Structure of Electrified Interfaces PDF Download

Author: Jacek Lipkowski
Publisher:
ISBN: 9783527287871
Category : Electrochemistry
Languages : en
Pages : 406

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Book Description

Author: Jacek Lipkowski
Publisher: Wiley-VCH
ISBN: 9780471188162
Category : Science
Languages : en
Pages : 406

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Book Description
Leading scientists provide a modern description of the metal-solution interface and describe the numerous advances made in interfacial electrochemistry during the past decade. Contributing authors summarize the impact of new ex situ and in situ techniques in studying electrode surfaces, and illustrate the significance of the developments of new experimental techniques and the availability of reliable data for the progress in the theory of electrified interfaces. The carefully selected review articles demonstrate how a molecular picture of the interface has emerged from traditional models that treated the solution as a dielectric and metals as an electronic continuum. This latest volume in the series leads the reader into the world of modern techniques, which probe the properties of atoms and the molecules at surfaces of metal electrodes. It will be of interest to graduate students and scientists, chemists and physicists interested in surface science and electrochemistry.

Author: R Guidelli
Publisher: Springer Science & Business Media
ISBN: 940112566X
Category : Science
Languages : en
Pages : 604

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Book Description
Electrified interfaces span from metaVsemiconductor and metaVelectrolyte interfaces to disperse systems and biological membranes, and are notably important in so many physical, chemical and biological systems that their study has been tackled by researchers with different scientific backgrounds using different methodological approaches. The various electrified interfaces have several common features. The equilibrium distribution of positive and negative ions in an electrolytic solution is governed by the same Poisson-Boltzmann equation independent of whether the solution comes into contact with a metal, a colloidal particle or a biomembrane, and the same is true for the equilibrium distribution of free electrons and holes of a semiconductor in contact with a different conducting phase. Evaluation of electric potential differences across biomembranes is based on the same identity of electrochemical potentials which holds for a glass electrode and which yields the Nernst equation when applied to a metal/solution interface. The theory of thermally activated electron tunneling, which was developed by Marcus, Levich, Dogonadze and others to account for electron transfer across metaVelectrolyte interfaces, is also applied to light induced charge separation and proton translocation reactions across intercellular membranes. From an experimental viewpoint, the same electrochemical and in situ spectroscopic techniques can equally well be employed for the study of apparently quite different electrified interfaces.

Author: Jacek Lipkowski
Publisher: Wiley-VCH
ISBN:
Category : Science
Languages : en
Pages : 424

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Book Description
This second volume in the Frontiers of Electrochemistry series provides a modern description of the metal-solution interface and describes the advances made in interfacial electrochemistry during the past decade. Contributing authors summarize the impact of new ex situ and in situ techniques in studying electrode surfaces, and illustrate the significance of the development of new experimental techniques and the availability of reliable data in the theory of electrified interfaces. The review articles demonstrate how a molecular picture of the interface has emerged from traditional models that treated the solution as a dielectric and metal as an electronic continuum. Annotation copyright by Book News, Inc., Portland, OR

Author: J. Lyklema
Publisher: Elsevier
ISBN: 0080507123
Category : Technology & Engineering
Languages : en
Pages : 787

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Book Description
Interface and colloid science is an important, though often under-valued, branch of science. It has applications and ramifications in domains as disparate as agriculture, mineral dressing, oil recovery, chemical industry, biotechnology, medical science, and many more. Proper application of interface and colloid science requires factual knowledge and insight into the many basic laws of physics and chemistry upon which it is based. Fundamentals of Interface and Colloid Science is the first book to cover this field in the depth neccessary to be a valuable reference and an excellent textbook.From the beginning to the end of the book, systems of growing complexity are treated gradually. The presentation is particularly suited to emphasize that interfaces are not autonomous phases. As a rule, interfacial properties can be varied only by changing the adjoining phases, so that the properties of these bulk phases must be understood first. The text also recognizes common principles behind a variety of phenomena, and helps the reader to understand them and to develop and improve processes. The systematic treatment of the material in the book makes this clear, and makes the text itself an important contribution to the field. Systematic treatment of information An excellent addition to volume I Two chapters contributed by other experts in the field Uses a deductive approach to increase the order of complexity Written by a leading expert in the field Two chapters contributed by other outstanding scientists Uses a systematic and deductive approach First comprehensive review of the topic

