Author: Seyed Morteza Sabet Publisher: ISBN: Category : Carbon composites Languages : en Pages : 173
Book Description
In fabrication of nanoparticle-reinforced polymers, two critical factors need to be taken into account to control properties of the final product; nanoparticle dispersion/distribution in the matrix; and interfacial interactions between nanoparticles and their surrounding matrix. The focus of this thesis was to examine the role of these two factors through experimental methodologies and molecular-level simulations. Carbon nanotubes (CNTs) and vinyl ester (VE) resin were used as nanoparticles and matrix, respectively. In a parametric study, a series of CNT/VE nanocomposites with different CNT dispersion conditions were fabricated using the ultrasonication mixing method. Thermomechanical properties of nanocomposites and quality of CNT dispersion were evaluated. By correlation between nanocomposite behavior and CNT dispersion, a thermomechanical model was suggested; at a certain threshold level of sonication energy, CNT vii dispersion would be optimal and result in maximum enhancement in properties. This threshold energy level is also related to particle concentration. Sonication above this threshold level, leads to destruction of nanotubes and renders a negative effect on the properties of nanocomposites. In an attempt to examine the interface condition, a novel process was developed to modify CNT surface with polyhedral oligomeric silsesquioxane (POSS). In this process, a chemical reaction was allowed to occur between CNTs and POSS in the presence of an effective catalyst. The functionalized CNTs were characterized using TEM, SEM-EDS, AFM, TGA, FTIR and Raman spectroscopy techniques. Formation of amide bonds between POSS and nanotubes was established and verified. Surface modification of CNTs with POSS resulted in significant improvement in nanotube dispersion. In-depth SEM analysis revealed formation of a 3D network of well-dispersed CNTs with POSS connections to the polymer. In parallel, molecular dynamics simulation of CNT-POSS/VE system showed an effective load transfer from polymer chains to the CNT due to POSS linkages at the interface. The rigid and flexible network of CNTs is found to be responsible for enhancement in elastic modulus, strength, fracture toughness and glass transition temperature (Tg) of the final nanocomposites.
Author: Jiji Abraham Publisher: Springer Nature ISBN: 3030913465 Category : Technology & Engineering Languages : en Pages : 2099
Book Description
This Handbook covers the fundamentals of carbon nanotubes (CNT), their composites with different polymeric materials (both natural and synthetic) and their potential advanced applications. Three different parts dedicated to each of these aspects are provided, with chapters written by worldwide experts in the field. It provides in-depth information about this material serving as a reference book for a broad range of scientists, industrial practitioners, graduate and undergraduate students, and other professionals in the fields of polymer science and engineering, materials science, surface science, bioengineering and chemical engineering. Part 1 comprises 22 chapters covering early stages of the development of CNT, synthesis techniques, growth mechanism, the physics and chemistry of CNT, various innovative characterization techniques, the need of functionalization and different types of functionalization methods as well as the different properties of CNT. A full chapter is devoted to theory and simulation aspects. Moreover, it pursues a significant amount of work on life cycle analysis of CNT and toxicity aspects. Part 2 covers CNT-based polymer nanocomposites in approximately 23 chapters. It starts with a short introduction about polymer nanocomposites with special emphasis on CNT-based polymer nanocomposites, different manufacturing techniques as well as critical issues concerning CNT-based polymer nanocomposites. The text deeply reviews various classes of polymers like thermoset, elastomer, latex, amorphous thermoplastic, crystalline thermoplastic and polymer fibers used to prepare CNT based polymer composites. It provides detailed awareness about the characterization of polymer composites. The morphological, rheological, mechanical, viscoelastic, thermal, electrical, electromagnetic shielding properties are discussed in detail. A chapter dedicated to the simulation and multiscale modelling of polymer nanocomposites is an additional attraction of this part of the Handbook. Part 3 covers various potential applications of CNT in approximately 27 chapters. It focuses on individual applications of CNT including mechanical applications, energy conversion and storage applications, fuel cells and water splitting, solar cells and photovoltaics, sensing applications, nanofluidics, nanoelectronics and microelectronic devices, nano-optics, nanophotonics and nano-optoelectronics, non-linear optical applications, piezo electric applications, agriculture applications, biomedical applications, thermal materials, environmental remediation applications, anti-microbial and antibacterial properties and other miscellaneous applications and multi-functional applications of CNT based polymer nanocomposites. One chapter is fully focussed on carbon nanotube research developments: published papers and patents. Risks associated with carbon nanotubes and competitive analysis of carbon nanotubes with other carbon allotropes are also addressed in this Handbook.
