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Evaluation of Passive Samplers for the Monitoring of Contaminants in Sediment and Water

Evaluation of Passive Samplers for the Monitoring of Contaminants in Sediment and Water PDF Author: Martin Larsen
Publisher: Nordic Council of Ministers
ISBN: 9289319143
Category : Contaminated sediments
Languages : en
Pages : 103

Book Description
Passive samplers spiked with performance reference compounds (PRC) were prepared in Holland, and deployed at 9 sites in the Nordic countries and Greenland. Mussels were collected at the same sites to compare passive sampler results with the mussel-watch approach usually applied in national monitoring. Sediments were sampled from 6 sites, and analysed both by total methods and passive samplers for pore water concentration. From the spiked PRCs, sampling rates was calculated, and used to determine water phase concentration of PAHs and other organic compounds with a high octanol-water partitioning coefficient. The project has shown that silicone passive samplers can be used for monitoring programmes, and development of guidelines and quality assurance of analysis are underway. Within the next 2-3 years it could become part of the monitoring strategy of OSPAR, EU and the Nordic Countries.

Evaluation of Passive Samplers for the Monitoring of Contaminants in Sediment and Water

Evaluation of Passive Samplers for the Monitoring of Contaminants in Sediment and Water PDF Author: Martin Larsen
Publisher: Nordic Council of Ministers
ISBN: 9289319143
Category : Contaminated sediments
Languages : en
Pages : 103

Book Description
Passive samplers spiked with performance reference compounds (PRC) were prepared in Holland, and deployed at 9 sites in the Nordic countries and Greenland. Mussels were collected at the same sites to compare passive sampler results with the mussel-watch approach usually applied in national monitoring. Sediments were sampled from 6 sites, and analysed both by total methods and passive samplers for pore water concentration. From the spiked PRCs, sampling rates was calculated, and used to determine water phase concentration of PAHs and other organic compounds with a high octanol-water partitioning coefficient. The project has shown that silicone passive samplers can be used for monitoring programmes, and development of guidelines and quality assurance of analysis are underway. Within the next 2-3 years it could become part of the monitoring strategy of OSPAR, EU and the Nordic Countries.

Evaluation of Passive Samplers for the Monitoring of Contaminants in Sediment and Water

Evaluation of Passive Samplers for the Monitoring of Contaminants in Sediment and Water PDF Author: Martin Larsen
Publisher:
ISBN: 9789289332309
Category : Contaminated sediments
Languages : en
Pages : 81

Book Description
Passive samplers spiked with performance reference compounds (PRC) were prepared in Holland, and deployed at 9 sites in the Nordic countries and Greenland. Mussels were collected at the same sites to compare passive sampler results with the mussel-watch approach usually applied in national monitoring. Sediments were sampled from 6 sites, and analysed both by total methods and passive samplers for pore water concentration. From the spiked PRCs, sampling rates was calculated, and used to determine water phase concentration of PAHs and other organic compounds with a high octanol-water partitioning coefficient. The project has shown that silicone passive samplers can be used for monitoring programmes, and development of guidelines and quality assurance of analysis are underway. Within the next 2-3 years it could become part of the monitoring strategy of OSPAR, EU and the Nordic Countries.

TemaNord

TemaNord PDF Author: Martin Mørk Larsen
Publisher:
ISBN:
Category :
Languages : un
Pages :

Book Description


TemaNord

TemaNord PDF Author: Martin Mørk Larsen
Publisher:
ISBN:
Category :
Languages : en
Pages :

Book Description


Passive Sampling Techniques in Environmental Monitoring

Passive Sampling Techniques in Environmental Monitoring PDF Author: Richard Greenwood
Publisher: Elsevier
ISBN: 0080489508
Category : Science
Languages : en
Pages : 487

Book Description
Monitoring pollutants in air, soil and water is a routine requirement in the workplace, and in the wider environment. Passive samplers can provide a representative picture of levels of pollutants over a period of time from days to months by measuring the average concentrations to which they have been exposed. Air monitors are widely used, for instance to measure the exposure of workers to volatile compounds, but also for monitoring the fate of pollutants in the atmosphere. Passive sampling devices are now becomining increasingly used to monitor pollutants in rivers, coastal waters and ground water where contamination results from sources such as domestic and industrial discharges, and the use of agrochemicals. Passive Sampling Techniques in Environmental Monitoring provides a timely collection of information on a set of techniques that help monitor the quality of air, surface and ground waters. Passive sampling can provide an inexpensive means of obtaining a representative picture of quality over a period of time, even where levels of pollutants fluctuate due to discontinuous discharges or seasonal application of chemicals such as pesticides. Recent changes in legislation have increased the pressure to obtain better information than that provided by classical infrequent spot sampling.Brought together in one source, this book looks at the performance of a range of devices for the passive sampling of metals, and of non-polar and polar organic chemicals in air and in water. The strengths and weaknesses and the range of applicability of the technology are considered.* Comprehensive review of passive sampling - covering air, water and majority of available technologies in one volume* Chapters written by international specialist experts * Covers theory and applications, providing background information and guidelines for use in the field

Bioaccumulation Using Surrogate Samplers (Bass)

Bioaccumulation Using Surrogate Samplers (Bass) PDF Author:
Publisher:
ISBN:
Category :
Languages : en
Pages : 6

Book Description
DOE sites conduct traditional environmental monitoring programs that require collecting, processing, and analyzing water, sediment, and fish samples. However, recently developed passive sampling technologies, such as Diffusive Gradient in Thin films (DGT), may measure the chemical phases that are available and toxic to organisms (the bioavailable fraction), thereby producing more accurate and economical results than traditional methods. Our laboratory study showed that dissolved copper concentrations measured by DGT probes were strongly correlated with the uptake of copper by Lumbriculus variegatus, an aquatic worm, and with concentrations of copper measured by conventional methods. Dissolved copper concentrations in DGT probes increased with time of exposure, paralleling the increase in copper with time that ocurred in Lumbriculus. Additional studies with a combination of seven dissolved metals showed similar results. These findings support the use of DGT as a biomimetic monitoring tool and provide a basis for refinement of these methods for cost-effective environmental monitoring at DOE sites.

