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Author: Jens Timmermann Publisher: Cuvillier Verlag ISBN: 3736988753 Category : Technology & Engineering Languages : en Pages : 130
Book Description
Gases have to be specifically mixed with a continuous liquid phase to perform a reaction with high yield and selectivity. The time scales of mixing are determined by the transport processes in the boundary layer close to the phase boundary and by bubble swarm turbulence. For clarification of the local mass transfer in bubbly flows, an experimental setup is developed and successfully used to investigate single rectilinear (spherical), helical (ellipsoid) and irregular rising bubbles with and without chemical reaction. Therefore, the time resolved scanning laser induced fluorescence technique is further developed and applied for the first time to bubbly flows to allow new insights in the mass transfer processes.
Author: Jens Timmermann Publisher: Cuvillier Verlag ISBN: 3736988753 Category : Technology & Engineering Languages : en Pages : 130
Book Description
Gases have to be specifically mixed with a continuous liquid phase to perform a reaction with high yield and selectivity. The time scales of mixing are determined by the transport processes in the boundary layer close to the phase boundary and by bubble swarm turbulence. For clarification of the local mass transfer in bubbly flows, an experimental setup is developed and successfully used to investigate single rectilinear (spherical), helical (ellipsoid) and irregular rising bubbles with and without chemical reaction. Therefore, the time resolved scanning laser induced fluorescence technique is further developed and applied for the first time to bubbly flows to allow new insights in the mass transfer processes.
Author: Michael Schlüter Publisher: Springer Nature ISBN: 3030723615 Category : Technology & Engineering Languages : en Pages : 642
Book Description
This book presents experimental and numerical methods that have been developed during six years of targeted research within the DFG priority program SPP 1740, elucidating the interaction between hydrodynamics, mass transfer and transport as well as chemical reactions in bubbly flows. A special feature of this book is its focus on an interdisciplinary research approach with contributions from chemistry, mathematics and engineering sciences, providing enhanced or novel experimental methods, models and numerical simulations. This book provides fundamental knowledge to students about the current state of knowledge regarding transport processes in reactive bubbly flows as well as to scientists, emphasizing pressing research questions and further current demands for fundamental research. Engineers from the chemical industries will get valuable insights into relevant gas-liquid processes and benefit from recommendations concerning the design of gas-liquid reactors and laboratory experiments for studying the performance of gas-liquid reactions in their own lab.
Author: Sven Kastens Publisher: Cuvillier Verlag ISBN: 3736964048 Category : Technology & Engineering Languages : en Pages : 190
Book Description
Gas / liquid contact apparatuses are widely used in chemical, biochemical or pharmaceutical industry to provide and transfer gas species as reactant from the gaseous phase to pre-dissolved reactants in the liquid phase enabling a preferred reaction. The global and local transport are complex interlinked processes and therefore in practice in reactor design industry, mostly empirically correlated. For a secure control of the overall process and a more efficient reactor design, the local transport processes at gas / liquid interfaces need to be investigated in complexity reduced systems to be understood. Elongated bubbles, Taylor bubbles, in vertical channels 5.5 < D < 8 mm overcome the problem of dynamic shape deformation, complex 3D rise trajectories and they have a volume independent rise velocity, which make them the ideal experiment for reliable and reproducible investigations. Detailed optical measurements of global and local processes via high-speed Shadowgraphy, 2D2C PIV and p-2D LIF give new insights into the dependency of local bubble shape and global terminal rise velocity, establish a Sherwood correlation of shrinking CO2 bubbles in various channel sizes and shows the coupling of local transport phenomena at the bubble interface and the mixing in the wake region.
Author: Simon Matthes Publisher: Cuvillier Verlag ISBN: 3736965117 Category : Technology & Engineering Languages : en Pages : 154
Book Description
Multiphase contact apparatuses are widely used in the chemical and biocatalytic process industry in which a gaseous reactant has to be supplied. The achievement of high mass transfer rates with regard to process efficiency is mostly challenging. In this work a novel aeration technique based on fine bubbles with diameters smaller 100 µm is experimentally analyzed, providing large interfacial areas for the mass transfer process. The experiments show the benefit of using fine bubbles by reaching significantly higher mass transfer rates compared to conventional aeration. Especially stirred tank reactors prove to be most suitable for fine bubble aeration. Finally, models are developed, describing the mass transfer characteristics at microscales.
Author: Karl Minsker Publisher: CRC Press ISBN: 9067644099 Category : Technology & Engineering Languages : en Pages : 184
Book Description
This book deals with the fundamental laws of passing of fast liquid-phase chemical as well as heat and mass transfer processes in turbulent flows. The fundamental laws of passing of fast liquid-phase chemical and also heat and mass transfer processes in turbulent flows are considered in the book. Development of a macrokinetics approach is generalized to the analysis of fast chemical reactions mainly based on an example of cationic isobutylene polymerization, which falls into to a new class of liquid-phase processes. The ways of decision of the hydrodynamical, thermal and kinetic movement’s equations of reaction mixture in which the fast exothermic chemical reaction runs are described. The principles and laws of formation of the essentially new mode of quasi-plug-flow mode are considered in turbulent flows ensuring quasi-isothermal conditions in zone reaction. The principles of work and area of industrial use of tubular turbulent devices cylindrical reactor, divergent-covergent reactor, shell-and-tube reactor, and reactor with fractional introduction of reactants are considered.
Author: Bryan Philip Levitt Publisher: Springer ISBN: Category : Science Languages : en Pages : 358
Book Description
The chapters in this book are devoted to the elementary reactions of small molecules in the gas phase, with some emphasis on reactions important in combustion. The first three chapters cover experimental measurements made at high temperatures, mainly using shock waves and flames; the final chapter describes discharge flow methods near room temperature. The authors-all active in the fields they describe were asked to aim at a level intermediate between a textbook and a review, designed for readers not already familiar with this branch of chemical kinetics. We hope the book will prove especially useful to research workers in related subjects, to research students, and perhaps as source material for the preparation of lectures. The examples have been chosen to illustrate the theoretical basis of the topics rather than attempt a complete coverage. Professors Wagner and Troe describe the remarkable progress made in recent years in measuring dissociation rates for small molecules. Tests ofunimolecular reaction theories are usually made in the 'fall-off' region of pressure: the kinetics change from first order to second order as the pressure is reduced. For large molecules this region lies below atmospheric pressure and is relatively easily accessible. For molecules with four or less atoms, however, the fall-off region lies well above atmospheric pressure: it has been explored using the high pressure shock tube techniques developed by the authors.
Author: Hugo de Lasa Publisher: Springer Science & Business Media ISBN: 9400944004 Category : Science Languages : en Pages : 839
Book Description
Today's frustrations and anxieties resulting from two energy crises in only one decade, show us the problems and fragility of a world built on high energy consumption, accustomed to the use of cheap non-renewable energy and to the acceptance of eXisting imbalances between the resources and demands of countries. Despite all these stressing factors, our world is still hesitatins about the urgency of undertaking new and decisive research that could stabilize our future, Could this trend change in the near future? In our view, two different scenarios are possible. A renewed energy tension could take place with an unpredictable timing mostly related to political and economic factors, This could bring again scientists and technologists to a new state of shock and awaken our talents, A second interesting and beneficial scenario could result from the positive influence of a new generation of researchers that with or without immediate crisis, acting both in industry and academia, will face the challenge of developing technologies and processes to pave the way to a less vulnerable society, Because Chemical Reactor Design and Technology activities are at the heart of these required new technologies the timeliness of the NATO-Advanced Study Institute at the University of Western Ontario, London, was very appropriate.
Author: Jens Timmermann
Author: Jens Timmermann
Author: Michael Schlüter
Author: Sven Kastens
Author: Simon Matthes
Author: Karl Minsker
Author: Bryan Philip Levitt
Author: John N. Bradley
Author: Hugo de Lasa
Author: United States. Energy Research and Development Administration
Author: