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Author: Royce W. Murray Publisher: ISBN: Category : Languages : en Pages : 21
Book Description
Application of modern transient techniques to the study of metal complex adsorptions at mercury electrodes has strengthened further the suspected dominating influence of the ligand adsorption properties in the adsorption process. Adsorptions of cadmium iodide, indium(III)thiocyanate, and the organometal phenyl-mercury(II) have been studied. Inhibition of electrode processes by adsorbed species has also been examined for the unusual cases of lead halides (two-dimensional crystallizations) and brucine (simulated optically active electrodes). Extensive development of the field of thin-layer electrochemistry has been made. Design, theoretical characterization, and application of twin working electrode cells have been accomplished, with emphasis on general steady-state current features and application to chemical kinetics (benzidine rearrangement, uranium(V) disproportionation). Single electrode cells have been used in potential scan coulometry and have been modified to alleviate edge diffusion effects (getter electrode). The development of thin-layer cells useful for in situ spectral measurements was also accomplished and a number of applications made (metal acetylacetonate reactions, infrared study of ninhydrin reduction, o-tolidine oxidation, fluorescence). Work in A.C. polarographic instrumentation has produced a high-performance instrument having good signal-to-noise and lacking troublesome tuned amplifier components. A study of acetylacetonate coordination chemistry has revealed a 1:2 complexation with lithium ion in acetonitrile solvent. (Author).
Author: Royce W. Murray Publisher: ISBN: Category : Languages : en Pages : 21
Book Description
Application of modern transient techniques to the study of metal complex adsorptions at mercury electrodes has strengthened further the suspected dominating influence of the ligand adsorption properties in the adsorption process. Adsorptions of cadmium iodide, indium(III)thiocyanate, and the organometal phenyl-mercury(II) have been studied. Inhibition of electrode processes by adsorbed species has also been examined for the unusual cases of lead halides (two-dimensional crystallizations) and brucine (simulated optically active electrodes). Extensive development of the field of thin-layer electrochemistry has been made. Design, theoretical characterization, and application of twin working electrode cells have been accomplished, with emphasis on general steady-state current features and application to chemical kinetics (benzidine rearrangement, uranium(V) disproportionation). Single electrode cells have been used in potential scan coulometry and have been modified to alleviate edge diffusion effects (getter electrode). The development of thin-layer cells useful for in situ spectral measurements was also accomplished and a number of applications made (metal acetylacetonate reactions, infrared study of ninhydrin reduction, o-tolidine oxidation, fluorescence). Work in A.C. polarographic instrumentation has produced a high-performance instrument having good signal-to-noise and lacking troublesome tuned amplifier components. A study of acetylacetonate coordination chemistry has revealed a 1:2 complexation with lithium ion in acetonitrile solvent. (Author).
Author: Cynthia G. Zoski Publisher: Elsevier ISBN: 0444519580 Category : Science Languages : en Pages : 935
Book Description
Electrochemistry plays a key role in a broad range of research and applied areas including the exploration of new inorganic and organic compounds, biochemical and biological systems, corrosion, energy applications involving fuel cells and solar cells, and nanoscale investigations. The Handbook of Electrochemistry serves as a source of electrochemical information, providing details of experimental considerations, representative calculations, and illustrations of the possibilities available in electrochemical experimentation. The book is divided into five parts: Fundamentals, Laboratory Practical, Techniques, Applications, and Data. The first section covers the fundamentals of electrochemistry which are essential for everyone working in the field, presenting an overview of electrochemical conventions, terminology, fundamental equations, and electrochemical cells, experiments, literature, textbooks, and specialized books. Part 2 focuses on the different laboratory aspects of electrochemistry which is followed by a review of the various electrochemical techniques ranging from classical experiments to scanning electrochemical microscopy, electrogenerated chemiluminesence and spectroelectrochemistry. Applications of electrochemistry include electrode kinetic determinations, unique aspects of metal deposition, and electrochemistry in small places and at novel interfaces and these are detailed in Part 4. The remaining three chapters provide useful electrochemical data and information involving electrode potentials, diffusion coefficients, and methods used in measuring liquid junction potentials. * serves as a source of electrochemical information * includes useful electrochemical data and information involving electrode potentials, diffusion coefficients, and methods used in measuring liquid junction potentials * reviews electrochemical techniques (incl. scanning electrochemical microscopy, electrogenerated chemiluminesence and spectroelectrochemistry)
Author: Allen J. Bard Publisher: Wiley Global Education ISBN: 1118312805 Category : Science Languages : en Pages : 862
Book Description
Das führende Werk auf seinem Gebiet - jetzt durchgängig auf den neuesten Stand gebracht! Die theoretischen Grundlagen der Elektrochemie, erweitert um die aktuellsten Erkenntnisse in der Theorie des Elektronentransfers, werden hier ebenso besprochen wie alle wichtigen Anwendungen, darunter modernste Verfahren (Ultramikroelektroden, modifizierte Elektroden, LCEC, Impedanzspektrometrie, neue Varianten der Pulsvoltammetrie und andere). In erster Linie als Lehrbuch gedacht, läßt sich das Werk aber auch hervorragend zum Selbststudium und zur Auffrischung des Wissensstandes verwenden. Lediglich elementare Grundkenntnisse der physikalischen Chemie werden vorausgesetzt.
Author: Royce W. Murray
Author: Royce W. Murray
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Author: Cynthia G. Zoski
Author: Allen J. Bard
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