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Fabrication and characterisation of multilayer thin film using self assembly of colloidal gold and silica nanoparticles

Fabrication and characterisation of multilayer thin film using self assembly of colloidal gold and silica nanoparticles PDF Author: Zaheer Abbas Khan
Publisher: GRIN Verlag
ISBN: 3668243042
Category : Science
Languages : en
Pages : 114

Book Description
Doctoral Thesis / Dissertation from the year 2011 in the subject Materials Science, Asian Insitute of Technology, language: English, abstract: A novel approach of multilayered thin film based on layer-by-layer deposition using colloidal nanoparticles was carried out in this work. The films were made by the self-assembly of oppositely charged metal and dielectric nanoparticles, alternately capped with polymers. Synthesized colloidal suspensions of gold nanoparticles (~20nm) and silica nanoparticles (~30nm) were used as the building blocks for the self-organisation of the films. Capping with PDDA and chitosan was used effectively to control the optical absorption of the surface plasmon resonance peaks of the gold nanoparticles. Using different combinations of layer formation, absorption characteristics in the near-ultraviolet (NUV), green and blue region were controlled through capping and varying the thickness of the film. Capping with chitosan or PDDA reduced the absorption peak of the coated silica nanoparticles in a similar fashion. Peak absorption in the UV range was achieved by assembling bare silica nanoparticles layers onto layers of gold nanoparticles. Transmission color was controlled (less than 1% color distance per added bi-layer) by changing the film thickness. Optical modeling of multilayer thin films constructed with oppositely charged nanoparticles helped us to understand phenomenon such as surface plasmon resonance, absorbance, transmittance and reflectance. Maxwell-Garnett effective medium theory in this case is applied in quasi-static limit to multilayer composite consisting of host material silica and inclusion material gold nanoparticles. Maxwell Garnett optical simulations is correlated with experimental spectra obtained for the thin film composites. The thickness of layers, size and spacing of metal inclusion is varied to alter the optical properties for the required device applications. The multilayered thin film of gold and silica resembles a structure consisting of large charge sheets of metal separated by a dielectric layer. When the applied electric potential reaches a threshold value, it drives the electrons to tunnel through the charge sheets producing a rectification effect. Therefore current-voltage measurements of the multilayer thin films were performed to calculate the threshold voltages. The electrical capacitance in these multilayer devices was modified with the change in thickness of the dielectric layers between two conducting layers and calculated by capacitance-voltage measurements of multilayer stack. [...]

Fabrication and characterisation of multilayer thin film using self assembly of colloidal gold and silica nanoparticles

Fabrication and characterisation of multilayer thin film using self assembly of colloidal gold and silica nanoparticles PDF Author: Zaheer Abbas Khan
Publisher: GRIN Verlag
ISBN: 3668243042
Category : Science
Languages : en
Pages : 114

Book Description
Doctoral Thesis / Dissertation from the year 2011 in the subject Materials Science, Asian Insitute of Technology, language: English, abstract: A novel approach of multilayered thin film based on layer-by-layer deposition using colloidal nanoparticles was carried out in this work. The films were made by the self-assembly of oppositely charged metal and dielectric nanoparticles, alternately capped with polymers. Synthesized colloidal suspensions of gold nanoparticles (~20nm) and silica nanoparticles (~30nm) were used as the building blocks for the self-organisation of the films. Capping with PDDA and chitosan was used effectively to control the optical absorption of the surface plasmon resonance peaks of the gold nanoparticles. Using different combinations of layer formation, absorption characteristics in the near-ultraviolet (NUV), green and blue region were controlled through capping and varying the thickness of the film. Capping with chitosan or PDDA reduced the absorption peak of the coated silica nanoparticles in a similar fashion. Peak absorption in the UV range was achieved by assembling bare silica nanoparticles layers onto layers of gold nanoparticles. Transmission color was controlled (less than 1% color distance per added bi-layer) by changing the film thickness. Optical modeling of multilayer thin films constructed with oppositely charged nanoparticles helped us to understand phenomenon such as surface plasmon resonance, absorbance, transmittance and reflectance. Maxwell-Garnett effective medium theory in this case is applied in quasi-static limit to multilayer composite consisting of host material silica and inclusion material gold nanoparticles. Maxwell Garnett optical simulations is correlated with experimental spectra obtained for the thin film composites. The thickness of layers, size and spacing of metal inclusion is varied to alter the optical properties for the required device applications. The multilayered thin film of gold and silica resembles a structure consisting of large charge sheets of metal separated by a dielectric layer. When the applied electric potential reaches a threshold value, it drives the electrons to tunnel through the charge sheets producing a rectification effect. Therefore current-voltage measurements of the multilayer thin films were performed to calculate the threshold voltages. The electrical capacitance in these multilayer devices was modified with the change in thickness of the dielectric layers between two conducting layers and calculated by capacitance-voltage measurements of multilayer stack. [...]

