Electrochemical Studies of the Adsorption of Metal Complexes on Mercury Electrodes and Chronopotentiometric Studies of Spherical, Shielding, and Streaming Effects at the Hanging Mercury Drop Electrode PDF Download

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Electrochemical Studies of the Adsorption of Metal Complexes on Mercury Electrodes and Chronopotentiometric Studies of Spherical, Shielding, and Streaming Effects at the Hanging Mercury Drop Electrode

Electrochemical Studies of the Adsorption of Metal Complexes on Mercury Electrodes and Chronopotentiometric Studies of Spherical, Shielding, and Streaming Effects at the Hanging Mercury Drop Electrode PDF Author: Donald James Gross
Publisher:
ISBN:
Category : Adsorption
Languages : en
Pages : 630

Book Description

Electrochemical Studies of the Adsorption of Metal Complexes on Mercury Electrodes and Chronopotentiometric Studies of Spherical, Shielding, and Streaming Effects at the Hanging Mercury Drop Electrode

Electrochemical Studies of the Adsorption of Metal Complexes on Mercury Electrodes and Chronopotentiometric Studies of Spherical, Shielding, and Streaming Effects at the Hanging Mercury Drop Electrode PDF Author: Donald James Gross
Publisher:
ISBN:
Category : Adsorption
Languages : en
Pages : 630

Book Description

Dissertation Abstracts

Dissertation Abstracts PDF Author:
Publisher:
ISBN:
Category : Dissertations, Academic
Languages : en
Pages : 1018

Book Description

Dissertation Abstracts International

Dissertation Abstracts International PDF Author:
Publisher:
ISBN:
Category : Dissertations, Academic
Languages : en
Pages : 1396

Book Description

American Doctoral Dissertations

American Doctoral Dissertations PDF Author:
Publisher:
ISBN:
Category : Dissertation abstracts
Languages : en
Pages : 298

Book Description

Comprehensive Dissertation Index, 1861-1972: Chemistry

Comprehensive Dissertation Index, 1861-1972: Chemistry PDF Author: Xerox University Microfilms
Publisher:
ISBN:
Category : Dissertations, Academic
Languages : en
Pages : 968

Book Description

Research: a Record of Scholarship and Publication

Research: a Record of Scholarship and Publication PDF Author: University of North Carolina at Chapel Hill. Graduate School
Publisher:
ISBN:
Category : Research
Languages : en
Pages : 860

Book Description

Comprehensive Dissertation Index

Comprehensive Dissertation Index PDF Author:
Publisher:
ISBN:
Category : Dissertations, Academic
Languages : en
Pages : 978

Book Description

Adsorption of Organic Compounds on Electrodes

Adsorption of Organic Compounds on Electrodes PDF Author: Boris Damaskin
Publisher: Springer
ISBN: 9781461581925
Category : Science
Languages : en
Pages : 0

Book Description
The systematic study of the adsorption of organic compounds on electrodes began with the comprehensive survey of adsorption on mercury carried out by Gouy in the first decade of this century. His studies with the capillary electrometer are still useful but do not lend themselves to detailed quantitative analysis. A more de tailed study of a few systems by Frumkin in his thesis (1919) led him to propose a quantitative phenomenological theory of organic adsorption (1925, 1926) at almost the same time as Stern proposed the model of the electrical double layer which remains the picture accepted in general terms today. The attempt at a molecular model made by Butler (1929) should be more satisfying but up to the pres ent the formidable difficulties of a molecular theory of interfacial phenomena have prevented the full interpretation of experimental results along these lines. In his work with Proskurnin (1935), Frumkin is also respon sible for the major experimental advance in the demonstration that reliable measurements of the capacity of an electrode-solution interface can be obtained provided that the work is carried out under conditions of scrupulous cleanliness. Even so, preCise mea surements of double layer capacities were not obtained until Grahame (1941) showed how convenient and reliable the dropping mercury electrode was the for these studies. This method and the hanging drop electrode remain the preferred methods for study of adsorp tion on mercury. Solid electrodes present a more difficult problem.

Electrolysis at Stationary Spherical Mercury Electrodes ...

Electrolysis at Stationary Spherical Mercury Electrodes ... PDF Author: Kenneth John Martin
Publisher:
ISBN:
Category :
Languages : en
Pages : 234

Book Description

Fundamental Electrochemical Studies of Adsorption, Kinetics, and Excited Electronic States

Fundamental Electrochemical Studies of Adsorption, Kinetics, and Excited Electronic States PDF Author: Royce W. Murray
Publisher:
ISBN:
Category :
Languages : en
Pages : 21

Book Description
Application of modern transient techniques to the study of metal complex adsorptions at mercury electrodes has strengthened further the suspected dominating influence of the ligand adsorption properties in the adsorption process. Adsorptions of cadmium iodide, indium(III)thiocyanate, and the organometal phenyl-mercury(II) have been studied. Inhibition of electrode processes by adsorbed species has also been examined for the unusual cases of lead halides (two-dimensional crystallizations) and brucine (simulated optically active electrodes). Extensive development of the field of thin-layer electrochemistry has been made. Design, theoretical characterization, and application of twin working electrode cells have been accomplished, with emphasis on general steady-state current features and application to chemical kinetics (benzidine rearrangement, uranium(V) disproportionation). Single electrode cells have been used in potential scan coulometry and have been modified to alleviate edge diffusion effects (getter electrode). The development of thin-layer cells useful for in situ spectral measurements was also accomplished and a number of applications made (metal acetylacetonate reactions, infrared study of ninhydrin reduction, o-tolidine oxidation, fluorescence). Work in A.C. polarographic instrumentation has produced a high-performance instrument having good signal-to-noise and lacking troublesome tuned amplifier components. A study of acetylacetonate coordination chemistry has revealed a 1:2 complexation with lithium ion in acetonitrile solvent. (Author).
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