studies, we also successfully applied numerical simulations to study the mutual interaction between the nonplanar liquid-solid interface and colloidal particles during the freezing of the colloidal suspensions. Colloidal particles can be either rejected or engulfed by the evolving interface depending on the freezing speed and strength of interface-particle interaction. Our interactive simulation was achieved by programming both simulation module and visualization module on high performance GPU devices.

Porous Media

Porous Media PDF Author: Wolfgang Ehlers
Publisher: Springer Science & Business Media
ISBN: 3662049996
Category : Technology & Engineering
Languages : en
Pages : 459

Book Description
The present volume offers a state-of-the-art report on the various recent sci entific developments in the Theory of Porous Media (TPM) comprehending the basic theoretical concepts in continuum mechanics on porous and mul tiphasic materials as well as the wide range of experimental and numerical applications. Following this, the volume does not only address the sophisti cated reader but also the interested beginner in the area of Porous Media by presenting a collection of articles. These articles written by experts in the field concern the fundamental approaches to multiphasic and porous materials as well as various applications to engineering problems. In many branches of engineering just as in applied natural sciences like bio- and chemomechanics, one often has to deal with continuum mechanical problems which cannot be uniquely classified within the well-known disci plines of either "solid mechanics" or "fluid mechanics". These problems, characterized by the fact that they require a unified treatment of volumetri cally coupled solid-fluid aggregates; basically fall into the categories of either mixtures or porous media. Following this, there is a broad variety of problems ranging in this category as for example the investigation of reacting fluid mix tures or solid-fluid suspensions as well as the investigation of the coupled solid deformation and pore-fluid flow behaviour of liquid- and gas-saturated porous solid skeleton materials like geomaterials (soil, rock, concrete, etc. ), polymeric and metallic foams or biomaterials (hard and soft tissues, etc).

Advanced Functional Porous Materials

Advanced Functional Porous Materials PDF Author: Arya Uthaman
Publisher: Springer Nature
ISBN: 3030853977
Category : Technology & Engineering
Languages : en
Pages : 690

Book Description
This book presents synthesis, characterization, and applications of macroporous, mesoporous, nanoporous, hierarchical porous, porous metals, and porous ceramics. Special emphasis is given to the preparation of porous activated carbon materials and porous ionic liquid-derived materials for CO2 emissions mitigation. Additionally, a chapter includes the physical and mathematical modeling in porous media. Many analytical techniques for characterization are discussed in this book. Also, the biomedical and industrial applications of porous materials in adsorption, catalysis, biosensors, drug delivery, nanotechnology are described. The content helps solving fundamental and applied problems in porous materials with length scales varying from macro- to nano-level.

Diffusion in Nanoporous Materials, 2 Volumes

Diffusion in Nanoporous Materials, 2 Volumes PDF Author: Jörg Kärger
Publisher: John Wiley & Sons
ISBN: 352731024X
Category : Science
Languages : en
Pages : 932

Book Description
Atoms and molecules in all states of matter are subject to continuous irregular movement. This process, referred to as diffusion, is among the most general and basic phenomena in nature and determines the performance of many technological processes. This book provides an introduction to the fascinating world of diffusion in microporous solids. Jointly written by three well-known researchers in this field, it presents a coherent treatise, rather than a compilation of separate review articles, covering the theoretical fundamentals, molecular modeling, experimental observation and technical applications. Based on the book Diffusion in Zeolites and other Microporous Solids, originally published in 1992, it illustrates the remarkable speed with which this field has developed since that time. Specific topics include: new families of nanoporous materials, micro-imaging and single-particle tracking, direct monitoring of transient profiles by interference microscopy, single-file diffusion and new approaches to molecular modeling.

Microporomechanics

Microporomechanics PDF Author: Luc Dormieux
Publisher: John Wiley & Sons
ISBN: 0470031999
Category : Science
Languages : en
Pages : 344

Book Description
Intended as a first introduction to the micromechanics of porous media, this book entitled “Microporomechanics” deals with the mechanics and physics of multiphase porous materials at nano and micro scales. It is composed of a logical and didactic build up from fundamental concepts to state-of-the-art theories. It features four parts: following a brief introduction to the mathematical rules for upscaling operations, the first part deals with the homogenization of transport properties of porous media within the context of asymptotic expansion techniques. The second part deals with linear microporomechanics, and introduces linear mean-field theories based on the concept of a representative elementary volume for the homogenization of poroelastic properties of porous materials. The third part is devoted to Eshelby’s problem of ellipsoidal inclusions, on which much of the micromechanics techniques are based, and illustrates its application to linear diffusion and microporoelasticity. Finally, the fourth part extends the analysis to microporo-in-elasticity, that is the nonlinear homogenization of a large range of frequently encountered porous material behaviors, namely, strength homogenization, nonsaturated microporomechanics, microporoplasticity and microporofracture and microporodamage theory.

