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Author: JS Miller (ed)Publisher:
ISBN:
Category :
Languages : en
Pages :
Book Description
Extended Linear Chain Compounds [Vols 1-3].
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Author: JS Miller (ed)Extended Linear Chain Compounds
Author: Joel S. MillerPublisher: Springer Science & Business Media
ISBN: 1461332494
Category : Mathematics
Languages : en
Pages : 491
Book Description
Linear chain substances span a large cross section of contemporary chemistry ranging from covalent polymers, to organic charge transfer com plexes to nonstoichiometric transition metal coordination complexes. Their commonality, which coalesced intense interest in the theoretical and exper imental solid state physics/chemistry communities, was based on the obser vation that these inorganic and organic polymeric substrates exhibit striking metal-like electrical and optical properties. Exploitation and extension of these systems has led to the systematic study of both the chemistry and physics of highly and poorly conducting linear chain substances. To gain a salient understanding of these complex materials rich in anomalous aniso tropic electrical, optical, magnetic, and mechanical properties, the conver gence of diverse skills and talents was required. The constructive blending of traditionally segregated disciplines such as synthetic and physical organic, inorganic, and polymer chemistry, crystallography, and theoretical and ex perimental solid state physics has led to the timely development of a truly interdisciplinary science. This is evidenced in the contributions of this monograph series. Within the theme of Extended Linear Chain Compounds, experts in important, but varied, facets of the discipline have reflected upon the progress that has been made and have cogently summarized their field of specialty. Consequently, up-to-date reviews of numerous and varied aspects of "extended linear chain compounds" have developed. Within these vol umes, numerous incisive contributions covering all aspects of the diverse linear chain substances have been summarized.
Extended Linear Chain Compounds
Author: Joel S. MillerPublisher: Springer Science & Business Media
ISBN: 1468441752
Category : Mathematics
Languages : en
Pages : 569
Book Description
Linear chain substances span a large cross section of contemporary chemis try ranging from covalent polymers, organic charge transfer complexes to nonstoichiometric transition metal coordination complexes. Their common ality, which coalesced intense interest in the theoretical and experimental solid-state-physics/chemistry communities, was based on the observation that these inorganic and organic polymeric substrates exhibit striking metal-like electrical and optical properties. Exploitation and extension of these systems has led to the systematic study of both the chemistry and physics of highly and poorly conducting linear chain substances. To gain a salient understanding of these complex materials rich in anomalous anisotropic electrical, optical, magnetic, and mechanical properties, the convergence of diverse skills and talents was required. The constructive blending of traditionally segregated disciplines such as synthetic and physical organic, inorganic, and polymer chemistry, crystallography, and theoretical and experimental solid state physics has led to the timely devel opment of a truly interdisciplinary science. This is evidenced in the contri butions of this monograph series. Within the theme of Extended Linear Chain Compounds, experts in important, but varied, facets of the discipline have reflected upon the progress that has been made and have cogently summarized their field of specialty. Consequently, up-to-date reviews of numerous and varied aspects of "extended linear chain compounds" has developed. Within these volumes, numerous incisive contributions covering all aspects of the diverse linear chain substances have been summarized. I am confident that assimilation of the state-of-the-art and clairvoy ance will be rewarded with extraordinary developments in the near future.
Extended Linear Chain Compounds
Author: Joel S. MillerPublisher: Springer
ISBN: 9781468441772
Category : Mathematics
Languages : en
Pages : 580
Book Description
Linear chain substances span a large cross section of contemporary chemis try ranging from covalent polymers, organic charge transfer complexes to nonstoichiometric transition metal coordination complexes. Their common ality, which coalesced intense interest in the theoretical and experimental solid-state-physics/chemistry communities, was based on the observation that these inorganic and organic polymeric substrates exhibit striking metal-like electrical and optical properties. Exploitation and extension of these systems has led to the systematic study of both the chemistry and physics of highly and poorly conducting linear chain substances. To gain a salient understanding of these complex materials rich in anomalous anisotropic electrical, optical, magnetic, and mechanical properties, the convergence of diverse skills and talents was required. The constructive blending of traditionally segregated disciplines such as synthetic and physical organic, inorganic, and polymer chemistry, crystallography, and theoretical and experimental solid state physics has led to the timely devel opment of a truly interdisciplinary science. This is evidenced in the contri butions of this monograph series. Within the theme of Extended Linear Chain Compounds, experts in important, but varied, facets of the discipline have reflected upon the progress that has been made and have cogently summarized their field of specialty. Consequently, up-to-date reviews of numerous and varied aspects of "extended linear chain compounds" has developed. Within these volumes, numerous incisive contributions covering all aspects of the diverse linear chain substances have been summarized. I am confident that assimilation of the state-of-the-art and clairvoy ance will be rewarded with extraordinary developments in the near future.