Author: Allen J. Bard
Publisher: Wiley-VCH
ISBN: 9783527303939
Category : Science
Languages : en
Pages : 620

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Book Description
From fundamental research to its application in the industry, this encyclopedia covers all aspects of electrochemistry. It provides both a comprehensive overview for electrochemists and an accessible look at electrochemical topics for users from other scientific disciplines. Volume 1 in this series offers a detailed examination of thermodynamics and electrified interfaces.

Author: R Guidelli
Publisher:
ISBN: 9789401125673
Category :
Languages : en
Pages : 620

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Book Description

Author: Andrzej Wieckowski
Publisher: CRC Press
ISBN: 9780824760007
Category : Science
Languages : en
Pages : 1008

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Book Description
This text probes topics and reviews progress in interfacial electrochemistry. It supplies chapter abstracts to give readers a concise overview of individual subjects and there are more than 1500 drawings, photographs, micrographs, tables and equations. The 118 contributors are international scholars who present theory, experimentation and applications.

Author: Vladimir E. Kazarinov
Publisher: Springer Science & Business Media
ISBN: 3642718817
Category : Science
Languages : en
Pages : 254

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Book Description
Studies on the electrochemical processes at the interface between two immiscible liquids began a long time ago: they date back to the end of the last century. Such celebrated scientists as Nemst and Haber, and also young A. N. Frumkin were among those who originated this science. Later A. N. Frumkin went a long way in furthering the studies at the Institute of Electrochemistry. The theory of the appearance of potential in a system of two immiscible electrolytes was developed and experimentally verified before the beginning of the thirties. In later years the studies in this area considerably lagged behind those conducted at metal electrodes which were widely used in different industries. In the past 15 years, however, the situation has radically changed and we have witnessed a drastic increase in the number of publications on the electrochemistry of immiscible electrolytes. We are glad to note that the investiga tions show not only a quantitative but also a qualitative change. The theoretical works on the oil/water interface test not only the thermodynamic aspects of the inter face but also recreate the molecular picture of the process. Along with the now con ventional oilfwater system, electrochemical studies are made on various membranes, including the frnest bilayer lipid membranes, and also on microemulsion systems. A prominent place in the investigation of the oil/water interface is occupied by photoprocesses that come into play at the interface between two ionic conductors.

Author: Kohei Uosaki
Publisher: Springer
ISBN: 3319573101
Category : Science
Languages : en
Pages : 262

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Book Description
This book honors Professor. John O’M. Bockris, presenting authoritative reviews on some of the subjects to which he made significant contributions – i.e., electrocatalysis, fuel cells, electrochemical theory, electrochemistry of single crystals, in situ techniques, rechargeable batteries, passivity, and solar-fuels – and revealing the roles of electrochemical science and technology in achieving a sustainable society. Electrochemistry has long been an object of study and is now growing in importance, not only because of its fundamental scientific interest but also because of the central role it is expected to play in a future sustainable society. Professor John O’M. Bockris contributed greatly to various aspects of fundamental and applied electrochemistry – such as the structure of the double layer, kinetics and mechanism of the electrochemistry of hydrogen and oxygen, electrocatalysis, adsorption and electrochemical oxidation of small organic molecules, fuel cells, electrocrystallization, theoretical electrochemistry, new methods, photoelectrochemistry, bioelectrochemistry, corrosion and passivity, hydrogen in metals, ionic solutions and ionic liquids, and molten silicates and glasses, as well as socio-economic issues such as the hydrogen economy – for over half a century from 1945 until his retirement in 1997.