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Environmental Implications of Phosphate-based Amendments in Heavy Metal Contaminated Alluvial Soil

Environmental Implications of Phosphate-based Amendments in Heavy Metal Contaminated Alluvial Soil PDF Author: John Stephen Weber
Publisher:
ISBN:
Category :
Languages : en
Pages : 104

Book Description
A diverse suite of research has focused on the immobilization of lead (Pb) compounds in soil through the application of phosphate-based amendments that create insoluble Pb compounds. Water quality threats associated with the phosphorus (P) remediation technology are a concern, particularly near riparian areas. This study investigated P fertilizer application rates on metals and P loss via surface runoff following P application to a lead contaminated alluvial soil. Soil was treated with Triple Super Phosphate (TSP) at differing molar ratios of P to Pb: 0:1 (control); 4:1; 8:1; and 16:1. Effluents from treated soils were collected during rainfall simulation (RFS) events at six months and one year post-treatment and analyzed for total and dissolved P and Pb loss. At elevated P treatment levels (8:1, 16:1 P:Pb), P and total Pb concentrations were significantly greater (p

Environmental Implications of Phosphate-based Amendments in Heavy Metal Contaminated Alluvial Soil

Environmental Implications of Phosphate-based Amendments in Heavy Metal Contaminated Alluvial Soil PDF Author: John Stephen Weber
Publisher:
ISBN:
Category :
Languages : en
Pages : 104

Book Description
A diverse suite of research has focused on the immobilization of lead (Pb) compounds in soil through the application of phosphate-based amendments that create insoluble Pb compounds. Water quality threats associated with the phosphorus (P) remediation technology are a concern, particularly near riparian areas. This study investigated P fertilizer application rates on metals and P loss via surface runoff following P application to a lead contaminated alluvial soil. Soil was treated with Triple Super Phosphate (TSP) at differing molar ratios of P to Pb: 0:1 (control); 4:1; 8:1; and 16:1. Effluents from treated soils were collected during rainfall simulation (RFS) events at six months and one year post-treatment and analyzed for total and dissolved P and Pb loss. At elevated P treatment levels (8:1, 16:1 P:Pb), P and total Pb concentrations were significantly greater (p

Phosphate in Soils

Phosphate in Soils PDF Author: H. Magdi Selim
Publisher: CRC Press
ISBN: 148223680X
Category : Nature
Languages : en
Pages : 381

Book Description
Edited by One of the Best Specialists in Soil Science Recent studies reveal that Phosphorus (P) in the form of phosphate, a macronutrient essential for plant growth, and crop yields can influence the bioavailability, retention, and mobility of trace elements, metal(loid)s, and radio nuclides in soils. When this occurs, phosphates can affect the dynamics of heavy metals and influence soil characteristics, impacting soil mobility and toxicity. Phosphate in Soils: Interaction with Micronutrients, Radionuclides and Heavy Metals utilizes the latest research to emphasize the role that phosphate plays in enhancing or reducing the mobility of heavy metals in soil, and the soil-water-plant environment. It provides an in-depth understanding of each heavy metal species, and expands on phosphate interactions in geological material. Composed of 12 chapters, this text: Provides an overview of the reactions of metal(loid)s and common P compounds that are used as fertilizer in soils Emphasizes the effect of phosphorus on copper and zinc adsorption in acid soils Discusses findings on the influence of phosphate compounds on speciation, mobility, and bioavailability of heavy metals in soils as well as the role of phosphates on in situ and phytoremediation of heavy metals for contaminated soils Places emphasis on the influence of phosphate on various heavy metals species in soils, and their solubility/mobility and availability Provides extensive information on testing various high phosphate materials for remediation of heavy metal, micronutrients, and radionuclides contaminated sites Explores the reactivity of heavy metals, micronutrients and radionuclides elements in several soils Presents a case study illustrating various remediation efforts of acidic soils and remediation of Cu, Zn, and lead (Pb) contaminated soils around nonferrous industrial plants Emphasizes the significance of common ions (cations and anions) on phosphate mobility and sorption in soils, and more The author includes analytical and numerical solutions along with hands-on applications, and addresses other topics that include the transport and sorption modeling of heavy metals in the presence of phosphate at different scales in the vadose zone.

Behavior of Metals in Soils

Behavior of Metals in Soils PDF Author: Joan E. McLean
Publisher:
ISBN:
Category : Hazardous waste sites
Languages : en
Pages : 28

Book Description


Die Eamburger Sterrwarte in Bergedorf, erbaut 1906-1912

Die Eamburger Sterrwarte in Bergedorf, erbaut 1906-1912 PDF Author:
Publisher:
ISBN:
Category :
Languages : en
Pages :

Book Description


Laboratory- to Field-scale Investigations to Evaluate Phosphate Amendments and Miscanthus for Phytostabilization of Lead-contaminated Military Sites

Laboratory- to Field-scale Investigations to Evaluate Phosphate Amendments and Miscanthus for Phytostabilization of Lead-contaminated Military Sites PDF Author: Zafer Saad Alasmary
Publisher:
ISBN:
Category :
Languages : en
Pages :

Book Description
Potentially toxic substances can contaminate extensive areas of productive land due to military activities. The most common and widespread metal contaminant in military lands is lead (Pb). The main objectives of this study were to evaluate the feasibility of using Miscanthus, a second-generation biofuel crop, for photostabilization of Pb in contaminated military site soils; the effect of soil amendments on Miscanthus growth; and the effects of continual plant growth, nutrient removal and the soil chemical changes induced by Miscanthus growth on soil Pb bioaccessibility. In 2016, we established a field site on a US Army reservation in Fort Riley, KS. Miscanthus was planted in an area with soil total Pb concentration ranging from 900 - 1,500 mg kg−1 and near-neutral soil pH. Five treatments were evaluated: (i) control plots without tillage with existing vegetation, (ii) no-tillage, no additional amendments planted with Miscanthus, (iii) tilled soil, no additional amendments planted with Miscanthus, (iv) tilled soil amended with triple superphosphate (at 5:3 Pb:P molar ratio) planted with Miscanthus, and (v) tilled soil amended with organic P source (class B biosolids applied at 45 Mg/ha ) planted with Miscanthus. Results from three years show that one-time addition of soil amendments to Pb-contaminated soil supports establishing and stabilizing Miscanthus, increasing biomass yield as well as reducing phytoavailability and bioaccessibility of Pb. Plots amended with biosolids had significantly less total Pb uptake, plant tissue Pb concentration, and Pb bioaccessibility, and more soil enzyme activities, organic carbon, and microbial biomass. Controlled-environment greenhouse and laboratory incubation studies were conducted to test selected additional P sources. Additional sources included non-traditional, less soluble types such as struvite and apatite. The greenhouse study aimed to evaluate the effect of Miscanthus growth on bioaccessibility of amended and non-amended soils and the effect of soil amendments on soil-plant transfer of soil Pb over three Miscanthus cuttings. Soil amendments increased dry matter yield in the first cutting. Soils in Miscanthus pots that were amended with biosolids, had significantly lower total Pb uptake, Pb concentration in plant tissues, and Pb bioaccessibility when compared to the control across all cuttings. Overall, the results suggested that Miscanthus can be effectively and safely grown on Pb-contaminated soils amended with biosolids. The incubation study evaluated the effectiveness of various in situ P treatments on reducing Pb bioaccessibility and the effects of different P sources on the speciation of soil Pb over time. X-ray absorption spectroscopy was used to understand treatment-induced changes to soil Pb speciation. Results showed that soil pH decreased slightly for all treatments. Percent of bioaccessible Pb in soils amended with biosolid were significantly ([alpha]=0.05) less than the other amendments. The high rate of biosolids (225 Mg ha−1) was the most effective in controlling the bioaccessibility of soil Pb, and the reductions in bioaccessibility ranged from 63 to 76% compared to the control. X-ray absorption spectroscopy results indicated pyromorphite (stable Pb phosphates) phases were the most dominant Pb species in both amended and non-amended soils. The results of these studies suggest that Miscanthus can be grown successfully in Pb-contaminated shooting range soils in combination with organic or inorganic phosphate amendments, while minimizing the associated environmental risks.

