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Fluorine-Carbon and Fluoride-Carbon Materials

Fluorine-Carbon and Fluoride-Carbon Materials PDF Author: Tsuyoshi Nakajima
Publisher: CRC Press
ISBN: 9781439809310
Category : Science
Languages : en
Pages : 418

Book Description
"This outstanding reference presents the latest scientific findings concerning the synthesis, structure, thermodynamics, and physical and chemical properties of fluorine- and fluoride-carbon compounds elucidating their practical applications in lithium batteries, superhydrophobic composites, and the electrolytic production of elemental fluorine."

Fluorine-Carbon and Fluoride-Carbon Materials

Fluorine-Carbon and Fluoride-Carbon Materials PDF Author: Tsuyoshi Nakajima
Publisher: CRC Press
ISBN: 9781439809310
Category : Science
Languages : en
Pages : 418

Book Description
"This outstanding reference presents the latest scientific findings concerning the synthesis, structure, thermodynamics, and physical and chemical properties of fluorine- and fluoride-carbon compounds elucidating their practical applications in lithium batteries, superhydrophobic composites, and the electrolytic production of elemental fluorine."

New Fluorinated Carbons: Fundamentals and Applications

New Fluorinated Carbons: Fundamentals and Applications PDF Author: Olga V. Boltalina
Publisher: Academic Press
ISBN: 0128035021
Category : Science
Languages : en
Pages : 444

Book Description
New Fluorinated Carbons: Fundamentals and Applications is the second volume in Alain Tressaud’s Progress in Fluorine Science series. This volume provides an overview of cutting-edge research and emerging applications using new fluorinated carbon materials such as fullerenes, carbon nanotubes, polycyclic aromatic molecules, carbon nanofibers, and graphenes. Edited by recognized experts Olga Boltalina and Tsuyoshi Nakajima, this book includes valuable chapters on syntheses, structure analyses, and chemical and physical properties of fluorinated carbons written by leaders in each respective field. The work also explores the diverse practical applications of these functional materials—from energy storage and energy conversion devices to molecular electronics and lubricants. Features contributions by leading experts in the field Includes fundamental and current research on synthesis, chemical, and physical properties of fluorinated carbons Explores practical applications in energy, electronics, and lubricants Examines a range of new fluorinated carbon materials

Advanced Fluoride-Based Materials for Energy Conversion

Advanced Fluoride-Based Materials for Energy Conversion PDF Author: Tsuyoshi Nakajima
Publisher: Elsevier
ISBN: 0128007125
Category : Technology & Engineering
Languages : en
Pages : 459

Book Description
Advanced Fluoride-Based Materials for Energy Conversion provides thorough and applied information on new fluorinated materials for chemical energy devices, exploring the electrochemical properties and behavior of fluorinated materials in lithium ion and sodium ion batteries, fluoropolymers in fuel cells, and fluorinated carbon in capacitors, while also exploring synthesis applications, and both safety and stability issues. As electronic devices, from cell phones to hybrid and electric vehicles, are increasingly common and prevalent in modern lives and require dependable, stable chemical energy devices with high-level functions are becoming increasingly important. As research and development in this area progresses rapidly, fluorine compounds play a critical role in this rapid progression. Fluorine, with its small size and the highest electronegativity, yields stable compounds under various conditions for utilization as electrodes, electrolytes, and membranes in energy devices. The book is an ideal reference for the chemist, researcher, technician, or academic, presenting valuable, current insights into the synthesis of fluorine compounds and fluorination reactions using fluorinating agents. Provides thorough and applied information on new fluorinated materials for chemical energy devices Describes the emerging role of stable energy devices with high-level functions and the research surrounding the technology Ideal for the chemist, research, technician, or academic seeking current insights into the synthesis of fluorine compounds and fluorination reactions using fluorinating agents

Fluorinated Materials for Energy Conversion

Fluorinated Materials for Energy Conversion PDF Author: Tsuyoshi Nakajima
Publisher: Elsevier
ISBN: 0080531784
Category : Technology & Engineering
Languages : en
Pages : 593

Book Description
Fluorinated Materials for Energy Conversion offers advanced information on the application of fluorine chemistry to energy conversion materials for lithium batteries, fuel cells, solar cells and so on. Fluorine compounds and fluorination techniques have recently gained important roles in improving the electrochemical characteristics of such energy production devices. The book therefore focuses on new batteries with high performance, the improvements of cell performance and the improvement of electrode and cell characteristics. The authors present new information on the effect of fluorine and how to make use of fluorination techniques and fluorine compounds. With emphasis on recent developments, this book is suitable for students, researchers and engineers working in chemistry, materials science and electrical engineering. Contains practical information, supported by examples Provides an update on recent developments in the field Written by specialists working in fluorine chemistry, electrochemistry, polymer and solid state chemistry

Graphite Fluorides & Carbon Fluoride Compounds

Graphite Fluorides & Carbon Fluoride Compounds PDF Author: Tsuyoshi Nakajima
Publisher: Springer
ISBN:
Category : Science
Languages : en
Pages : 192

Book Description


Fabrication of Iron-Containing Carbon Materials From Graphite Fluoride

Fabrication of Iron-Containing Carbon Materials From Graphite Fluoride PDF Author: Ching-cheh Hung
Publisher:
ISBN:
Category :
Languages : en
Pages : 20

