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Electrochemistry of Metalloporphyrins and Their Catalytic Reduction of Oxygen at Carbon Electrodes

Electrochemistry of Metalloporphyrins and Their Catalytic Reduction of Oxygen at Carbon Electrodes PDF Author: Yuhlong Oliver Su
Publisher:
ISBN:
Category : Catalysis
Languages : en
Pages : 314

Book Description


Electrochemistry of Metalloporphyrins and Their Catalytic Reduction of Oxygen at Carbon Electrodes

Electrochemistry of Metalloporphyrins and Their Catalytic Reduction of Oxygen at Carbon Electrodes PDF Author: Yuhlong Oliver Su
Publisher:
ISBN:
Category : Catalysis
Languages : en
Pages : 314

Book Description


Electrochemistry of N4 Macrocyclic Metal Complexes

Electrochemistry of N4 Macrocyclic Metal Complexes PDF Author: Jose H. Zagal
Publisher: Springer
ISBN: 3319311727
Category : Science
Languages : en
Pages : 325

Book Description
This new edition describes the state of the art regarding molecular catalysts such as MN4 metal complexes, like porphyrins and phthalocyanines. This volume focuses on the particular case of the electrocatalysis of the reduction of O2 for practical applications in fuel cells and air batteries. Indeed, active and stable materials have been developed in the last 5 years where MN4 catalytic systems can be obtained by the pyrolysis of starting materials that do not necessarily involve MN4 complexes. These latter systems constitute a new class of stable and highly active non-precious metal catalysts for ORR that can replace expensive Platinum containing electrodes. The book also offers future projections and points out new fields of research and development of these non-precious metal catalysts.

Electrochemical Reduction of Oxygen on Quinone-modified Carbon Electrodes and on Thin Films of Platinum and Gold

Electrochemical Reduction of Oxygen on Quinone-modified Carbon Electrodes and on Thin Films of Platinum and Gold PDF Author: Ave Sarapuu
Publisher:
ISBN:
Category : Electrodes, Carbon
Languages : en
Pages : 146

Book Description


Electrochemistry of N4 Macrocyclic Metal Complexes

Electrochemistry of N4 Macrocyclic Metal Complexes PDF Author: Jose H. Zagal
Publisher: Springer
ISBN: 3319313320
Category : Science
Languages : en
Pages : 442

Book Description
This new edition describes the state of the art regarding metal complexes of N4-ligands, such as porphyrins and phthalocyanines. Volume 2 focuses on the electro assisted use of N4 complexes as biomimetic models for studying several biological redox processes. It focuses on molecular oxygen transport and catalytic activation to mimic monooxygenase enzymes of the cytochrome P450 in particular. It also examines N4 complexes’ use as catalysts for the oxidative degradation of various types of pollutants (organo-halides, for example) and residual wastes. The remarkable activity of these complexes towards a large number of significantly relevant biological compounds makes them excellent candidates as electrode modifiers for electrochemical sensing. This volume also discusses applications of N4 Macrocyclic Metal Complexes to photoelectrochemistry and photocatalysis, and concludes with an exciting section on Electrosynthesis of N4.

Iron Porphyrins

Iron Porphyrins PDF Author: A. B. P. Lever
Publisher: Wiley-VCH
ISBN: 9780471187158
Category : Science
Languages : en
Pages : 322

Book Description
Porphyrins play a vital role in many biological functions including oxygen transport, electron transfer and catalyzing the incorporation of oxygen into other molecules. This current survey discusses the use of modern physical techniques to probe porphyrin structure and function. The authors review the data available through a particular technique and show what can be learned therefrom about the (electronic) structure and function of biologically important porphyrins. The techniques include magnetic circular dichroism, X-ray absorption fine structure (EXAFS) and Mössbauer spectroscopies. All contributors are well known in their respective fields, enjoying world-wide reputation.

Electrochemistry Of Metalloporphyrins

Electrochemistry Of Metalloporphyrins PDF Author: Karl M Kadish
Publisher: World Scientific
ISBN: 9811267634
Category : Science
Languages : en
Pages : 645

Book Description
This book is part of a series of ongoing volumes in the Series on Chemistry, Energy and the Environment, edited by Karl Kadish and Roger Guilard. The current volume on Electrochemistry of Metalloporphyrins covers all aspects of porphyrin electrochemistry in nonaqueous media and should be of benefit and interest to beginning graduate students as well as experienced researchers in many fields of porphyrin chemistry where electrochemistry is known to play a key role in influencing properties of the compounds as well as mechanisms and biological functions. The first half of the book is aimed at non-experts in the field of electrochemistry who would like to begin studies on porphyrin electrochemistry or understand the literature on porphyrin electrochemistry and this is then followed by detailed examples of how changes in the central metal ion of a given metalloporphyrin will affect its redox properties. The scope of the work covers the period in the literature between the mid-1960s and mid-2022 and expands greatly upon several earlier reviews by the senior author which are no longer in print and were never accessible in electronic form. This is the only book of its kind in the field which covers the basic electrochemistry of metalloporphyrins as well as describes the published data as a function of the central metal ion, considering all elements in the periodic table.

Electrochemical and Photoelectrochemical Studies of Oxygen Reduction on Metal Phthalocyanines and Porphyrins

Electrochemical and Photoelectrochemical Studies of Oxygen Reduction on Metal Phthalocyanines and Porphyrins PDF Author: Gary Alan Deborski
Publisher:
ISBN:
Category : Electrochemistry
Languages : en
Pages : 168

Book Description


Metalloporphyrins in Catalytic Oxidations

Metalloporphyrins in Catalytic Oxidations PDF Author: Roger A. Sheldon
Publisher: CRC Press
ISBN: 9780824792282
Category : Science
Languages : en
Pages : 412

Book Description
This volume provides an in-depth overview of the chemistry of metalloporphyrins as oxidation catalysts in chemical and biological systems. It discusses practical techniques for the synthesis of metalloporphyrins and introduces useful methods of immobilization to improve their synthetic utility. Detailed discussions of underlying mechanistic features are provided.

Environmental Analysis by Electrochemical Sensors and Biosensors

Environmental Analysis by Electrochemical Sensors and Biosensors PDF Author: Ligia Maria Moretto
Publisher: Springer
ISBN: 1493913018
Category : Science
Languages : en
Pages : 455

Book Description
This book discusses in detail the analysis and monitoring of the most important analytes in the environmental field. It also reviews the implementation, realization and application of sensor designs mentioned in the first volume of this set, dividing the coverage into global parameters, sensors of organics and sensors of inorganics.

Part I: Electrocatalytic Four-electron Reduction of Dioxygen by Metalloporphyrin Adsorbed on Graphite ; Part II: Synthesis, Characterization and Electrochemistry of Diruthenium Cofacial Porphyrin Dimers

Part I: Electrocatalytic Four-electron Reduction of Dioxygen by Metalloporphyrin Adsorbed on Graphite ; Part II: Synthesis, Characterization and Electrochemistry of Diruthenium Cofacial Porphyrin Dimers PDF Author: Kimoon Kim
Publisher:
ISBN:
Category :
Languages : en
Pages : 406

Book Description