Author: Dimitrios Tasis Publisher: Royal Society of Chemistry ISBN: 1782625828 Category : Technology & Engineering Languages : en Pages : 293
Book Description
Chemically-modified carbon nanotubes (CNTs) exhibit a wide range of physical and chemical properties which makes them an attractive starting material for the preparation of super-strong and highly-conductive fibres and films. Much information is available across the primary literature, making it difficult to obtain an overall picture of the state-of-the-art. This volume brings together some of the leading researchers in the field from across the globe to present the potential these materials have, not only in developing and characterising novel materials but also the devices which can be fabricated from them. Topics featured in the book include Raman characterisation, industrial polymer materials, actuators and sensors and polymer reinforcement, with chapters prepared by highly-cited authors from across the globe. A valuable handbook for any academic or industrial laboratory, this book will appeal to newcomers to the field and established researchers alike.
Author: Arvind Agarwal Publisher: CRC Press ISBN: 1439811504 Category : Technology & Engineering Languages : en Pages : 318
Book Description
From the Foreword, written by legendary nano pioneer M. Meyyappan, Chief Scientist for Exploration Technology NASA Ames Research Center, Moffett Field, California, USA: "...there is critical need for a book to summarize the status of the field but more importantly to lay out the principles behind the technology. This is what Professor Arvind Agarwal and his co-workers ... have done here." Carbon Nanotubes: Reinforced Metal Matrix Composites reflects the authors’ desire to share the benefits of nanotechnology with the masses by developing metal matrix carbon nanotube (MM-CNT) composites for large-scale applications. Multiwall carbon nanotubes can now be produced on a large scale and at a significantly reduced cost. The book explores potential applications and applies the author’s own research to highlight critical developmental issues for different MM-CNT composites—and then outline novel solutions. With this problem-solving approach, the book explores: Advantages, limitations, and the evolution of processing techniques used for MM-CNT composites Characterization techniques unique to the study of MM-CNT composites—and the limitations of these methods Existing research on different MM-CNT composites, presented in useful tables that include composition, processing method, quality of CNT dispersion, and properties The micro-mechanical strengthening that results from adding CNT The applicability of micro-mechanics models in MM-CNT composites Significance of chemical stability for carbon nanotubes in the metal matrix as a function of processing, and its impact on CNT/metal interface and mechanical properties Computational studies that have not been sufficiently covered although they are essential to research and development The critical issue of CNT dispersion in the metal matrix, as well as a unique way to quantify CNT distribution and subsequently improve control of the processing parameters for obtaining improved properties Carbon Nanotubes: Reinforced Metal Matrix Composites paints a vivid picture of scientific and application achievements in this field. Exploring the mechanisms through which CNTs are enhancing the properties of different metal-based composites, the authors provide a roadmap to help researchers develop MM-CNT composites and choose potential materials for use in emerging areas of technology.
