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Entropy and the Time Evolution of Macroscopic Systems

Entropy and the Time Evolution of Macroscopic Systems PDF Author: Walter T. Grandy Jr.
Publisher: OUP Oxford
ISBN: 0191562955
Category : Science
Languages : en
Pages : 225

Book Description
This book is based on the premise that the entropy concept, a fundamental element of probability theory as logic, governs all of thermal physics, both equilibrium and nonequilibrium. The variational algorithm of J. Willard Gibbs, dating from the 19th Century and extended considerably over the following 100 years, is shown to be the governing feature over the entire range of thermal phenomena, such that only the nature of the macroscopic constraints changes. Beginning with a short history of the development of the entropy concept by Rudolph Clausius and his predecessors, along with the formalization of classical thermodynamics by Gibbs, the first part of the book describes the quest to uncover the meaning of thermodynamic entropy, which leads to its relationship with probability and information as first envisioned by Ludwig Boltzmann. Recognition of entropy first of all as a fundamental element of probability theory in mid-twentieth Century led to deep insights into both statistical mechanics and thermodynamics, the details of which are presented here in several chapters. The later chapters extend these ideas to nonequilibrium statistical mechanics in an unambiguous manner, thereby exhibiting the overall unifying role of the entropy.

Entropy and the Time Evolution of Macroscopic Systems

Entropy and the Time Evolution of Macroscopic Systems PDF Author: Walter T. Grandy Jr.
Publisher: OUP Oxford
ISBN: 0191562955
Category : Science
Languages : en
Pages : 225

Book Description
This book is based on the premise that the entropy concept, a fundamental element of probability theory as logic, governs all of thermal physics, both equilibrium and nonequilibrium. The variational algorithm of J. Willard Gibbs, dating from the 19th Century and extended considerably over the following 100 years, is shown to be the governing feature over the entire range of thermal phenomena, such that only the nature of the macroscopic constraints changes. Beginning with a short history of the development of the entropy concept by Rudolph Clausius and his predecessors, along with the formalization of classical thermodynamics by Gibbs, the first part of the book describes the quest to uncover the meaning of thermodynamic entropy, which leads to its relationship with probability and information as first envisioned by Ludwig Boltzmann. Recognition of entropy first of all as a fundamental element of probability theory in mid-twentieth Century led to deep insights into both statistical mechanics and thermodynamics, the details of which are presented here in several chapters. The later chapters extend these ideas to nonequilibrium statistical mechanics in an unambiguous manner, thereby exhibiting the overall unifying role of the entropy.

Entropy

Entropy PDF Author: Andreas Greven
Publisher: Princeton University Press
ISBN: 1400865220
Category : Mathematics
Languages : en
Pages : 376

Book Description
The concept of entropy arose in the physical sciences during the nineteenth century, particularly in thermodynamics and statistical physics, as a measure of the equilibria and evolution of thermodynamic systems. Two main views developed: the macroscopic view formulated originally by Carnot, Clausius, Gibbs, Planck, and Caratheodory and the microscopic approach associated with Boltzmann and Maxwell. Since then both approaches have made possible deep insights into the nature and behavior of thermodynamic and other microscopically unpredictable processes. However, the mathematical tools used have later developed independently of their original physical background and have led to a plethora of methods and differing conventions. The aim of this book is to identify the unifying threads by providing surveys of the uses and concepts of entropy in diverse areas of mathematics and the physical sciences. Two major threads, emphasized throughout the book, are variational principles and Ljapunov functionals. The book starts by providing basic concepts and terminology, illustrated by examples from both the macroscopic and microscopic lines of thought. In-depth surveys covering the macroscopic, microscopic and probabilistic approaches follow. Part I gives a basic introduction from the views of thermodynamics and probability theory. Part II collects surveys that look at the macroscopic approach of continuum mechanics and physics. Part III deals with the microscopic approach exposing the role of entropy as a concept in probability theory, namely in the analysis of the large time behavior of stochastic processes and in the study of qualitative properties of models in statistical physics. Finally in Part IV applications in dynamical systems, ergodic and information theory are presented. The chapters were written to provide as cohesive an account as possible, making the book accessible to a wide range of graduate students and researchers. Any scientist dealing with systems that exhibit entropy will find the book an invaluable aid to their understanding.