Monitors of Organic Chemicals in the Environment

Monitors of Organic Chemicals in the Environment PDF Author: James N. Huckins
Publisher: Springer Science & Business Media
ISBN: 038735414X
Category : Science
Languages : en
Pages : 229

Book Description
The authors of this book are pioneers of the passive, integrative sampling approach and developers of globally applied semipermeable membrane devices (SPMDs). The book will boost understanding of how passive samplers such as SPMD function by examining basic exchange processes that mediate the concentration of SVOCs in a sampling matrix. The book delineates fundamental theory and modeling techniques, while providing a practical guide for its proper application.

Water Quality Assessments

Water Quality Assessments PDF Author: Deborah V Chapman
Publisher: CRC Press
ISBN: 0419215905
Category : Science
Languages : en
Pages : 658

Book Description
This guidebook, now thoroughly updated and revised in its second edition, gives comprehensive advice on the designing and setting up of monitoring programmes for the purpose of providing valid data for water quality assessments in all types of freshwater bodies. It is clearly and concisely written in order to provide the essential information for all agencies and individuals responsible for the water quality.

Passive Sampling to Evaluate Performance of in Situ Sediment Remediation

Passive Sampling to Evaluate Performance of in Situ Sediment Remediation PDF Author: Courtney Louanne Thomas
Publisher:
ISBN:
Category :
Languages : en
Pages : 474

Book Description
In situ passive sampling is the use of a polymer sorbent to directly assess freely dissolved concentration (C [subscript free]) profiles within the environment. The primary focus herein is the use of passive sampling methods to detect and quantify persistent hydrophobic organic compounds (HOCs) in sediment porewater and surface water using solid phase microextraction (SPME) profilers with polydimethylsiloxane (PDMS) as the receiving phase sorbent. Contaminated sediment sites pose a unique challenge in terms of remediation and monitoring for several reasons including: the large number of past and ongoing sources, sediment stability, and the extent of contamination. Capping with a clean layer of material, an accepted remediation approach, can reduce risk by stabilizing the underlying sediments, isolating the water column, and reducing contaminant flux. Evaluating cap performance is challenging due to the long time frames associated with migration of HOCs. Additionally, the non-sorbing nature of most caps limits the usefulness of bulk solid measurements. An alternative is the use of concentrations in the interstitial space or porewater to examine contaminant migration in the sediments and cap. Traditionally, porewater concentrations are obtained through a conversion of bulk sediment concentrations using an assumed sediment-water partitioning coefficient. This assumption often leads to a misrepresentation of risk as not all organic carbon is created equal. An alternative is the use of passive sampling with polymer sorbents to estimate the freely available concentration, C [subscript free]. In this work the focus is on the use of solid phase microextraction with polydimethylsiloxane (SPME PDMS) as the sorbent. C [subscript free] is proportional to chemical activity; therefore an accurate measurement of C [subscript free] is necessary for risk assessment and determination of transport mechanisms and ultimately improved management of contaminated sediment sites. A non-equilibrium correction protocol using performance reference compounds (PRCs) was developed to enhance the accuracy of the SPME PDMS method to assess C [subscript free]. The protocol was validated through laboratory experiments and field trials. Deployment times can be reduced without sacrificing accuracy when using the PRC protocol. Furthermore, it was shown that mathematical models of diffusive and advective flux can be fit using parameters determined from PRC desorption. The SPME PDMS with PRCs method was used at three different remediated contaminated sediment sites, Chattanooga Creek, Eagle Harbor, and the West Branch of the Grand Calumet River, to illustrate its utility at evaluating performance of in situ remediation. Overall, the results from laboratory and field studies suggest that SPME PDMS is a valuable tool for evaluating performance of in situ sediment remediation.

Guidelines for the Use of the Semipermeable Membrane Device (Spmd) and the Polar Organic Chemical Integrative Sampler (Pocis) in Environmental Monitoring Studies

Guidelines for the Use of the Semipermeable Membrane Device (Spmd) and the Polar Organic Chemical Integrative Sampler (Pocis) in Environmental Monitoring Studies PDF Author: David A. Alvarez
Publisher: CreateSpace
ISBN: 9781500220174
Category : Technology & Engineering
Languages : en
Pages : 34

Book Description
The success of an environmental monitoring study using passive samplers, or any sampling method, begins in the office or laboratory. Regardless of the specific methods used, the general steps include the formulation of a sampling plan, training of personnel, performing the field (sampling) work, processing the collected samples to recover chemicals of inter- est, analysis of the enriched extracts, and interpretation of the data. Each of these areas will be discussed in the following sections with emphasis on specific considerations with the use of passive samplers.