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Author: Publisher: ISBN: Category : Languages : en Pages : 80
Book Description
The Applied Technology Department at the Indian Head Division, Naval Surface Warfare Center and Shaw Environmental, Inc., have just successfully completed a field demonstration of in situ bioremediation of a groundwater aquifer contaminated with perchlorate. Using a recirculation cell design, naturally occurring microorganisms were stimulated to degrade perchlorate by injecting a food source (lactate) and neutralizing the groundwater acidity with a carbonate buffer. Starting with perchlorate concentrations in excess of 210 mg/L, perchlorate levels were reduced by more than 95% in eight of the nine test plot monitoring wells over the 5 months of sampling. In two of the monitoring wells, the perchlorate levels were lowered to less than 5 ppb. In addition to the perchlorate levels and the pH, alkalinity, nitrate, and sulfate concentrations were measured. In situ bioremediation techniques are much less expensive and significantly lower in maintenance than traditional ex situ pump-and-treat systems. This is the first field trial conducted on the east coast of the United States, the first trial performed in an acidic aquifer, and the first demonstration of treating in situ perchlorate levels in excess of 200 mg/L. This project provides new and valuable information concerning the application of bioremediation for in situ perchlorate treatment.
Author: Publisher: ISBN: Category : Languages : en Pages : 80
Book Description
The Applied Technology Department at the Indian Head Division, Naval Surface Warfare Center and Shaw Environmental, Inc., have just successfully completed a field demonstration of in situ bioremediation of a groundwater aquifer contaminated with perchlorate. Using a recirculation cell design, naturally occurring microorganisms were stimulated to degrade perchlorate by injecting a food source (lactate) and neutralizing the groundwater acidity with a carbonate buffer. Starting with perchlorate concentrations in excess of 210 mg/L, perchlorate levels were reduced by more than 95% in eight of the nine test plot monitoring wells over the 5 months of sampling. In two of the monitoring wells, the perchlorate levels were lowered to less than 5 ppb. In addition to the perchlorate levels and the pH, alkalinity, nitrate, and sulfate concentrations were measured. In situ bioremediation techniques are much less expensive and significantly lower in maintenance than traditional ex situ pump-and-treat systems. This is the first field trial conducted on the east coast of the United States, the first trial performed in an acidic aquifer, and the first demonstration of treating in situ perchlorate levels in excess of 200 mg/L. This project provides new and valuable information concerning the application of bioremediation for in situ perchlorate treatment.
Author: Randall J. Cramer Publisher: ISBN: 9781423514664 Category : Languages : en Pages : 80
Book Description
The Applied Technology Department at the Indian Head Division, Naval Surface Warfare Center and Shaw Environmental, Inc., have just successfully completed a field demonstration of in situ bioremediation of a groundwater aquifer contaminated with perchlorate. Using a recirculation cell design, naturally occurring microorganisms were stimulated to degrade perchlorate by injecting a food source (lactate) and neutralizing the groundwater acidity with a carbonate buffer. Starting with perchlorate concentrations in excess of 210 mg/L, perchlorate levels were reduced by more than 95% in eight of the nine test plot monitoring wells over the 5 months of sampling. In two of the monitoring wells, the perchlorate levels were lowered to less than 5 ppb. In addition to the perchlorate levels and the pH, alkalinity, nitrate, and sulfate concentrations were measured. In situ bioremediation techniques are much less expensive and significantly lower in maintenance than traditional ex situ pump- and-treat systems. This is the first field trial conducted on the east coast of the United States, the first trial performed in an acidic aquifer, and the first demonstration of treating in situ perchlorate levels in excess of 200 mg/L. This project provides new and valuable information concerning the application of bioremediation for in situ perchlorate treatment.
Author: Hans F. Stroo Publisher: Springer Science & Business Media ISBN: 0387849211 Category : Technology & Engineering Languages : en Pages : 281
Book Description
In the late 1970s and early 1980s, our nation began to grapple with the legacy of past disposal practices for toxic chemicals. With the passage in 1980 of the Comprehensive Environmental Response, Compensation, and Liability Act (CERCLA), commonly known as Superfund, it became the law of the land to remediate these sites. The U. S. Department of Defense (DoD), the nation’s largest industrial organization, also recognized that it too had a legacy of contaminated sites. Historic operations at Army, Navy, Air Force, and Marine Corps facilities, ranges, manufacturing sites, shipyards, and depots had resulted in widespread contamination of soil, groundwater, and sediment. While Superfund began in 1980 to focus on remediation of heavily contaminated sites largely abandoned or neglected by the private sector, the DoD had already initiated its Installation Restoration Program in the mid 1970s. In 1984, the DoD began the Defense Environmental Restoration Program (DERP) for contaminated site assessment and remediation. Two years later, the U. S. Congress codified the DERP and directed the Secretary of Defense to carry out a concurrent program of research, development, and demonstration of innovative remediation technologies. As chronicled in the 1994 National Research Council report, “Ranking Hazardous-Waste Sites for Remedial Action”, our early estimates on the cost and suitability of existing technologies for cleaning up contaminated sites were wildly optimistic. Original estimates, in 1980, projected an average Superfund cleanup cost of a mere $3.
Author: Baohua Gu Publisher: Springer Science & Business Media ISBN: 0387311130 Category : Technology & Engineering Languages : en Pages : 413
Book Description
Provides a detailed description of perchlorate chemistry and recent advances in innovative remediation technologies for perchlorate contamination and their pros and cons Additionally, the first book to describe the natural occurrence of perchlorate and its unique isotopic signatures for environmental forensics and its detection in the environment, particularly the real-time analysis using surface enhanced Raman spectroscopy
Author: Kathleen Sellers Publisher: CRC Press ISBN: 1482275120 Category : Science Languages : en Pages : 226
Book Description
The development of analytical methods for identifying widespread perchlorate contamination brought about an explosion of research into the environmental problems and their potential solutions along with a corresponding increase in the availability of information. Unlike reference works that focus on only a few aspects of this contaminant, Perchlora
Author: Peter G. Chosa Publisher: ISBN: 9781423518594 Category : Bioremediation Languages : en Pages : 193
Book Description
Perchlorate contaminated groundwater is rapidly becoming a significant environmental remediation issue for the Department of Defense. In this study, an existing numerical model that simulates the operation of a Horizontal Flow Treatment Well (HFTW) system to effect the in situ biodegradation of perchlorate through the addition of an electron donor is modified to include a submodel that describes bioclogging. Bioclogging restricts flow out of the HFTW due to the accumulation of biomass directly adjacent to the well. The modified model is then applied to an existing perchlorate contaminated site that will be used for an evaluation of the HFTW technology. Simulations were conducted to determine the impact of altering various engineered parameters on HFTW performance. Simulation results indicate that higher time averaged electron donor concentrations and HFTW pumping rates lead to more perchlorate degradation in terms of total mass of perchlorate removed. Simulation results also indicate that varying the electron donor addition schedule has little impact on HFTW performance. The simulations conducted in this study show that, regardless of the engineered parameter values, bioclogging does not impact the ability of the HFTW technology to effect in situ biodegradation of perchlorate at the evaluation site.
Author: Mark R. Knarr Publisher: ISBN: 9781423502609 Category : Bioremediation Languages : en Pages : 112
Book Description
Combining horizontal flow treatment wells (HFTWs) with in situ biodegradation is an innovative approach with the potential to remediate perchlorate-contaminated groundwater. A technology model was recently developed that combines the groundwater flow induced by HFTWs with in situ biodegradation processes that result from using the HFTWs to mix electron donor into perchlorate-contaminated groundwater. A field demonstration of this approach is planned to begin this year. In order to apply the technology in the field, project managers need to understand how contaminated site conditions and technology design parameters impact technology performance. One way to gain this understanding is to use the technology model to select engineering design parameters that optimize performance under given site conditions. In particular, a project manager desires to design a system that: 1) maximizes perchlorate destruction; 2) minimizes treatment expense; and 3) attains regulatory limits on down gradient contaminant concentrations. Unfortunately, for a relatively complex technology with a number of engineering design parameters to determine, as well as multiple objectives, system optimization is not straightforward. In this study, a multi-objective genetic algorithm (MOGA) is used to determine design parameter values (flow rate, well spacing, concentration of injected electron donor, and injection schedule) that optimize the first two objectives noted; to maximize perchlorate destruction while minimizing cost. Four optimization runs are performed, using two different remediation time spans (300 and 600 days) for two different sets of site conditions. Results from all four optimization runs indicate that the relationship between perchlorate mass removal and operating cost is positively correlated and nonlinear.
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Author: Randall J. Cramer
Author: Hans F. Stroo
Author: Baohua Gu
Author: Kathleen Sellers
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Author: Peter G. Chosa
Author: Mark R. Knarr