Book Description
Carbon materials containing iron alloy, iron metal, iron oxide or iron halide were fabricated. Typical samples of these metals were estimated to contain 1 iron atom per 3.5 to 5 carbon atoms. Those carbon materials containing iron alloy, iron metal, and/or Fe3O4 were magnetic. The kinetics of the fabrication process were studied by exposing graphite fluoride (CF(0.68)) to FeCl3 over a 280 to 420 C temperature range. Between 280 and 295 C, FeCl3 quickly entered the structure of CF(0.68), broke the carbon-fluorine bonds, and within 10 to 30 min, completely converted it to carbon made up of graphite planes between which particles of crystalline FeF3 and noncrystalline FeCl3 were located. Longer reaction times (e.g., 28 hr) or higher reaction temperatures (e.g., 420 C) produced materials containing graphite, a FeCl3-graphite intercalation compound, FeCl2(center dot)4H2O, and FeCl2(center dot)2H2O. These products were further heat treated to produce iron-containing carbon materials. When the heating temperature was kept in the 750 to 850 C range, and the oxygen supply was kept at the optimum level, the iron halides in the carbon structure were converted to iron oxides. Raising the heat to temperatures higher than 900 C reduced such iron oxides to iron metal. The kinetics of these reactions were used to suggest processes for fabricating carbon materials containing iron alloy. Such processes were then tested experimentally. In one of the successful trial runs, commercially purchased CF(0.7) powder was used as the reactant, and NiO was added during the final heating to 1200 C as a source of both nickel and oxygen. The product thus obtained was magnetic and was confirmed to be a nickel-iron alloy in carbon.

Carbon-Fluorine Compounds

Carbon-Fluorine Compounds PDF Author: Katherine Elliott
Publisher: John Wiley & Sons
ISBN: 0470717513
Category : Science
Languages : en
Pages : 428

Book Description
The Novartis Foundation Series is a popular collection of the proceedings from Novartis Foundation Symposia, in which groups of leading scientists from a range of topics across biology, chemistry and medicine assembled to present papers and discuss results. The Novartis Foundation, originally known as the Ciba Foundation, is well known to scientists and clinicians around the world.

Fluorine in Organic Chemistry

Fluorine in Organic Chemistry PDF Author: Richard D. Chambers
Publisher: CRC Press
ISBN: 9780849317903
Category : Science
Languages : en
Pages : 426

Book Description
The introduction of carbon-fluorine bonds into organic compounds can profoundly influence their chemical and physical properties when compared to their non-fluorine-containing analogues, leading to a range of man-made materials with highly desirable properties. These molecules are of interest across the wide spectrum of industrial and academic organic chemistry, from pharmaceuticals, through fine and specialty chemicals to polymers. From Prozac to Teflon, many of the most important products of the chemical and life-science industries rely on organic fluorine chemistry for their useful properties. This book covers both the preparative methodologies and chemical properties of partially and highly fluorinated organic systems.

Carbon Alloys

Carbon Alloys PDF Author: E. Yasuda
Publisher: Elsevier
ISBN: 0080528538
Category : Science
Languages : en
Pages : 584

Book Description
In recent years the Japanese have funded a comprehensive study of carbon materials which incorporate other elements including boron, nitrogen and fluorine, hence the title of the project "Carbon Alloys". Coined in 1992, the phrase "Carbon Alloys" can be applied to those materials mainly composed of carbon materials in multi-component systems. The carbon atoms of each component have a physical and/or chemical interactive relationship with other atoms or compounds. The carbon atoms of the components may have different hybrid bonding orbitals to create quite different carbon components. Eiichi Yasuda and his team consider the definition of Carbon Alloys, present the results of the Carbon Alloys projects, describe typical Carbon Alloys and their uses, discuss recent techniques for their characterization, and finally, illustrate potential applications and future developments for Carbon Alloy science. The book contains over thirty chapters on these studies from as many researchers. The most modern of techniques, particularly in the area of spectroscopy, were used as diagnostic tools, and many of these are applicable to pure carbons also. Porosity in carbons received considerable attention.

Fabrication of Iron-Containing Carbon Materials from Graphite Fluoride

Fabrication of Iron-Containing Carbon Materials from Graphite Fluoride PDF Author: National Aeronautics and Space Adm Nasa
Publisher: Independently Published
ISBN: 9781792713897
Category :
Languages : en
Pages : 36

Book Description
Carbon materials containing iron alloy, iron metal, iron oxide or iron halide were fabricated. Typical samples of these metals were estimated to contain 1 iron atom per 3.5 to 5 carbon atoms. Those carbon materials containing iron alloy, iron metal, and/or Fe3O4 were magnetic. The kinetics of the fabrication process were studied by exposing graphite fluoride (CF(0.68)) to FeCl3 over a 280 to 420 C temperature range. Between 280 and 295 C, FeCl3 quickly entered the structure of CF(0.68), broke the carbon-fluorine bonds, and within 10 to 30 min, completely converted it to carbon made up of graphite planes between which particles of crystalline FeF3 and noncrystalline FeCl3 were located. Longer reaction times (e.g., 28 hr) or higher reaction temperatures (e.g., 420 C) produced materials containing graphite, a FeCl3-graphite intercalation compound, FeCl2(center dot)4H2O, and FeCl2(center dot)2H2O. These products were further heat treated to produce iron-containing carbon materials. When the heating temperature was kept in the 750 to 850 C range, and the oxygen supply was kept at the optimum level, the iron halides in the carbon structure were converted to iron oxides. Raising the heat to temperatures higher than 900 C reduced such iron oxides to iron metal. The kinetics of these reactions were used to suggest processes for fabricating carbon materials containing iron alloy. Such processes were then tested experimentally. In one of the successful trial runs, commercially purchased CF(0.7) powder was used as the reactant, and NiO was added during the final heating to 1200 C as a source of both nickel and oxygen. The product thus obtained was magnetic and was confirmed to be a nickel-iron alloy in carbon. Hung, Ching-cheh Glenn Research Center NASA-TM-107133, E-10063, NAS 1.15:107133 RTOP 233-1A-1E...