Extended Linear Chain Compounds
Author: Joel S. MillerExtended Linear Chain Compounds
Author: Joel MillerPublisher: Springer
ISBN: 9781461332503
Category :
Languages : en
Pages : 500
Book Description
Extended Linear Chain Compounds
Author: Joel S. MillerPublisher: Springer
ISBN: 9781468439328
Category : Mathematics
Languages : en
Pages : 0
Book Description
Linear chain substances span a large cross section of contemporary chemistry ranging from covalent polymers, to organic charge transfer com plexes to nonstoichiometric transition metal coordination complexes. Their commonality, which coalesced intense interest in the theoretical and exper imental solid state physics/chemistry communities, was based on the obser vation that these inorganic and organic polymeric substrates exhibit striking metal-like elec,trical and optical properties. Exploitation and extension of these systems has led to the systematic study of both the chemistry and physics of highly and poorly conducting linear chain substances. To gain a salient understanding of these complex materials rich in anomalous aniso tropic electrical, optical, magnetic, and mechanical properties, the conver gence of diverse skills and talents was required. The constructive blending of traditionally segregated disciplines such as synthetic and physical organic, inorganic, and polymer chemistry, crystallography, and theoretical and ex perimental solid state physics has led to the timely development of a truly interdisciplinary science. This is evidenced in the contributions of this monograph series. Within the theme of Extended Linear Chain Compounds, experts in important, but varied, facets of the discipline have reflected upon the progress that has been made and have cogently summarized their field of speciality. Consequently, up-to-date reviews of numerous and varied aspects of "extended linear chain compounds" have developed. Within these vol umes, numerous incisive contributions covering all aspects of the diverse linear chain substances have been summarized.
Extended Linear Chain Compounds
Author: Inorganic Reactions and Methods, The Formation of Bonds to Transition and Inner-Transition Metals
Author: A. P. HagenPublisher: John Wiley & Sons
ISBN: 0470145501
Category : Science
Languages : en
Pages : 727
Book Description
Boasting numerous industrial applications, inorganic chemistry forms the basis for research into new materials and bioinorganic compounds such as calcium that act as biological catalysts. Now complete, this highly acclaimed series presents current knowledge in all areas of inorganic chemistry, including chemistry of the elements; organometallic, polymeric and solid-state materials; and compounds relevant to bioinorganic chemistry.
Material Designs and New Physical Properties in MX- and MMX-Chain Compounds
Author: Masahiro YamashitaPublisher: Springer Science & Business Media
ISBN: 3709113172
Category : Science
Languages : en
Pages : 275
Book Description
This is the first book to comprehensively address the recent developments in both the experimental and theoretical aspects of quasi-one-dimensional halogen-bridged mono- (MX) and binuclear metal (MMX) chain complexes of Pt, Pd and Ni. These complexes have one-dimensional electronic structures, which cause the various physical properties as well as electronic structures. In most MX-chain complexes, the Pt and Pd units are in M(II)-M(IV) mixed valence or charge density wave (CDW) states due to electron-phonon interactions, and Ni compounds are in Ni(III) averaged valence or Mott-Hubbard states due to the on-site Coulomb repulsion. More recently, Pd(III) Mott-Hubbard (MH) states have been realized in the ground state by using the chemical pressure. Pt and Pd chain complexes undergo photo-induced phase transitions from CDW to MH or metal states, and Ni chain complexes undergo photo-induced phase transitions from MH to metal states. Ni chain complexes with strong electron correlations show tremendous third-order optical nonlinearity and nonlinear electrical conductivities. They can be explained theoretically by using the extended Peierls-Hubbard model. For MMX-chain complexes, averaged valence, CDW, charge polarization, and alternating charge polarization states have been realized by using chemical modification and external stimuli, such as temperature, photo-irradiation, pressure, and water vapor. All of the electronic structures and phase transitions can be explained theoretically.