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Dienamine Catalysis for Organic Synthesis

Dienamine Catalysis for Organic Synthesis PDF Author: Kengadarane Anebouselvy
Publisher: Royal Society of Chemistry
ISBN: 1788014324
Category : Science
Languages : en
Pages : 220

Book Description
In the past decade a new era in asymmetric catalysis has been realised by the discovery of L-proline induced chiral enamines from carbonyls. Inspired by this, researchers have developed many other primary catalytic species in situ, more recently secondary catalytic species such as aminals have been identified for use in asymmetric synthesis. High-yielding asymmetric synthesis of bioactive and natural products through mild catalysis is an efficient approach in reaction engineering. In the early days, synthetic chemists mainly focused on the synthesis of complex molecules, with less attention on the reaction efficiency and eco-friendly conditions. Recent investigations have been directed towards the development of atom economy, eco-friendly and enantioselective synthesis for more targeted and efficient synthesis. Building on the momentum of this rapidly expanding research area, Dienamine Catalysis for Organic Synthesis will provide a comprehensive introduction, from the preformed species, in situ generation and onto their applications in the synthesis of bioactive molecules and natural products.

Dienamine Catalysis for Organic Synthesis

Dienamine Catalysis for Organic Synthesis PDF Author: Kengadarane Anebouselvy
Publisher: Royal Society of Chemistry
ISBN: 1782620907
Category : Science
Languages : en
Pages : 220

Book Description
In the last decade a new era in asymmetric catalysis has been realised by the discovery of L-proline induced chiral enamines from carbonyls. Inspired by this, researchers have developed many other primary catalytic species in situ, more recently secondary catalytic species such as aminals have been identified for use in asymmetric synthesis. High-yielding asymmetric synthesis of bioactive and natural products through mild catalysis is an efficient approach in reaction engineering. In the early days, synthetic chemists mainly focused on the synthesis of complex molecules, with less attention on the reaction efficiency and eco-friendly conditions. Recent investigations have been directed towards the development of atom economy, eco-friendly and enantioselective synthesis for more targeted and efficient synthesis. Building on the momentum of this rapidly expanding research area, Dienamine catalysis for organic synthesis will provide a comprehensive introduction, from the preformed species, in situ generation and onto their applications in the synthesis of bioactive molecules and natural products.

Catalysis of Organic Reactions

Catalysis of Organic Reactions PDF Author: Frank E. Herkes
Publisher: CRC Press
ISBN: 9780824719296
Category : Science
Languages : en
Pages : 676

Book Description
Documents up-to-date developments in the study of catalysis and its applications to organic synthesis and industrial processes. The text examines the area of homogenous and heterogenous catalysis for industrial and pharmaceutical chemicals, focusing on recent advances in asymmetric synthesis, environmental uses, acid-based synthesis, hydrogenation, oxidation, alkylation, isomerization, amination, hydroformlyation, and more.

Dienamine Catalysis for Organic Synthesis

Dienamine Catalysis for Organic Synthesis PDF Author: Kengadarane Anebouselvy
Publisher: Royal Society of Chemistry
ISBN: 1788014324
Category : Science
Languages : en
Pages : 220

Book Description
In the past decade a new era in asymmetric catalysis has been realised by the discovery of L-proline induced chiral enamines from carbonyls. Inspired by this, researchers have developed many other primary catalytic species in situ, more recently secondary catalytic species such as aminals have been identified for use in asymmetric synthesis. High-yielding asymmetric synthesis of bioactive and natural products through mild catalysis is an efficient approach in reaction engineering. In the early days, synthetic chemists mainly focused on the synthesis of complex molecules, with less attention on the reaction efficiency and eco-friendly conditions. Recent investigations have been directed towards the development of atom economy, eco-friendly and enantioselective synthesis for more targeted and efficient synthesis. Building on the momentum of this rapidly expanding research area, Dienamine Catalysis for Organic Synthesis will provide a comprehensive introduction, from the preformed species, in situ generation and onto their applications in the synthesis of bioactive molecules and natural products.

Phase Transfer Catalysis in Organic Synthesis

Phase Transfer Catalysis in Organic Synthesis PDF Author: William P. Weber
Publisher: Springer Science & Business Media
ISBN: 3642463576
Category : Science
Languages : en
Pages : 295

Book Description
The field of phase transfer catalysis is a tribute to the chemists involved in process development research. Phase transfer catalysis is a solution to numerous cost and yield problems encountered regularly in industrial laboratories. In fact, much of the early work in this area was conducted by industrial chemists although the work was not labelled phase transfer catalysis at the time. We certainly do not intend to minimize the contributions of academic chemists to this field, but it is an unalterable fact that much of the early understanding and many of the early advances came from industrial laboratories. A special tribute is due to Dr. Charles Starks of the Continental Oil Company. By the mid sixties, Starks had formulated the principles of phase transfer catalysis and had applied for patents on many reactions that others were later to examine in somewhat greater detail. His mechanistic model of phase transfer catalysis still stands up well today and is a model for much of the thinking in this area. It is fitting that Starks suggested the name "phase transfer catalysis" by which the whole field is now known. We wish to thank a number of people who have aided us in many ways in the preparation of this volume. We very much appreciate the helpful discussions and insights provided by Drs. Henry Stevens and Andrew Kaman of PPG Industries in Barberton, Ohio. We also thank Dr. L. A.

Enzyme Catalysis in Organic Synthesis, 3 Volume Set

Enzyme Catalysis in Organic Synthesis, 3 Volume Set PDF Author: Karlheinz Drauz
Publisher: John Wiley & Sons
ISBN: 3527325476
Category : Science
Languages : en
Pages : 2143

Book Description
This comprehensive three-volume set is the standard reference in the field of organic synthesis, catalysis and biocatalysis. Edited by a highly experienced and highly knowledgeable team with a tremendous amount of experience in this field and its applications, this edition retains the successful concept of past editions, while the contents are very much focused on new developments in the field. All the techniques described are directly transferable from the lab to the industrial scale, making for a very application-oriented approach. A must for all chemists and biotechnologists.

Catalysis in Organic Chemistry

Catalysis in Organic Chemistry PDF Author: Paul Sabatier
Publisher:
ISBN:
Category : Catalysis
Languages : en
Pages : 440

Book Description


Science of Synthesis: Catalytic Oxidation in Organic Synthesis

Science of Synthesis: Catalytic Oxidation in Organic Synthesis PDF Author: Kilian Muñiz
Publisher: Thieme
ISBN: 3132012718
Category : Science
Languages : en
Pages : 1425

Book Description
The development of catalytic systems for the oxidation of organic compounds continues to be of great importance. There is an ongoing and increasing demand for methods that are selective, proceed under mild conditions, and adhere to green chemistry principles. "Science of Synthesis: Catalytic Oxidation in Organic Synthesis" includes the latest developments in the field, as well as selective coverage of more well-established methods. Systems based on metal catalysts, organocatalysts, and biomimetic oxidation are covered, and there is a particular focus on asymmetric processes. Scope, limitations, and mechanism of the reactions are discussed and key experimental procedures are included. Typical examples of target synthesis are often provided to show the utility and inspire further applications.

Science of Synthesis: Catalytic Reduction in Organic Synthesis

Science of Synthesis: Catalytic Reduction in Organic Synthesis PDF Author: Johannes G. de Vries
Publisher: Thieme
ISBN: 3132406244
Category : Science
Languages : en
Pages : 667

Book Description
Catalytic reductions are among the most used synthetic transformations, and the past 15 years have seen great progress in this field. Science of Synthesis: Catalytic Reduction in Organic Synthesis includes the latest developments, as well as selective coverage of more well-established methods. Both heterogeneous and homogeneous catalytic systems are covered, and enantioselective methodology is well represented. There is a focus on the use of metal nanoparticles, both in suspension as well as on solid supports. Furthermore, the advent of research on the conversion of renewable resources into fuels and chemicals has given a great impetus to the field, as deoxygenations are often the first step in the conversion of biomass and this can often be achieved using hydrogenation or hydrogenolysis reactions. Scope, limitations, and mechanism of the reactions are discussed and key experimental procedures are included.

Innovative Catalysis in Organic Synthesis

Innovative Catalysis in Organic Synthesis PDF Author: Pher G. Andersson
Publisher: John Wiley & Sons
ISBN: 3527646604
Category : Science
Languages : en
Pages : 375

Book Description
C-H, C-O, C-C, and C-Heteroatom bond forming processes by using metal-ligand approaches for the synthesis of organic compounds of biological, pharmacological and organic nanotechnological utility are the key areas addressed in this book. Authored by a European team of leaders in the field, it brings together innovative approaches for a variety of catalysis reactions and processes frequently applied in organic synthesis into a handy reference work. It covers all major types of catalysis, including homogeneous, heterogeneous, and organocatalysis, as well as mechanistic and computational studies. Special attention is paid to the improvements in efficiency and sustainability of important catalytic processes, such as selective oxidations, hydrogenation, and cross-coupling reactions, and to their utilization in industry. The result is a valuable resource for advanced researchers in both academia and industry, as well as graduate students in organic chemistry aiming for chemo-, regio- or stereoselective synthesis of organic compounds by using novel catalytic systems.

Catalysis of Organic Reactions

Catalysis of Organic Reactions PDF Author: Robert L. Augustine
Publisher: CRC Press
ISBN: 9780824772635
Category : Science
Languages : en
Pages : 436

Book Description
Uniting the work of over 20 leading international authorities, this outstanding source provides a complete updating of important developments in the study of catalysis as it applies to organic synthesis -- with applications in major industrial processes. In self-contained chapters that include an abstract, introduction, discussion, conclusion, and detailed references, this book covers a broad variety of catalytic processes -- both homogeneous and heterogeneous. Comprehensive and definitive, this work contains practical information on asymmetric catalytic hydrogenation ... organoactinide complexes on aumina ... amphora catalysts ... phenol hydrogenation process ... and much more. Packed with useful illustrations, schemes, tables, and equations, Catalysis of Organic Reactions will benefit the work of chemical engineers; organic chemists; industrial researchers in chemical process technologies; academic researchers in the catalytic sciences; organometallic and coordination chemists; and students in chemical engineering, organic chemistry, and inorganic chemistry. Book jacket.