Multilayer Thin Films

Multilayer Thin Films PDF Author: Sukumar Basu
Publisher: BoD – Books on Demand
ISBN: 1789854377
Category : Technology & Engineering
Languages : en
Pages : 274

Book Description
This book, "Multilayer Thin Films-Versatile Applications for Materials Engineering", includes thirteen chapters related to the preparations, characterizations, and applications in the modern research of materials engineering. The evaluation of nanomaterials in the form of different shapes, sizes, and volumes needed for utilization in different kinds of gadgets and devices. Since the recently developed two-dimensional carbon materials are proving to be immensely important for new configurations in the miniature scale in the modern technology, it is imperative to innovate various atomic and molecular arrangements for the modifications of structural properties. Of late, graphene and graphene-related derivatives have been proven as the most versatile two-dimensional nanomaterials with superb mechanical, electrical, electronic, optical, and magnetic properties. To understand the in-depth technology, an effort has been made to explain the basics of nano dimensional materials. The importance of nano particles in various aspects of nano technology is clearly indicated. There is more than one chapter describing the use of nanomaterials as sensors. In this volume, an effort has been made to clarify the use of such materials from non-conductor to highly conducting species. It is expected that this book will be useful to the postgraduate and research students as this is a multidisciplinary subject.

Nanoscale Materials

Nanoscale Materials PDF Author: Luis M. Liz-Marzán
Publisher: Springer Science & Business Media
ISBN: 0306481081
Category : Science
Languages : en
Pages : 506

Book Description
Organized nanoassemblies of inorganic nanoparticles and organic molecules are building blocks of nanodevices, whether they are designed to perform molecular level computing, sense the environment or improve the catalytic properties of a material. The key to creation of these hybrid nanostructures lies in understanding the chemistry at a fundamental level. This book serves as a reference book for researchers by providing fundamental understanding of many nanoscopic materials.

Biopolymer Membranes and Films

Biopolymer Membranes and Films PDF Author: Mariana Agostini De Moraes
Publisher: Elsevier
ISBN: 0128181354
Category : Technology & Engineering
Languages : en
Pages : 658

Book Description
Biopolymer Membranes and Films: Health, Food, Environment, and Energy Applications presents the latest techniques for the design and preparation of biopolymer-based membranes and films, leading to a range of cutting-edge applications. The first part of the book introduces the fundamentals of biopolymers, two-dimensional systems, and the characterization of biopolymer membranes and films, considering physicochemical, mechanical and barrier properties. Subsequent sections are organized by application area, with each chapter explaining how biopolymer-based membranes or films can be developed for specific innovative uses across the health, food, environmental and energy sectors. This book is a valuable resource for researchers, scientists and advanced students involved in biopolymer science, polymer membranes and films, polymer chemistry and materials science, as well as for those in industry and academia who are looking to develop materials for advanced applications in the health, food science, environment or energy industries. - Presents detailed coverage of a range of novel applications in key strategic areas across health, food, environment and energy - Considers the difficulties associated with two-dimensional materials - Assists the reader in selecting the best materials and properties for specific applications - Helps researchers, scientists and engineers combine the enhanced properties of membranes and films with the sustainable characteristics of biopolymer-based materials

