Elastic Behavior of Polymer Melts - Rheology and Processing PDF Download

Author: Helmut Münstedt
Publisher:
ISBN: 9781523126828
Category :
Languages : en
Pages :

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Author: J. A. Brydson
Publisher:
ISBN:
Category : Polymer melting
Languages : en
Pages : 250

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Author: John D. Ferry
Publisher: John Wiley & Sons
ISBN: 9780471048947
Category : Technology & Engineering
Languages : en
Pages : 676

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Book Description
Viscoelastic behavior reflects the combined viscous and elastic responses, under mechanical stress, of materials which are intermediate between liquids and solids in character. Polymers the basic materials of the rubber and plastic industries and important to the textile, petroleum, automobile, paper, and pharmaceutical industries as well exhibit viscoelasticity to a pronounced degree. Their viscoelastic properties determine the mechanical performance of the final products of these industries, and also the success of processing methods at intermediate stages of production. Viscoelastic Properties of Polymers examines, in detail, the effects of the many variables on which the basic viscoelastic properties depend. These include temperature, pressure, and time; polymer chemical composition, molecular weight and weight distribution, branching and crystallinity; dilution with solvents or plasticizers; and mixture with other materials to form composite systems. With guidance by molecular theory, the dependence of viscoelastic properties on these variables can be simplified by introducing certain ancillary concepts such as the fractional free volume, the monomeric friction coefficient, and the spacing between entanglement loci, to provide a qualitative understanding and in many cases a quantitative prediction of how to achieve desired results. The phenomenological theory of viscoelasticity which permits interrelation of the results of different types of experiments is presented first, with many useful approximation procedures for calculations given. A wide variety of experimental methods is then described, with critical evaluation of their applicability to polymeric materials of different consistencies and in different regions of the time scale (or, for oscillating deformations, the frequency scale). A review of the present state of molecular theory follows, so that viscoelasticity can be related to the motions of flexible polymer molecules and their entanglements and network junctions. The dependence of viscoestic properties on temperature and pressure, and its descriptions using reduced variables, are discussed in detail. Several chapters are then devoted to the dependence of viscoelastic properties on chemical composition, molecular weight, presence of diluents, and other features, for several characteristic classes of polymer materials. Finally, a few examples are given to illustrate the many potential applications of these principles to practical problems in the processing and use of rubbers, plastics, and fibers, and in the control of vibration and noise. The third edition has been brought up to date to reflect the important developments, in a decade of exceptionally active research, which have led to a wider use of polymers, and a wider recognition of the importance and range of application of viscoelastic properties. Additional data have been incorporated, and the book s chapters on dilute solutions, theory of undiluted polymers, plateau and terminal zones, cross-linked polymers, and concentrated solutions have been extensively rewritten to take into account new theories and new experimental results. Technical managers and research workers in the wide range of industries in which polymers play an important role will find that the book provides basic information for practical applications, and graduate students in chemistry and engineering will find, in its illustrations with real data and real numbers, an accessible introduction to the principles of viscoelasticity.

Author: Ronald G. Larson
Publisher: Butterworth-Heinemann
ISBN: 1483162869
Category : Science
Languages : en
Pages : 381

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Constitutive Equations for Polymer Melts and Solutions presents a description of important constitutive equations for stress and birefringence in polymer melts, as well as in dilute and concentrated solutions of flexible and rigid polymers, and in liquid crystalline materials. The book serves as an introduction and guide to constitutive equations, and to molecular and phenomenological theories of polymer motion and flow. The chapters in the text discuss topics on the flow phenomena commonly associated with viscoelasticity; fundamental elementary models for understanding the rheology of melts, solutions of flexible polymers, and advanced constitutive equations; melts and concentrated solutions of flexible polymer; and the rheological properties of real liquid crystal polymers. Chemical engineers and physicists will find the text very useful.

Author: Frederick R. Eirich
Publisher: Academic Press
ISBN: 1483272982
Category : Technology & Engineering
Languages : en
Pages : 662

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Book Description
Rheology: Theory and Applications, Volume 5 focuses on overtly fluid behavior of polymers, including the theory of large deformations, thermoelastic effects, elastic phenomena observed during the extrusion of polymeric melts, and theories of the structure of liquids and glasses. The selection first elaborates on the application of large deformation theory to the thermomechanical behavior of rubberlike polymers and unstable flow of molten polymers. Discussions focus on the mechanism proposed for unstable flow, ripple and associated effects, direct observation of waviness phenomena, empirical behavior of porous, unfilled, and filled rubberlike polymers, and problems connected with the interpretation of mechanical response parameters. The text then examines elasticity effects in polymer extrusion and strength and extensibility of elastomers. The publication takes a look at free volume and polymer rheology and studies of the deformation of crystalline polymers. Topics include the contribution of the two orientation processes to the birefringence, deformation of superstructure, rate of orientation of crystalline regions, free volume and physical state, glass transition and free volume, and reappraisal of time-temperature superposition. The manuscript also elaborates on the deformation and dissipative processes in high polymeric solids and the thermodynamics of deformation. The selection is a vital source of data for researchers interested in the theories and applications of rheology.