Theory of Porous Media

Theory of Porous Media PDF Author: Reint de Boer
Publisher: Springer Science & Business Media
ISBN: 3642596371
Category : Science
Languages : en
Pages : 626

Book Description
This is a consistent treatment of the material-independent fundamental equations of the theory of porous media, formulating constitutive equations for frictional materials in the elastic and plastic range, while tracing the historical development of the theory. Thus, for the first time, a unique treatment of fluid-saturated porous solids is presented, including an explanation of the corresponding theory by way of its historical progression, and a thorough description of its current state.

Mathematical and Numerical Modeling in Porous Media

Mathematical and Numerical Modeling in Porous Media PDF Author: Martin A. Diaz Viera
Publisher: CRC Press
ISBN: 0203113888
Category : Mathematics
Languages : en
Pages : 370

Book Description
Porous media are broadly found in nature and their study is of high relevance in our present lives. In geosciences porous media research is fundamental in applications to aquifers, mineral mines, contaminant transport, soil remediation, waste storage, oil recovery and geothermal energy deposits. Despite their importance, there is as yet no complete

Mechanics and Physics of Porous Materials

Mechanics and Physics of Porous Materials PDF Author: Chin Hua Chia
Publisher: Apple Academic Press
ISBN: 9781774914649
Category : Science
Languages : en
Pages : 0

Book Description
Presents new research on porous materials with case studies on the synthesis, design, characterization, and applications of different types of porous materials and solids, considering experimental and theoretical aspects.

Fluid Flow In Porous Media: Fundamentals And Applications

Fluid Flow In Porous Media: Fundamentals And Applications PDF Author: Liang Xue
Publisher: World Scientific
ISBN: 9811219540
Category : Science
Languages : en
Pages : 408

Book Description
Processes of flow and displacement of multiphase fluids through porous media occur in many subsurface systems and have found wide applications in many scientific, technical, and engineering fields. This book focuses on the fundamental theory of fluid flow in porous media, covering fluid flow theory in classical and complex porous media, such as fractured porous media and physicochemical fluid flow theory. Key concepts are introduced concisely and derivations of equations are presented logically. Solutions of some practical problems are given so that the reader can understand how to apply these abstract equations to real world situations. The content has been extended to cover fluid flow in unconventional reservoirs. This book is suitable for senior undergraduate and graduate students as a textbook in petroleum engineering, hydrogeology, groundwater hydrology, soil sciences, and other related engineering fields.

Introduction to Porous Materials

Introduction to Porous Materials PDF Author: Pascal Van Der Voort
Publisher: John Wiley & Sons
ISBN: 111942660X
Category : Science
Languages : en
Pages : 441

Book Description
The first comprehensive textbook on the timely and rapidly developing topic of inorganic porous materials This is the first textbook to completely cover a broad range of inorganic porous materials. It introduces the reader to the development of functional porous inorganic materials, from the synthetic zeolites in the 50’s, to today’s hybrid materials such as metal-organic frameworks (MOFs), covalent organic frameworks (COFs) and related networks. It also provides the necessary background to understand how porous materials are organized, characterized, and applied in adsorption, catalysis, and many other domains. Additionally, the book explains characterization and application from the materials scientist viewpoint, giving the reader a practical approach on the characterization and application of the respective materials. Introduction to Inorganic Porous Materials begins by describing the basic concepts of porosity and the different types of pores, surfaces, and amorphous versus crystalline materials, before introducing readers to nature’s porous materials. It then goes on to cover everything from adsorption and catalysis to amorphous materials such as silica to inorganic carbons and Periodic Mesoporous Organosilicas (PMOs). It discusses the synthesis and applications of MOFs and the broad family of COFs. It concludes with a look at future prospects and emerging trends in the field. The only complete book of its kind to cover the wide variety of inorganic and hybrid porous materials A comprehensive reference and outstanding tool for any course on inorganic porous materials, heterogeneous catalysis, and adsorption Gives students and investigators the opportunity to learn about porous materials, how to characterize them, and understand how they can be applied in different fields Introduction to Inorganic Porous Materials is an excellent book for students and professionals of inorganic chemistry and materials science with an interest in porous materials, functional inorganic materials, heterogeneous catalysis and adsorption, and solid state characterization techniques.