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Author: Maciej Chotkowski Publisher: Springer Nature ISBN: 3030628639 Category : Science Languages : en Pages : 162
Book Description
This book provides detailed information on the electrochemistry of technetium compounds. After a brief physico-chemical characterization of this element, it presents the comparative chemistry of technetium, manganese and rhenium. Particular attention is paid to the stability, disproportionation, comproportionation, hydrolysis and polymerization reactions of technetium ions and their influence on the observed redox systems. The electrochemical properties of both inorganic as well as organic technetium species in aqueous and non-aqueous solutions are also discussed. The respective chapters cover the whole spectrum of topics related to the application of technetium in nuclear medicine, electrochemistry of technetium in spent nuclear fuel (including corrosion properties of technetium alloys), and detecting trace amounts of technetium with the aid of electrochemical methods. Providing readers with information not easily obtained in any other single source, the book will appeal to researchers working in nuclear chemistry, nuclear medicine or the nuclear industry.
Author: Maciej Chotkowski Publisher: Springer Nature ISBN: 3030628639 Category : Science Languages : en Pages : 162
Book Description
This book provides detailed information on the electrochemistry of technetium compounds. After a brief physico-chemical characterization of this element, it presents the comparative chemistry of technetium, manganese and rhenium. Particular attention is paid to the stability, disproportionation, comproportionation, hydrolysis and polymerization reactions of technetium ions and their influence on the observed redox systems. The electrochemical properties of both inorganic as well as organic technetium species in aqueous and non-aqueous solutions are also discussed. The respective chapters cover the whole spectrum of topics related to the application of technetium in nuclear medicine, electrochemistry of technetium in spent nuclear fuel (including corrosion properties of technetium alloys), and detecting trace amounts of technetium with the aid of electrochemical methods. Providing readers with information not easily obtained in any other single source, the book will appeal to researchers working in nuclear chemistry, nuclear medicine or the nuclear industry.
Author: Klaus Schwochau Publisher: John Wiley & Sons ISBN: 3527613374 Category : Science Languages : en Pages : 458
Book Description
This unique handbook provides a comprehensive survey of the present status of Technetium chemistry and its radiopharmaceutical applications. All Technetium aspects such as · natural and artificial occurence in the environment, · isotopes and isomers, · analytical chemistry and electrochemistry, · thermodynamic data, stability and reactivity, · intermetallic and binary compounds, and predominantly · complex chemistry, and · radiopharmacy are presented in an clear and precise manner. This outstanding presentation allows both experts and non-experts a quick access to the subject. Therefore this handbook is an indispensable reference for researchers at universities and research centers, in the nuclear medicine and radiopharmaceutical industries as well as consultants in government and environmental agencies.
Author: Derek Pletcher Publisher: Royal Society of Chemistry ISBN: 0851860672 Category : Reference Languages : en Pages : 86
Book Description
Specialist Periodical Reports provide systematic and detailed review coverage of progress in the major areas of chemical research. Written by experts in their specialist fields the series creates a unique service for the active research chemist, supplying regular critical in-depth accounts of progress in particular areas of chemistry. For over 80 years the Royal Society of Chemistry and its predecessor, the Chemical Society, have been publishing reports charting developments in chemistry, which originally took the form of Annual Reports. However, by 1967 the whole spectrum of chemistry could no longer be contained within one volume and the series Specialist Periodical Reports was born. The Annual Reports themselves still existed but were divided into two, and subsequently three, volumes covering Inorganic, Organic and Physical Chemistry. For more general coverage of the highlights in chemistry they remain a 'must'. Since that time the SPR series has altered according to the fluctuating degree of activity in various fields of chemistry. Some titles have remained unchanged, while others have altered their emphasis along with their titles; some have been combined under a new name whereas others have had to be discontinued.
Author: A.J.L. Pombeiro Publisher: Springer Science & Business Media ISBN: 9401116288 Category : Science Languages : en Pages : 652
Book Description
The use of electrochemical techniques by chemists, particularly those who regard themselves as "inorganic" coordination chemists, has undergone a very rapid growth in the last 15-20 years. The techniques, as dassically applied to inorganic species, had their origins in analytical chemistry, and the methodology had assumed, until the mid 60s, more importance than the chemiStry. However, the growth of interest in coordination compounds (including organometallic complexes) having unusually rich of electron-transfer in bio-inorganic redox properties, and in the understanding species, has propelfed electro-chemistry into the foreground of potentially readily available techniques for application to a very wide range of problems of interest to those chemists. This growth has been fuelled additionally by the availability of relatively cheap equipment of growing sophistication and by an increase in the "inorganic" chemists' general knowledge of physical electrochemistry. In particular, with increasing availability and sophistication of eqUipment, kinetic problems are now being addressed, and the range of electrode types and configuration and solvents has been greatly expanded. Furthermore, the rapid expansion of interest in biological problems has opened new avenues in functionalisation of electrodes, in the development of sensory devices and, in a sense, a return to the analytical base of the science, using novel and multi-disciplinary techniques drawing on synthesis chemistry of and electronic micro-engeneering. The drive towards increasing use microcomputer-controlled data analysis and the development of microeledrodes has opened exciting new avenues for the exploration of chemical reactions involving electron-transfer processes.
Author: J.A. Rard Publisher: North Holland ISBN: Category : Science Languages : en Pages : 578
Book Description
This volume in the series Chemical Thermodynamics provides a comprehensive review and critical evaluation of experimental data available for the chemical thermodynamics of inorganic compounds and aqueous species and complexes of technetium. The objective of the reviews in the series Chemical Thermodynamics is to provide a set of reliable thermodynamic data that can be used to describe the behaviour of the elements reviewed under conditions relevant for radioactive waste disposal systems and various geochemical environments. Data and their uncertainty limits are recommended for the formation energies, enthalpies and entropies of selected aqueous complexes, solids and gaseous compounds containing technetium. The data are internally consistent and compatible with the CODATA Key Values, as well as with the data in the earlier volumes in the series Chemical Thermodynamics. The book contains a detailed discussion of the selection procedures used
Author: Karl M Kadish Publisher: World Scientific ISBN: 9811267634 Category : Science Languages : en Pages : 645
Book Description
This book is part of a series of ongoing volumes in the Series on Chemistry, Energy and the Environment, edited by Karl Kadish and Roger Guilard. The current volume on Electrochemistry of Metalloporphyrins covers all aspects of porphyrin electrochemistry in nonaqueous media and should be of benefit and interest to beginning graduate students as well as experienced researchers in many fields of porphyrin chemistry where electrochemistry is known to play a key role in influencing properties of the compounds as well as mechanisms and biological functions. The first half of the book is aimed at non-experts in the field of electrochemistry who would like to begin studies on porphyrin electrochemistry or understand the literature on porphyrin electrochemistry and this is then followed by detailed examples of how changes in the central metal ion of a given metalloporphyrin will affect its redox properties. The scope of the work covers the period in the literature between the mid-1960s and mid-2022 and expands greatly upon several earlier reviews by the senior author which are no longer in print and were never accessible in electronic form. This is the only book of its kind in the field which covers the basic electrochemistry of metalloporphyrins as well as describes the published data as a function of the central metal ion, considering all elements in the periodic table.
Author: Maciej Chotkowski
Author: Maciej Chotkowski
Author: Klaus Schwochau
Author: 
Author: Derek Pletcher
Author: A.J.L. Pombeiro
Author: J.A. Rard
Author: Jane Y. Lewis
Author: William E. Bleidner
Author: Karl M Kadish
Author: