Author: Curtis N. EngPublisher:
ISBN:
Category : Ammonia
Languages : en
Pages : 536
Book Description
Development of Catalysts for the Selective Reduction of Nitric Oxide by Ammonia
Author: Curtis N. EngPublisher:
ISBN:
Category : Ammonia
Languages : en
Pages : 536
Book Description
Kinetics of No-NH3 Reaction Over Platinum
Author: John D. WannerPublisher:
ISBN:
Category : Catalysts
Languages : en
Pages : 186
Book Description
Selective Catalytic Reduction of Nitric Oxide by Ammonia Over Iron Exchanged Y Zeolites
Author: Michael Dimitrios AmiridisPublisher:
ISBN:
Category :
Languages : en
Pages : 684
Book Description
Development and Characterization of Mixed Oxide Catalysts for the Selective Catlytic Reduction of Nitric Oxide from Stationary Sources Using Amonnia
Author: Publisher:
ISBN:
Category :
Languages : en
Pages :
Book Description
Seven first row transition metals were deposited on various commercial TiO2, SiO2, and Al2 O3 supports to create mono- and bimetallic catalysts that were compared in the selective catalytic reduction of nitric oxide using ammonia at low temperatures ranging from 373-523 K. The catalyst with the highest activity both in the absence and presence of water in the feed was 20 wt.% Mn/Hombikat TiO2 synthesized from a nitrate precursor and calcined below 673 K. Under those conditions, it was capable of achieving 100% NO conversion at 393 K. Numerous surface characterization techniques were used to identify the surface properties that result in highly active and selective low temperature SCR catalysts. The deposition of manganese as MnO2, the ease of reducibility of the metal oxide, and the symmetric deformation of ammonia coordinated to Lewis acid sites at 1167 cm−1, were all found to be important for good catalytic performance. No synergistic effects were observed from combinations of the three most active transition metals. However, MnO x -NiO/TiO2 had an extended lifetime relative to MnO x /TiO2 in feeds containing SO2 . The extensive data collected from in-situ FTIR experiments in the presence of NO and NH 3 were used to propose a reaction mechanism for MnO x /TiO2 that begins with the coordination of NH3 over Mn4 species and proceeds through the formation of bridged nitrates. A combination of potentiometric titrations and UV/Vis spectroscopy were used to quantify the reduction of V5 to V4 after the addition of oxalic acid as the solution is aged. After approximately four hours, the aging vanadium oxalate solution reaches steady state, and the final distribution of the vanadium present is 89% V+4 and 11% V+5 . TiO2 supported monolayer catalysts synthesized from the aged (V+4) vanadium oxalate solution consistently outperformed catalysts made from freshly prepared (V+5) vanadium oxalate solutions. Surface characterization revealed that surface acid sites increase in strength and vanadia reduces more easily in catalysts synthesized from aged vanadium oxalate solutions, which enhances reaction mechanism depends upon acid sites and redox operation.
The Selective Catalytic Reduction of Nitric Oxide with Ammonia
Author: Hans BoschPublisher:
ISBN: 9789090019048
Category :
Languages : en
Pages : 207
Book Description
Selective Reduction of Nitric Oxide by Ammonia on Vanadium Pentoxide Catalyst
Author: Mohsen NazemiPublisher:
ISBN:
Category : Nitric oxide
Languages : en
Pages : 56
Book Description
Experimental Investigation of a Dual-catalyst for the Selective Catalytic Reduction of Nitric Oxide with Ammonia
Author: Frank G. MedrosPublisher:
ISBN:
Category : Ammonia
Languages : en
Pages : 736
Book Description
The Selective Catalytic Reduction of Nitric Oxide with Ammonia
Author: Franciscus Johannes Josephus Gerardus JanssenPublisher:
ISBN: 9789090018508
Category :
Languages : en
Pages : 120
Book Description
Selective Reduction of Nitric Oxide with Ammonia Over Vanadia on Pillared Titanium Phosphate
Author: Lawrence Joseph CzarneckiPublisher:
ISBN:
Category : Catalysts
Languages : en
Pages : 182
Book Description
Role of Ammonia Oxidation in Selective Catalytic Reduction of Nitric Oxide Over Vanadia Based Catalysts
Author: Mahesh Waman KumthekarPublisher:
ISBN:
Category :
Languages : en
Pages : 362
Book Description