Dynamics of Polymerization Induced Phase Separation in Reactive Polymer Blends PDF Download

Author: Jaehyung Lee
Publisher:
ISBN:
Category : Crosslinked polymers
Languages : en
Pages : 534

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Author: Daniel J. Duffy
Publisher:
ISBN:
Category : Phase partition
Languages : en
Pages : 684

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Author: Boris A Rozenberg
Publisher: CRC Press
ISBN: 1134453841
Category : Technology & Engineering
Languages : en
Pages : 252

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Book Description
This volume explains the theory and experimental investigations in the preparation of heterophase polymer network materials through cure reaction-induced microphase separation (CRIMPS). It describes the synthesis of a new family of block- and graft-copolymers with controlled solubility in epoxies and characterizes CRIMPS processes using novel applications of known methods such as nuclear magnetic resonance, electron spin resonance and photochemistry. The text develops a new method for characterizing the molecular mass distribution (MMD) of linear and network polymers using thermomechanical analysis data, as well as new methods for determining internal stresses and flaw formation during thermoset curing. The CRIMPS theory will be helpful for researchers and engineers designing and improving toughened plastics and other smart heterophase network materials for different applications. The new method for MMD characterization of polymers in bulk will be very useful to quickly analyze a polymer's MMD and to design new polymers. This book will provide a useful reference for graduates, researchers and working professionals in polymer chemistry and physics and materials science.

Author: Ezio Martuscelli
Publisher: VSP
ISBN: 9789067640916
Category : Science
Languages : en
Pages : 232

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Book Description
The development of new polymeric materials has caused a considerable expansion in the field of reactive processing. These new materials are very competitive compared to the traditional ones with respect to production costs and performance. The reports published in this volume present the recent developments and emerging trends in the field of reactive processing and the physical properties of the resulting polymeric materials. Special attention is given to the chemical, kinetic and rheological aspects of reactive processing.

Author: Suprakas Sinha Ray
Publisher: Carl Hanser Verlag GmbH Co KG
ISBN: 1569909199
Category : Technology & Engineering
Languages : en
Pages : 215

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Book Description
Phase separation in polymer blends has achieved a tremendous techno-commercial importance. Most of the applications of polymer blends, such as tissue engineering, membrane technology, electromagnetic shielding, energy harvesting, structural materials, packaging, smart multiphase polymer coatings, depend on the morphologies developed during processing. This book outlines the fundamental aspects of polymer blend thermodynamics, the state-of-the-art processing techniques for specific polymer blend systems currently in use, and the design and fabrication of multiphasic polymeric materials, which will present a multiplicity of opportunities in the water remediation, packaging, and electronic industries, to mention a few. It emphasizes recent research developments, processing techniques, characterization methods, factors influencing phase separation temperature in phase-separated, including partially miscible, polymer blends, and key research challenges in the development of phase-separated polymers materials. With unique and systematic coverage of the journey from fundamentals to applications in polymer blends, this book is ideal for polymer scientists and engineers, material scientists, researchers, engineers, and under- and post-graduate students who are interested in this exciting field of research. It will help industrial researchers and R&D managers bring advanced phase-separated polymer materials/products to the market.

Author: Chen Kuang
Publisher:
ISBN:
Category : Polymers
Languages : en
Pages : 154

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Book Description
Phase separation in complex fluids such as polymers has been the subject of several experimental and theoretical studies in recent years. Understanding the phase separation mechanisms and controlling morphological evolution are very important for designing various advanced materials with novel mechanical, optical, electrical, and transport properties. In polymer blends, dynamic asymmetry is induced by a large difference in glass transition temperature. In this work, phase separation behavior of ternary blends of polystyrene/poly(vinyl methyl ether)/polyisoprene, PS/PVME/PI, and polystyrene/poly(vinyl methyl ether)/poly(ethyl methacrylate), PS/PVME/PEMA are investigated. Ternary blends of PS/PVME/PI and PS/PVME/PEMA exhibit complex phase separation behavior since PS and PVME have a lower critical solution temperature (LCST) behavior, while PI and PS (or PVME), PEMA and PS (or PVME) have upper critical solution temperature (UCST) behavior. 2D and 3D phase diagrams for these two ternary systems were plotted by both Flory-Huggins incompressible and regular solution compressible models. Casting the solutions of PS/PVME/PI and PS/PVME/PEMA blends form two phase-separated domains in most compositions: (i) PI-rich or PEMA rich, and (ii) PS/PVME-rich. Post-annealing of such samples leads to the second-stage phase separation due to unfavorable interaction of PS and PVME at temperatures about 100°C. Such behavior that is observed for the first time provides a new potential method for making different morphologies with the same system by changing annealing parameters and composition. Washing one polymer at a time using a selective solvent is used to study the morphology of ternary blends. Optical microscopy and scanning electron microscopy are used to study the kinetics and morphology of viscoelastic phase separation (VPS) in ternary blends.

Author: John A. Pojman
Publisher: John Wiley & Sons
ISBN: 352763262X
Category : Science
Languages : en
Pages : 391

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Book Description
Closing a gap in the literature, this is the first comprehensive handbook on this modern and important polymer topic. Edited by highly experienced and top scientists in the field, this ready reference covers all aspects, including material science, biopolymers, gels, phase separating systems, frontal polymerization and much more. The introductory chapter offers the perfect starting point for the non-expert.

Author: Sabu Thomas
Publisher: John Wiley & Sons
ISBN: 3527331530
Category : Science
Languages : en
Pages : 972

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Book Description
Filling the gap for a reference dedicated to the characterization of polymer blends and their micro and nano morphologies, this book provides comprehensive, systematic coverage in a one-stop, two-volume resource for all those working in the field. Leading researchers from industry and academia, as well as from government and private research institutions around the world summarize recent technical advances in chapters devoted to their individual contributions. In so doing, they examine a wide range of modern characterization techniques, from microscopy and spectroscopy to diffraction, thermal analysis, rheology, mechanical measurements and chromatography. These methods are compared with each other to assist in determining the best solution for both fundamental and applied problems, paying attention to the characterization of nanoscale miscibility and interfaces, both in blends involving copolymers and in immiscible blends. The thermodynamics, miscibility, phase separation, morphology and interfaces in polymer blends are also discussed in light of new insights involving the nanoscopic scale. Finally, the authors detail the processing-morphology-property relationships of polymer blends, as well as the influence of processing on the generation of micro and nano morphologies, and the dependence of these morphologies on the properties of blends. Hot topics such as compatibilization through nanoparticles, miscibility of new biopolymers and nanoscale investigations of interfaces in blends are also addressed. With its application-oriented approach, handpicked selection of topics and expert contributors, this is an outstanding survey for anyone involved in the field of polymer blends for advanced technologies.

Author: Domasius Nwabunma
Publisher:
ISBN:
Category : Monomers
Languages : en
Pages : 472

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Author:
Publisher:
ISBN:
Category : Dissertations, Academic
Languages : en
Pages : 924

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