Electrodeposition of Plutonium from Molten Salt Solutions of Cs$sub 2$PuCl$sub 6$ PDF Download
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Author: Publisher: ISBN: Category : Languages : en Pages :
Book Description
The usefulness of molten salt solutions of Cs/sub 2/PuCl/sub 6/ for plutonium electrolyses has been investigated. Plutonium metal has been recovered from solutions without the use of Pu anodes. Up to 88% of the Pu dissolved in salt solutions has been recovered with Ta cathodes. No net Pu was recovered from solution when Pu cathodes were used because of the reoxidation of the deposit by dissolved chlorine. The potential of the Pu(IV)-Pu(III) couple was measured and found to be -0.28 volts. (auth).
Author: Publisher: ISBN: Category : Languages : en Pages :
Book Description
The usefulness of molten salt solutions of Cs/sub 2/PuCl/sub 6/ for plutonium electrolyses has been investigated. Plutonium metal has been recovered from solutions without the use of Pu anodes. Up to 88% of the Pu dissolved in salt solutions has been recovered with Ta cathodes. No net Pu was recovered from solution when Pu cathodes were used because of the reoxidation of the deposit by dissolved chlorine. The potential of the Pu(IV)-Pu(III) couple was measured and found to be -0.28 volts. (auth).
Author: Publisher: ISBN: Category : Languages : en Pages : 5
Book Description
Equipment for electrolytic deposition of plutonium from molten salt solutions was designed and built and was tested with cerium as a stand-in for plutonium. The electrolysis cell is a graphite crucible that serves as the anode; the cathode is a molybdenum rod. This paper discusses results of that test.
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