Time, Chance, and Reduction

Time, Chance, and Reduction PDF Author: Gerhard Ernst
Publisher: Cambridge University Press
ISBN: 1139485431
Category : Science
Languages : en
Pages : 219

Book Description
Statistical mechanics attempts to explain the behaviour of macroscopic physical systems in terms of the mechanical properties of their constituents. Although it is one of the fundamental theories of physics, it has received little attention from philosophers of science. Nevertheless, it raises philosophical questions of fundamental importance on the nature of time, chance and reduction. Most philosophical issues in this domain relate to the question of the reduction of thermodynamics to statistical mechanics. This book addresses issues inherent in this reduction: the time-asymmetry of thermodynamics and its absence in statistical mechanics; the role and essential nature of chance and probability in this reduction when thermodynamics is non-probabilistic; and how, if at all, the reduction is possible. Compiling contributions on current research by experts in the field, this is an invaluable survey of the philosophy of statistical mechanics for academic researchers and graduate students interested in the foundations of physics.

Statistical Mechanics And Scientific Explanation: Determinism, Indeterminism And Laws Of Nature

Statistical Mechanics And Scientific Explanation: Determinism, Indeterminism And Laws Of Nature PDF Author: Valia Allori
Publisher: World Scientific
ISBN: 9811211736
Category : Science
Languages : en
Pages : 698

Book Description
The book explores several open questions in the philosophy and the foundations of statistical mechanics. Each chapter is written by a leading expert in philosophy of physics and/or mathematical physics. Here is a list of questions that are addressed in the book:

Multiscale Thermo-Dynamics

Multiscale Thermo-Dynamics PDF Author: Michal Pavelka
Publisher: Walter de Gruyter GmbH & Co KG
ISBN: 3110350955
Category : Science
Languages : en
Pages : 292

Book Description
One common feature of new emerging technologies is the fusion of the very small (nano) scale and the large scale engineering. The classical environment provided by single scale theories, as for instance by the classical hydrodynamics, is not anymore satisfactory. The main challenge is to keep the important details while still be able to keep the overall picture and simplicity. It is the thermodynamics that addresses this challenge. Our main reason for writing this book is to explain such general viewpoint of thermodynamics and to illustrate it on a very wide range of examples. Contents Levels of description Hamiltonian mechanics Irreversible evolution Reversible and irreversible evolution Multicomponent systems Contact geometry Appendix: Mathematical aspects

Mystery Of Time, The: Asymmetry Of Time And Irreversibility In The Natural Processes

Mystery Of Time, The: Asymmetry Of Time And Irreversibility In The Natural Processes PDF Author: Alexander Leonidovich Kuzemsky
Publisher: World Scientific
ISBN: 9811267022
Category : Science
Languages : en
Pages : 484

Book Description
The book focuses on the study of the temporal behavior of complex many-particle systems. The phenomenon of time and its role in the temporal evolution of complex systems is a remaining mystery. The book presents the necessity of the interdisciplinary point of view regarding on the phenomenon of time.The aim of the present study is to summarize and formulate in a concise but clear form the trends and approaches to the concept of time from a broad interdisciplinary perspective exposing tersely the complementary approaches and theories of time in the context of thermodynamics, statistical physics, cosmology, theory of information, biology and biophysics, including the problem of time and aging. Various approaches to the problem show that time is an extraordinarily interdisciplinary and multifaceted underlying notion which plays an extremely important role in various natural complex processes.

Foundations of Statistical Mechanics

Foundations of Statistical Mechanics PDF Author: O. Penrose
Publisher: Elsevier
ISBN: 1483156486
Category : Science
Languages : en
Pages : 272

Book Description
International Series of Monographs in Natural Philosophy, Volume 22: Foundations of Statistical Mechanics: A Deductive Treatment presents the main approaches to the basic problems of statistical mechanics. This book examines the theory that provides explicit recognition to the limitations on one's powers of observation. Organized into six chapters, this volume begins with an overview of the main physical assumptions and their idealization in the form of postulates. This text then examines the consequences of these postulates that culminate in a derivation of the fundamental formula for calculating probabilities in terms of dynamic quantities. Other chapters provide a careful analysis of the significant notion of entropy, which shows the links between thermodynamics and statistical mechanics and also between communication theory and statistical mechanics. The final chapter deals with the thermodynamic concept of entropy. This book is intended to be suitable for students of theoretical physics. Probability theorists, statisticians, and philosophers will also find this book useful.

Entropy

Entropy PDF Author: Andreas Greven
Publisher:
ISBN: 9781322063225
Category : Electronic books
Languages : en
Pages :

Book Description
The concept of entropy arose in the physical sciences during the nineteenth century, particularly in thermodynamics and statistical physics, as a measure of the equilibria and evolution of thermodynamic systems. Two main views developed: the macroscopic view formulated originally by Carnot, Clausius, Gibbs, Planck, and Caratheodory and the microscopic approach associated with Boltzmann and Maxwell. Since then both approaches have made possible deep insights into the nature and behavior of thermodynamic and other microscopically unpredictable processes. However, the mathematical tools used have later developed independently of their original physical background and have led to a plethora of methods and differing conventions. The aim of this book is to identify the unifying threads by providing surveys of the uses and concepts of entropy in diverse areas of mathematics and the physical sciences. Two major threads, emphasized throughout the book, are variational principles and Ljapunov functionals. The book starts by providing basic concepts and terminology, illustrated by examples from both the macroscopic and microscopic lines of thought. In-depth surveys covering the macroscopic, microscopic and probabilistic approaches follow. Part I gives a basic introduction from the views of thermodynamics and probability theory. Part II collects surveys that look at the macroscopic approach of continuum mechanics and physics. Part III deals with the microscopic approach exposing the role of entropy as a concept in probability theory, namely in the analysis of the large time behavior of stochastic processes and in the study of qualitative properties of models in statistical physics. Finally in Part IV applications in dynamical systems, ergodic and information theory are presented. The chapters were written to provide as cohesive an account as possible, making the book accessible to a wide range of graduate students and researchers. Any scientist dealing with systems that exhibit entropy will find the book an invaluable aid to their understanding.

Time's Arrow

Time's Arrow PDF Author: Michael C. Mackey
Publisher: New York : Springer-Verlag
ISBN:
Category : Science
Languages : en
Pages : 200

Book Description


The Statistical Foundations Of Entropy

The Statistical Foundations Of Entropy PDF Author: John D Ramshaw
Publisher: World Scientific
ISBN: 9813234148
Category : Science
Languages : en
Pages : 217

Book Description
This book presents an innovative unified approach to the statistical foundations of entropy and the fundamentals of equilibrium statistical mechanics. These intimately related subjects are often developed in a fragmented historical manner which obscures the essential simplicity of their logical structure. In contrast, this book critically reassesses and systematically reorganizes the basic concepts into a simpler sequential framework which reveals more clearly their logical relationships. The inherent indistinguishability of identical particles is emphasized, and the resulting unification of classical and quantum statistics is discussed in detail.The discussion is focused entirely on fundamental concepts, so applications are omitted. The book is written at the advanced undergraduate or beginning graduate level, and will be useful as a concise supplement to conventional books and courses in statistical mechanics, thermal physics, and thermodynamics. It is also suitable for self-study by those seeking a deeper and more detailed analysis of the fundamentals.