Author: Anna Boczkowska Publisher: Mdpi AG ISBN: 9783036522012 Category : Technology & Engineering Languages : en Pages : 128
Book Description
The Special issue, "Carbon nanotube-based nanocomposites", provides an extensive overview of current trends in the area of polymer matrix nanocomposites based on carbon nanotubes (CNTs) from the papers contributed by internationally recognized specialists. The Special Issue brings together 7 papers that deal with the various aspects of processing, as well as experimental and analytical approaches to carbon nanotube-based nanocomposites fabrication, characterization and application. Each paper demonstrates how enhancements in materials, processes and characterization techniques can improve performance in the field of engineering. The Special issue gives a unique opportunity to discover the latest research on carbon nanotube-based nanocomposites from different laboratories. Numerous references are given at the end of each paper to enable the reader to explore the topics covered in greater detail. Most of the papers describe the improvement of electrical and mechanical properties of polymer-based nanocomposites due to the application of CNTs, independently on the matrix used: (ethylene vinyl acetate) copolymer, hot melt copolyamides, epoxy and silicone resins. In each case, the relationships between the processing parameters and microstructure of obtained nanocomposites were described. The synergistic effect of hybrid nanofillers was also explored in nanocomposites with carbon and halloysite nanotubes. The effect of carbon nanotubes on the wear behavior of nanocomposites based on epoxy resin was investigated as well. The original results on the synthesis and characterization of composite shear thickening fluids containing carbon nanofillers are presented. The addition of the CNTs modified the impact absorption ability of such fluids. The presented Special Issue results also proved that CNTs can be used to obtain more resistant and durable cement-based composites.
Author: Peng-Cheng Ma Publisher: CRC Press ISBN: 1439826242 Category : Technology & Engineering Languages : en Pages : 210
Book Description
Discovered in the twentieth century, carbon nanotubes (CNT) were an integral part of science and industry by the beginning of the twenty first century, revolutionizing chemistry, physics, and materials science. More recent advances in carbon nanotube production methods have resulted in a tremendous push to incorporate CNTs into polymer matrices. Al
Author: Andy Nieto Publisher: CRC Press ISBN: 1000377504 Category : Technology & Engineering Languages : en Pages : 376
Book Description
This discovery of carbon nanotubes (CNT) three decades ago ushered in the technological era of nanotechnology. Among the most widely studied areas of CNT research is their use as structural reinforcements in composites. This book describes the development of CNT reinforced metal matrix composites (CNT-MMCs) over the last two decades. The field of CNT-MMCs is abundant in fundamental science, rich in engineering challenges and innovations and ripe for technological maturation and commercialization. The authors have sought to present the current state of the-art in CNT-MMC technology from their synthesis to their myriad potential end-use applications. Specifically, topics explored include: • Advantages, limitations, and evolution of processing techniques used to synthesize and fabricate CNT-MMCs • Emphasizes dispersion techniques of CNTs in metallic systems, a key challenge to the successful and widespread implementation of CNT-MMCs. Methods for quantification and improved control of CNT distributions are presented • Methods for quantification and improved control of CNT distributions are presented • Characterization techniques uniquely suited for charactering these nanoscale materials and their many chemical and physical interactions with the metal matrix, including real-time in-situ characterization of deformation mechanisms • Electron microscope images from premier studies enrich discussions on micro-mechanical modeling, interfacial design, mechanical behavior, and functional properties • A chapter is dedicated to the emergence of dual reinforcement composites that seek to enhance the efficacy of CNTs and lead to material properties by design This book highlights seminal findings in CNT-MMC research and includes several tables listing processing methods, associated CNT states, and resulting properties in order to aid the next generation of researchers in advancing the science and engineering of CNT-MMCs. In addition, a survey of the patent literature is presented in order to shed light on what the first wave of CNT-MMC commercialization may look like and the challenges that will have to be overcome, both technologically and commercially.
