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Effects of Impurities on the Processing of Aluminum Alloys

Effects of Impurities on the Processing of Aluminum Alloys PDF Author:
Publisher:
ISBN:
Category :
Languages : en
Pages :

Book Description
Project partners are investigating the effect of impurities on aluminum alloy processing with the aim of lower product rejection rates with the resultant effect of lower melt losses.

Effects of Impurities on the Processing of Aluminum Alloys

Effects of Impurities on the Processing of Aluminum Alloys PDF Author:
Publisher:
ISBN:
Category :
Languages : en
Pages :

Book Description
Project partners are investigating the effect of impurities on aluminum alloy processing with the aim of lower product rejection rates with the resultant effect of lower melt losses.

The Effect of Impurities on the Processing of Aluminum Alloys

The Effect of Impurities on the Processing of Aluminum Alloys PDF Author:
Publisher:
ISBN:
Category :
Languages : en
Pages :

Book Description
For this Aluminum Industry of the Future (IOF) project, the effect of impurities on the processing of aluminum alloys was systematically investigated. The work was carried out as a collaborative effort between the Pennsylvania State University and Oak Ridge National Laboratory. Industrial support was provided by ALCOA and ThermoCalc, Inc. The achievements described below were made. A method that combines first-principles calculation and calculation of phase diagrams (CALPHAD) was used to develop the multicomponent database Al-Ca-K-Li-Mg-Na. This method was extensively used in this project for the development of a thermodynamic database. The first-principles approach provided some thermodynamic property data that are not available in the open literature. These calculated results were used in the thermodynamic modeling as experimental data. Some of the thermodynamic property data are difficult, if not impossible, to measure. The method developed and used in this project allows the estimation of these data for thermodynamic database development. The multicomponent database Al-Ca-K-Li-Mg-Na was developed. Elements such as Ca, Li, Na, and K are impurities that strongly affect the formability and corrosion behavior of aluminum alloys. However, these impurity elements are not included in the commercial aluminum alloy database. The process of thermodynamic modeling began from Al-Na, Ca-Li, Li-Na, K-Na, and Li-K sub-binary systems. Then ternary and higher systems were extrapolated because of the lack of experimental information. Databases for five binary alloy systems and two ternary systems were developed. Along with other existing binary and ternary databases, the full database of the multicomponent Al-Ca-K-Li-Mg-Na system was completed in this project. The methodology in integrating with commercial or other aluminum alloy databases can be developed. The mechanism of sodium-induced high-temperature embrittlement (HTE) of Al-Mg is now understood. Using the thermodynamic database developed in this project, thermodynamic simulations were carried out to investigate the effect of sodium on the HTE of Al-Mg alloys. The simulation results indicated that the liquid miscibility gap resulting from the dissolved sodium in the molten material plays an important role in HTE. A liquid phase forms from the solid face-centered cubic (fcc) phase (most likely at grain boundaries) during cooling, resulting in the occurrence of HTE. Comparison of the thermodynamic simulation results with experimental measurements on the high-temperature ductility of an Al-5Mg-Na alloy shows that HTE occurs in the temperature range at which the liquid phase exists. Based on this fundamental understanding of the HTE mechanism during processing of aluminum alloy, an HTE sensitive zone and a hot-rolling safe zone of the Al-Mg-Na alloys are defined as functions of processing temperature and alloy composition. The tendency of HTE was evaluated based on thermodynamic simulations of the fraction of the intergranular sodium-rich liquid phase. Methods of avoiding HTE during rolling/extrusion of Al-Mg-based alloys were suggested. Energy and environmental benefits from the results of this project could occur through a number of avenues: (1) energy benefits accruing from reduced rejection rates of the aluminum sheet and bar, (2) reduced dross formation during the remelting of the aluminum rejects, and (3) reduced CO2 emission related to the energy savings. The sheet and extruded bar quantities produced in the United States during 2000 were 10,822 and 4,546 million pounds, respectively. It is assumed that 50% of the sheet and 10% of the bar will be affected by implementing the results of this project. With the current process, the rejection rate of sheet and bar is estimated at 5%. Assuming that at least half of the 5% rejection of sheet and bar will be eliminated by using the results of this project and that 4% of the aluminum will be lost through dross (Al2O3) during remelting of the rejects, the full-scale industrial implementation of the project results would lead to energy savings in excess of 6.2 trillion Btu/year and cost savings of $42.7 million by 2020.

Aluminium Alloys

Aluminium Alloys PDF Author: Subbarayan Sivasankaran
Publisher: BoD – Books on Demand
ISBN: 9535136976
Category : Technology & Engineering
Languages : en
Pages : 326

Book Description
The major issue of energy saving and conservation of the environment in the world is being emphasized to us to concentrate on lightweight materials in which aluminium alloys are contributing more in applications in the twenty-first century. Aluminium and its related materials possess lighter weight, considerable strength, more corrosion resistance and ductility. Especially from the past one decade, the use of aluminium alloys is increasing in construction field, transportation industries, packaging purposes, automotive, defence, aircraft and electrical sectors. Around 85% is being used in the form of wrought products, which replace the use of cast iron. Further, the major features of aluminium alloy are recyclability and its abundant availability in the world. In general, aluminium and its related materials are being processed via casting, drawing, forging, rolling, extrusion, welding, powder metallurgy process, etc. To improve the physical and mechanical properties, scientists are doing more research and adding some second-phase particles in to it called composites in addition to heat treatment. Therefore, to explore more in this field, the present book has been aimed and focused to bridge all scientists who are working in this field. The main objective of the present book is to focus on aluminium, its alloys and its composites, which include, but are not limited to, the various processing routes and characterization techniques in both macro- and nano-levels.