Semiconductor Nanocrystal Quantum Dots

Semiconductor Nanocrystal Quantum Dots PDF Author: Andrey Rogach
Publisher: Springer Science & Business Media
ISBN: 3211752374
Category : Technology & Engineering
Languages : en
Pages : 374

Book Description
This is the first book to specifically focus on semiconductor nanocrystals, and address their synthesis and assembly, optical properties and spectroscopy, and potential areas of nanocrystal-based devices. The enormous potential of nanoscience to impact on industrial output is now clear. Over the next two decades, much of the science will transfer into new products and processes. One emerging area where this challenge will be very successfully met is the field of semiconductor nanocrystals. Also known as colloidal quantum dots, their unique properties have attracted much attention in the last twenty years.

Chemical Abstracts

Chemical Abstracts PDF Author:
Publisher:
ISBN:
Category : Chemistry
Languages : en
Pages : 2540

Book Description


Protein Architecture

Protein Architecture PDF Author: Lvov/Mohwald
Publisher: CRC Press
ISBN: 9780824782368
Category : Medical
Languages : en
Pages : 410

Book Description
Considers the design, structure and biological activity of ordered films comprised of proteins, polymers, amphiphile molecules and colloidal particles, and assesses the ability of protein/polyion multilayers to mimic living organelles. The book discusses how to reach predetermined locations with proteins and orient molecules while preserving their bioactivity.

Encyclopedia of Surface and Colloid Science

Encyclopedia of Surface and Colloid Science PDF Author: P. Somasundaran
Publisher: CRC Press
ISBN: 9780849396038
Category : Science
Languages : en
Pages : 1014

Book Description


Encyclopedia of Interfacial Chemistry

Encyclopedia of Interfacial Chemistry PDF Author:
Publisher: Elsevier
ISBN: 0128098945
Category : Science
Languages : en
Pages : 5276

Book Description
Encyclopedia of Interfacial Chemistry: Surface Science and Electrochemistry, Seven Volume Set summarizes current, fundamental knowledge of interfacial chemistry, bringing readers the latest developments in the field. As the chemical and physical properties and processes at solid and liquid interfaces are the scientific basis of so many technologies which enhance our lives and create new opportunities, its important to highlight how these technologies enable the design and optimization of functional materials for heterogeneous and electro-catalysts in food production, pollution control, energy conversion and storage, medical applications requiring biocompatibility, drug delivery, and more. This book provides an interdisciplinary view that lies at the intersection of these fields. Presents fundamental knowledge of interfacial chemistry, surface science and electrochemistry and provides cutting-edge research from academics and practitioners across various fields and global regions

Advances in Unconventional Lithography

Advances in Unconventional Lithography PDF Author: Gorgi Kostovski
Publisher: BoD – Books on Demand
ISBN: 9533076070
Category : Science
Languages : en
Pages : 202

Book Description
The term Lithography encompasses a range of contemporary technologies for micro and nano scale fabrication. Originally driven by the evolution of the semiconductor industry, lithography has grown from its optical origins to demonstrate increasingly fine resolution and to permeate fields as diverse as photonics and biology. Today, greater flexibility and affordability are demanded from lithography more than ever before. Diverse needs across many disciplines have produced a multitude of innovative new lithography techniques. This book, which is the final instalment in a series of three, provides a compelling overview of some of the recent advances in lithography, as recounted by the researchers themselves. Topics discussed include nanoimprinting for plasmonic biosensing, soft lithography for neurobiology and stem cell differentiation, colloidal substrates for two-tier self-assembled nanostructures, tuneable diffractive elements using photochromic polymers, and extreme-UV lithography.