Author: Lawrence E. Nielsen
Publisher:
ISBN:
Category : Technology & Engineering
Languages : en
Pages : 222

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Author: Helmut Münstedt
Publisher: Carl Hanser Verlag GmbH Co KG
ISBN: 1569907552
Category : Technology & Engineering
Languages : en
Pages : 299

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Book Description
Understanding the elastic properties of polymer melts is necessary for ensuring successful polymer processing and thus producing high-quality plastic parts. This unique book is the first to focus on this important topic. Starting with the molecular origin of elastic behavior and an explanation of the physical quantities involved, experimental methods and the dependence of elastic behavior on experimental parameters are then presented. Elastic properties of filled and unfilled systems are compared directly, and polymer blends are also considered. Elastic effects in various applications are included, such as in extrudate swell, internal stresses, and shrink films, to illustrate the importance of this field in the plastics processing industry.

Author: Ravin Narain
Publisher: Elsevier
ISBN: 0128168072
Category : Technology & Engineering
Languages : en
Pages : 488

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Book Description
Polymer Science and Nanotechnology: Fundamentals and Applications brings together the latest advances in polymer science and nanoscience. Sections explain the fundamentals of polymer science, including key aspects and methods in terms of molecular structure, synthesis, characterization, microstructure, phase structure and processing and properties before discussing the materials of particular interest and utility for novel applications, such as hydrogels, natural polymers, smart polymers and polymeric biomaterials. The second part of the book examines essential techniques in nanotechnology, with an emphasis on the utilization of advanced polymeric materials in the context of nanoscience. Throughout the book, chapters are prepared so that materials and products can be geared towards specific applications. Two chapters cover, in detail, major application areas, including fuel and solar cells, tissue engineering, drug and gene delivery, membranes, water treatment and oil recovery. - Presents the latest applications of polymers and polymeric nanomaterials, across energy, biomedical, pharmaceutical, and environmental fields - Contains detailed coverage of polymer nanocomposites, polymer nanoparticles, and hybrid polymer-metallic nanoparticles - Supports an interdisciplinary approach, enabling readers from different disciplines to understand polymer science and nanotechnology and the interface between them

Author: Montgomery T. Shaw
Publisher: John Wiley & Sons
ISBN: 0470388447
Category : Technology & Engineering
Languages : en
Pages : 410

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Book Description
An introduction to the rheology of polymers Designed for practicing scientists and engineers interested in polymer rheology science, education, consulting, or research and development, Introduction to Polymer Rheology is a comprehensive yet accessible guide to the study of the deformation and flow of matter under applied stress. Often considered a complicated topic for beginners, the book makes grasping the fundamentals of polymer rheology easy by presenting information in an approachable way and limiting the use of complex mathematics. By doing so, this introductory overview provides readers with easy access to the key concepts underlying the flow behavior of polymer melts, solutions, and suspensions. Incorporating sample problems that are worked through and explained on the page, as well as numerous practice problems to gauge learning comprehension, the book prepares new students and practitioners for moving on to more advanced concepts. Comprising twelve chapters, the book covers stress, velocity and rate of deformation, the relationship between stress and rate of deformation (Newtonian fluid), generalized Newtonian fluids, normal stresses and elastic behavior, experimental methods, small and large strain, the molecular origins of rheological behavior, elementary polymer processing concepts, quality control in rheology, and the flow of modified polymers and those with supermolecular structure. The essential reference for accurately interpreting polymer rheology data, Introduction to Polymer Rheology provides readers with an elementary understanding of the key issues and modern approaches to resolving problems in the field.

Author: Christopher W. Macosko
Publisher: VCH Publishers
ISBN:
Category : Science
Languages : en
Pages : 576

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Book Description
Rheology: Principles, Measurements, and Applications will be of greatest interest to chemical engineers, chemists, polymer scientists, and mechanical engineers, as well as students in these and related fields.