The Effects of Impurities on the Mechanical Behaviour of Primary and Secondary Cast Aluminium Alloys

The Effects of Impurities on the Mechanical Behaviour of Primary and Secondary Cast Aluminium Alloys PDF Author: Juhani Eklund
Publisher:
ISBN: 9789512208852
Category :
Languages : en
Pages :

Book Description


Impurities in Engineering Materials

Impurities in Engineering Materials PDF Author: Clyde Briant
Publisher: Routledge
ISBN: 1351439065
Category : Technology & Engineering
Languages : en
Pages : 328

Book Description
Provides a state-of-the-art account of the various effects of impurities on the properties of engineering alloys. Outlines a wide range of methods for producing cleaner alloys. Traces the technological advances that allow the economical manufacture of purer materials.

Separation of Cast and Wrought Aluminum Alloys by Thermo-mechanical Processing

Separation of Cast and Wrought Aluminum Alloys by Thermo-mechanical Processing PDF Author: Robert Duane Brown
Publisher:
ISBN:
Category : Aluminum alloys
Languages : en
Pages : 20

Book Description


Semi-Solid Processing of Aluminum Alloys

Semi-Solid Processing of Aluminum Alloys PDF Author: Shahrooz Nafisi
Publisher: Springer
ISBN: 3319403354
Category : Technology & Engineering
Languages : en
Pages : 372

Book Description
This book describes in great detail the semi-solid processing of aluminum alloys. The authors examine the fundamentals of semi-solid metal processing, provide guidelines for research, illustrate the tools that are employed, and explain the measured parameters for semi-solid processing characterization.

Foundry Processes

Foundry Processes PDF Author: Seymour Katz
Publisher: Springer Science & Business Media
ISBN: 146131013X
Category : Technology & Engineering
Languages : en
Pages : 527

Book Description
For a number of years it has been a General Motors Research Laboratories custom to hold a symposium on a subject which is new and emerging, and to invite the best people in the world in that subject to come together to talk to each other. Initially, I had some difficulty in regarding foundry processes as a new and emerging subject. Copper alloys have been in foundry practice for about six thousand years. Foundrymen working with those alloys have been recognized, as such, for nearly all that time. Iron has a much shorter history, probably only three or four thousand years. So what's new? What is new is that a subject which has always been so complex and so difficult that it could only be a craft skill, with bits and pieces of knowledge and bits and pieces of insight, has begun to yield to new abilities to solve very complex problems. We do this now because we can handle great amounts of data by computational means, using new and more complicated theoretical treatments than we could deal with before. In fact, we have a new technology with which we can attack these terribly difficult problems. Thus, foundry processing is becoming a new subject because new things can be done with it.

Separation Technologies for the Industries of the Future

Separation Technologies for the Industries of the Future PDF Author: Panel on Separation Technology for Industrial Reuse and Recycling
Publisher: National Academies Press
ISBN: 0309592828
Category : Technology & Engineering
Languages : en
Pages : 128

Book Description
Separation processes—or processes that use physical, chemical, or electrical forces to isolate or concentrate selected constituents of a mixture—are essential to the chemical, petroleum refining, and materials processing industries. In this volume, an expert panel reviews the separation process needs of seven industries and identifies technologies that hold promise for meeting these needs, as well as key technologies that could enable separations. In addition, the book recommends criteria for the selection of separations research projects for the Department of Energy's Office of Industrial Technology.

Casting Aluminum Alloys

Casting Aluminum Alloys PDF Author: Michael V Glazoff
Publisher: Butterworth-Heinemann
ISBN: 0128121149
Category : Technology & Engineering
Languages : en
Pages : 564

Book Description
Casting Aluminum Alloys, Second Edition, the follow up to the fall 2007 work on the structure, properties, thermal resistance, corrosion and fatigue of aluminum alloys in industrial manufacturing, discusses findings from the past decade, including sections on new casting alloys, novel casting technologies, and new methods of alloys design. The book also includes other hot topics, such as the implementation of computational technologies for the calculation of phase equilibria and thermodynamic properties of alloys, the development of software for calculation of diffusion processes in aluminum alloys, computational modeling of solidification microstructure and texture evolution of multi-component aluminum materials. In addition to changes in computational predictive abilities, there is a review of novel casting aluminum alloy compositions and properties, as well as descriptions of new casting technologies and updates to coverage on the mechanical properties of aluminum casting alloys. - Presents a discussion of thermodynamic calculations used for assessing non-equilibrium solidifications of casting aluminum alloys - Expands coverage of mathematical models for alloy mechanical properties, helping facilitate the selection of the best prospective candidate for new alloy development - Contains a new section that describes the self-consistent evaluation of phase equilibria and thermodynamic properties of aluminum alloys