The Impact of Inorganic Phosphates in the Environment

The Impact of Inorganic Phosphates in the Environment PDF Author: Justine Welch
Publisher:
ISBN:
Category : Eutrophication
Languages : en
Pages : 104

Book Description


Heavy Metals in Soils

Heavy Metals in Soils PDF Author: B. J. Alloway
Publisher: Springer Science & Business Media
ISBN: 9780751401981
Category : Nature
Languages : en
Pages : 392

Book Description
Heavy metals in soils continue to receive increasing attention due to the growing scientific and public awareness of environmental issues and the development of analytical techniques to measure their concentrations accurately. Building on the success and acclaim of the first edition, this book continues to provide an up-to-date, balanced and comprehensive review of the subject in two sections: the first providing an introduction to the metals chemistry, sources and methods used for their analysis; and the second containing chapters dealing with individual elements in detail.

Reviews of Environmental Contamination and Toxicology

Reviews of Environmental Contamination and Toxicology PDF Author: George Ware
Publisher: Springer Science & Business Media
ISBN: 0387217258
Category : Science
Languages : en
Pages : 222

Book Description
Reviews of Environmental Contamination and Toxicology attempts to provide concise, critical reviews of timely advances, philosophy, and significant areas of accomplished or needed endeavor in the total field of xenobiotics in any segment of the environment, as well as toxicological implications.

Soil pollution: a hidden reality

Soil pollution: a hidden reality PDF Author: Food and Agriculture Organization of the United Nations
Publisher: Food & Agriculture Org.
ISBN: 9251305056
Category : Technology & Engineering
Languages : en
Pages : 156

Book Description
This document presents key messages and the state-of-the-art of soil pollution, its implications on food safety and human health. It aims to set the basis for further discussion during the forthcoming Global Symposium on Soil Pollution (GSOP18), to be held at FAO HQ from May 2nd to 4th 2018. The publication has been reviewed by the Intergovernmental Technical Panel on Soil (ITPS) and contributing authors. It addresses scientific evidences on soil pollution and highlights the need to assess the extent of soil pollution globally in order to achieve food safety and sustainable development. This is linked to FAO’s strategic objectives, especially SO1, SO2, SO4 and SO5 because of the crucial role of soils to ensure effective nutrient cycling to produce nutritious and safe food, reduce atmospheric CO2 and N2O concentrations and thus mitigate climate change, develop sustainable soil management practices that enhance agricultural resilience to extreme climate events by reducing soil degradation processes. This document will be a reference material for those interested in learning more about sources and effects of soil pollution.

Biochar Application

Biochar Application PDF Author: T. Komang Ralebitso-Senior
Publisher: Elsevier
ISBN: 012803436X
Category : Technology & Engineering
Languages : en
Pages : 342

Book Description
Biochar Application: Essential Soil Microbial Ecology outlines the cutting-edge research on the interactions of complex microbial populations and their functional, structural, and compositional dynamics, as well as the microbial ecology of biochar application to soil, the use of different phyto-chemical analyses, possibilities for future research, and recommendations for climate change policy. Biochar, or charcoal produced from plant matter and applied to soil, has become increasingly recognized as having the potential to address multiple contemporary concerns, such as agricultural productivity and contaminated ecosystem amelioration, primarily by removing carbon dioxide from the atmosphere and improving soil functions. Biochar Application is the first reference to offer a complete assessment of the various impacts of biochar on soil and ecosystems, and includes chapters analyzing all aspects of biochar technology and application to soil, from ecogenomic analyses and application ratios to nutrient cycling and next generation sequencing. Written by a team of international authors with interdisciplinary knowledge of biochar, this reference will provide a platform where collaborating teams can find a common resource to establish outcomes and identify future research needs throughout the world. - Includes multiple tables and figures per chapter to aid in analysis and understanding - Includes a comprehensive table of the methods used within the contents, ecosystems, contaminants, future research, and application opportunities explored in the book - Includes knowledge gaps and directions of future research to stimulate further discussion in the field and in climate change policy - Outlines the latest research on the interactions of complex microbial populations and their functional, structural, and compositional dynamics - Offers an assessment of the impacts of biochar on soil and ecosystems