Author: Marcio Loos Publisher: Elsevier ISBN: 145573196X Category : Technology & Engineering Languages : en Pages : 305
Book Description
Carbon Nanotube Reinforced Composites introduces a wide audience of engineers, scientists and product designers to this important and rapidly expanding class of high performance composites. Dr Loos provides readers with the scientific fundamentals of carbon nanotubes (CNTs), CNT composites and nanotechnology in a way which will enable them to understand the performance, capability and potential of the materials under discussion. He also investigates how CNT reinforcement can be used to enhance the mechanical, electrical and thermal properties of polymer composites. Production methods, processing technologies and applications are fully examined, with reference to relevant patents. Finally, health and safety issues related to the use of CNTs are investigated. Dr. Loos compares the theoretical expectations of using CNTs to the results obtained in labs, and explains the reasons for the discrepancy between theoretical and experimental results. This approach makes the book an essential reference and practical guide for engineers and product developers working with reinforced polymers – as well as researchers and students in polymer science, materials and nanotechnology. A wealth of applications information is included, taken from the wide range of industry sectors utilizing CNT reinforced composites, such as energy, coatings, defense, electronics, medical devices, and high performance sports equipment. Introduces a wide range of readers involved in plastics engineering, product design and manufacturing to the relevant topics in nano-science, nanotechnology, nanotubes and composites. Assesses effects of CNTs as reinforcing agents, both in a materials context and an applications setting. Focuses on applications aspects – performance, cost, health and safety, etc – for a wide range of industry sectors, e.g. energy, coatings, defense, electronics, medical devices, high performance sports equipment, etc.
Author: Andres Alvarez Publisher: ISBN: Category : Carbon composites Languages : en Pages : 122
Book Description
Current applications within areas such as electronics, military, and aerospace are demanding for lightweight and high-performing composite systems. More specifically, thermosetting formulations with minimal hazardous emissions that are used for high-temperature applications are in high demand. Cyanate ester resin (CE) has a high glass transition temperature (Tg, as high as 350oC), excellent flammability, thermal stability, mechanical properties, and it does not release harmful volatiles during the cure process. Multiwall carbon nanotubes (MWCNT) can offer excellent electrical and thermal conductivity, structural strength and stiffness, and thermal stability. The enhancement of the resin's properties is highly dependent on the qualitative and quantitative dispersion of MWCNT. In this research, CE was blended with MWCNT (0.5%, 1%, and 1.5% by weight) using a combination of a Planetary Centrifugal Mixer (THINKY) and a Stand Mixer. In order to improve dispersion, MWCNTs were processed with ceramic beads using the THINKY mixer to break-up the entangled nanoparticles. Transmission electron microscopy (TEM) was performed to evaluate separation of MWCNT entanglements. Carbon fiber-reinforced nanomodified cyanate ester composite panels were manufactured using a wet layup process followed by compression molding. Mechanical tests were then performed to evaluate tensile strength and modulus, flexural strength and modulus, compressive strength and modulus, and short-beam shear strength. Thermogravimetric analysis (TGA) was used to study the four different formulations thermal stability in both air and nitrogen. Lastly, the flammability properties were also analyzed with micro combustion calorimetry (MCC). Results were compared with control samples showing a positive effect of MWCNT on the final properties of carbon-reinforced cyanate ester composites.
Author: Oxana Vasilievna Kharissova Publisher: Springer ISBN: 3319629506 Category : Technology & Engineering Languages : en Pages : 258
Book Description
This book describes a series of contemporary techniques and their combinations used for CNTs solubilization, from physical to chemical and biological, applying inorganic and organic compounds, as well as some metal complexes. In some cases, successive steps can be applied, for instance the use of low and high-weight surfactants, or mineral acid treatment for creation of –OH and –COOH groups and their further interaction with organic molecules. Each discussed method leads to an improvement of CNT solubility, frequently a considerable one. The formed dispersions can be stable for long periods of time, from several weeks to some months, and they sometimes even remain stable after centrifugation. Several special studies have been carried out in the areas of influence of solvent and light on CNTs dispersibility, combinations and abilities of surfactants, CNT cytotoxicity, etc. Applications of solubilized CNTs are discussed in this book as well.
Author: Seyed Morteza Sabet
Author: Jiji Abraham
Author: Dimitrios Tasis
Author: Arvind Agarwal
Author: Anna Boczkowska
Author: Peng-Cheng Ma
Author: Andy Nieto
Author: Marcio Loos
Author: Andres Alvarez
Author: Oxana Vasilievna Kharissova