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Author: Publisher: ISBN: Category : Languages : en Pages :
Book Description
A high pressure, supersonic, radio frequency discharge nozzle beam source was developed for the production of intense beams of ground state oxygen atoms. An efficient impedance matching scheme was devised for coupling the radio frequency power to the plasma as a function of both gas pressure and composition. Techniques for localizing the discharge directly behind the orifice of a water-cooled quartz nozzle were also developed. The above combine to yield an atomic oxygen beam source which produces high molecular dissociation in oxygen seeded rare gas mixtures at total pressures up to 200 torr: 80 to 90% dissociation for oxygen/argon mixtures and 60 to 70% for oxygen/helium mixtures. Atomic oxygen intensities are found to be greater than 1017 atom sr−1 sec−1. A brief discussion of the reaction dynamics of 0 + IC1 .-->. I0 + C1 is also presented. 12 references.
Author: Publisher: ISBN: Category : Languages : en Pages :
Book Description
A high pressure, supersonic, radio frequency discharge nozzle beam source was developed for the production of intense beams of ground state oxygen atoms. An efficient impedance matching scheme was devised for coupling the radio frequency power to the plasma as a function of both gas pressure and composition. Techniques for localizing the discharge directly behind the orifice of a water-cooled quartz nozzle were also developed. The above combine to yield an atomic oxygen beam source which produces high molecular dissociation in oxygen seeded rare gas mixtures at total pressures up to 200 torr: 80 to 90% dissociation for oxygen/argon mixtures and 60 to 70% for oxygen/helium mixtures. Atomic oxygen intensities are found to be greater than 1017 atom sr−1 sec−1. A brief discussion of the reaction dynamics of 0 + IC1 .-->. I0 + C1 is also presented. 12 references.
Author: Publisher: ISBN: Category : Languages : en Pages :
Book Description
A high pressure, radio frequency discharge nozzle beam source was developed for the production of very intense (greater than or equal to 1018 atoms sr−1 sec−1) supersonic beams of oxygen atoms. This source is capable of producing seeded beams of ground state O(3P/sub J/) atoms when dilute oxygen-argon mixtures are used, with molecular dissociation levels exceeding 80% being realized for operation at pressures up to 350 torr. When dilute oxygen-helium mixtures are employed both ground state O(3P/sub J/) and excited state O(1D2) atoms are present in the terminal beam, with molecular dissociation levels typically exceeding 60% being achieved for operation at pressures up to 200 torr. Atomic oxygen mean translational energies from 0.14 to 0.50 eV were obtained using the seeded beams technique, with Mach numbers as high as 10 (FWHM .delta. v/v approx. = 20%) being realized. The IC1, CF3I, C6H6, and C6D6 reactions are discussed in detail. The IC1 and CF3I studies have enabled us to determine an improved value for the bond energy of the IO radical: D/sub o/(IO) = 55 +- 2 kcal/mole. The IO product angular and velocity distributions have been used to generate center-of-mass flux contour maps, which indicate that these two reactions proceed via relatively long-lived collision complexes whose mean lifetimes are slightly shorter than their respective rotational periods. The O(3P/sub J/) + C6H6 and C6D6 reactions were studied in order to elucidate the reaction mechanism, and, in particular, to identify the primary reaction products produced in these reactions. Finally, a series of beam-surface scattering experiments are described which examined the internal and translational energy dependence of molecular condensation probabilities for collisions involving either CC14 or SF6 and their respective condensed phases. 117 references. (JFP).
Author: Calvin K. Lam Publisher: ISBN: Category : Molecular beams Languages : en Pages : 47
Book Description
Initial studies of the feasibility of producing a hypersonic molecular beam containing appreciable amount of atomic oxygen have been successfully completed. The purpose of the work was to produce a molecular beam which could be used for basic and applied studies related to the interaction of the earth's upper atmosphere, such as accommodation coefficient measurements or surface reactions at high kinetic energy. A quartz tube source was developed for the molecular beam in which a 200 watt microwave discharge could be maintained. The studies included the effect of pressure and orifice size, for which a compromise was involved in order to achieve high Mach numbers and high dissociation levels, the use of double cavities, and the effect of small additions of H2O. It was demonstrated in these initial tests that a hypersonic beam from a 92% He 8% O2 mixture could be produced with 17% dissociation. (Author).
Author: Alfred E. Beylich Publisher: ISBN: 9783527282500 Category : Science Languages : en Pages : 1638
Book Description
This book describes the most recent international research in the field of rarefied gas dynamics (RGD). Unique in the depth and scope of its presentation, it considers progress made in the treatment of non-equilibrium phenomena in such fields as aerospace, vacuum technology, isotope separation and gas dynamic lasers. Due to the broad range of RGD applications, the volume will appeal to readers from numerous fields (e.g. physics, engineering, mathematics, chemistry).
Author: John H. Moore Publisher: CRC Press ISBN: 1003803296 Category : Science Languages : en Pages : 1161
Book Description
The Encyclopedia of Physical Chemistry and Chemical Physics introduces possibly unfamiliar areas, explains important experimental and computational techniques, and describes modern endeavors. The encyclopedia quickly provides the basics, defines the scope of each subdiscipline, and indicates where to go for a more complete and detailed explanation. Particular attention has been paid to symbols and abbreviations to make this a user-friendly encyclopedia. Care has been taken to ensure that the reading level is suitable for the trained chemist or physicist. The encyclopedia is divided in three major sections: FUNDAMENTALS: the mechanics of atoms and molecules and their interactions, the macroscopic and statistical description of systems at equilibrium, and the basic ways of treating reacting systems. The contributions in this section assume a somewhat less sophisticated audience than the two subsequent sections. At least a portion of each article inevitably covers material that might also be found in a modern, undergraduate physical chemistry text. METHODS: the instrumentation and fundamental theory employed in the major spectroscopic techniques, the experimental means for characterizing materials, the instrumentation and basic theory employed in the study of chemical kinetics, and the computational techniques used to predict the static and dynamic properties of materials. APPLICATIONS: specific topics of current interest and intensive research. For the practicing physicist or chemist, this encyclopedia is the place to start when confronted with a new problem or when the techniques of an unfamiliar area might be exploited. For a graduate student in chemistry or physics, the encyclopedia gives a synopsis of the basics and an overview of the range of activities in which physical principles are applied to chemical problems. It will lead any of these groups to the salient points of a new field as rapidly as possible and gives pointers as to where to read about the topic in more detail.
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Author: Steven Jay Sibener
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Author: Calvin K. Lam
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Author: Alfred E. Beylich
Author: R. Campargue
Author: John H. Moore
Author: John H. Moore