Development and Application of Chemical Mechanisms for the Oxidation of Organic Compounds in the Atmosphere PDF Download

Author: Shabana Naz Anwar
Publisher:
ISBN:
Category :
Languages : en
Pages : 198

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Author: Jack Calvert
Publisher: Oxford University Press
ISBN: 0199877475
Category : Science
Languages : en
Pages : 1634

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Book Description
Prepared by an international team of eminent atmospheric scientists, Mechanisms of Atmospheric Oxidation of the Oxygenates is an authoritative source of information on the role of oxygenates in the chemistry of the atmosphere. The oxygenates, including the many different alcohols, ethers, aldehydes, ketones, acids, esters, and nitrogen-atom containing oxygenates, are of special interest today due to their increased use as alternative fuels and fuel additives. This book describes the physical properties of oxygenates, as well as the chemical and photochemical parameters that determine their reaction pathways in the atmosphere. Quantitative descriptions of the pathways of the oxygenates from release or formation in the atmosphere to final products are provided, as is a comprehensive review and evaluation of the extensive kinetic literature on the atmospheric chemistry of the different oxygenates and their many halogen-atom substituted analogues. This book will be of interest to modelers of atmospheric chemistry, environmental scientists and engineers, and air quality planning agencies as a useful input for development of realistic modules designed to simulate the atmospheric chemistry of the oxygenates, their major oxidation products, and their influence on ozone and other trace gases within the troposhere.

Author: Jack G. Calvert
Publisher: Oxford University Press
ISBN: 9780199771547
Category : Science
Languages : en
Pages : 570

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Book Description
This text reviews many of the aspects of the chemistry of the aromatic hydrocarbons and a consensus evaluation of the data by seven of the leading atmospheric scientists. The book covers topics ranging from the relative importance of the compounds in ozone and haze development to methods of estimating elemantary rate coefficients based on structural features of the compounds to mechanisms of aerosol generation and atmostpheric reaction of the polycyclic compounds to photochemical processes. It identifies features of the aromatic hydrocarbons requiring further study and appendicies give the structural formulas and nomenclature of the compounds reviewed in the book.

Author: Georges Le Bras
Publisher: Springer
ISBN: 9783642592171
Category : Science
Languages : en
Pages : 314

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Book Description
Oxidation and removal of atmospheric constituents involve complex sequences of reactions which can lead to the production of photo-oxidants such as ozone. In order to understand and model these complex reaction sequences, it is necessary to have a comprehensive understanding of reaction mechanisms and accurate estimates of kinetic parameters for relevant gas-phase atmospheric reactions. This book presents recent advances in the field and includes the following topics: e.g. the oxidation of simple organic compounds, NOx kinetics and mechanisms, OH radical production and rate constants for the OH attack on more complex organic compounds, peroxy and alkoxy radical reactions, photo-oxidation of aromatic and biogenic compounds, and the interaction between radical species.

Author: Georges Le Bras
Publisher: Springer Science & Business Media
ISBN:
Category : Science
Languages : en
Pages : 348

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Book Description
Oxidation and removal of atmospheric constituents involve complex sequences of reactions which can lead to the production of photo-oxidants such as ozone. In order to understand and model these complex reaction sequences, it is necessary to have a comprehensive understanding of reaction mechanisms and accurate estimates of kinetic parameters for relevant gas-phase atmospheric reactions. This book presents recent advances in the field and includes the following topics: e.g. the oxidation of simple organic compounds, NOx kinetics and mechanisms, OH radical production and rate constants for the OH attack on more complex organic compounds, peroxy and alkoxy radical reactions, photo-oxidation of aromatic and biogenic compounds, and the interaction between radical species.

Author: James G. Speight
Publisher: Butterworth-Heinemann
ISBN: 0128006676
Category : Technology & Engineering
Languages : en
Pages : 458

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Book Description
Reaction Mechanisms in Environmental Engineering: Analysis and Prediction describes the principles that govern chemical reactivity and demonstrates how these principles are used to yield more accurate predictions. The book will help users increase accuracy in analyzing and predicting the speed of pollutant conversion in engineered systems, such as water and wastewater treatment plants, or in natural systems, such as lakes and aquifers receiving industrial pollution. Using examples from air, water and soil, the book begins with a clear exposition of the properties of environmental and inorganic organic chemicals that is followed by partitioning and sorption processes and sorption and transformation processes. Kinetic principles are used to calculate or estimate the pollutants' half-lives, while physical-chemical properties of organic pollutants are used to estimate transformation mechanisms and rates. The book emphasizes how to develop an understanding of how physico-chemical and structural properties relate to transformations of organic pollutants. Offers a one-stop source for analyzing and predicting the speed of organic and inorganic reaction mechanisms for air, water and soil Provides the tools and methods for increased accuracy in analyzing and predicting the speed of pollutant conversion in engineered systems Uses kinetic principles and the physical-chemical properties of organic pollutants to estimate transformation mechanisms and rates

Author: Ralf Koppmann
Publisher: John Wiley & Sons
ISBN: 0470994150
Category : Science
Languages : en
Pages : 512

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Book Description
Every day, large quantities of volatile organic compounds (VOCs) are emitted into the atmosphere from both anthropogenic and natural sources. The formation of gaseous and particulate secondary products caused by oxidation of VOCs is one of the largest unknowns in the quantitative prediction of the earth’s climate on a regional and global scale, and on the understanding of local air quality. To be able to model and control their impact, it is essential to understand the sources of VOCs, their distribution in the atmosphere and the chemical transformations which remove these compounds from the atmosphere. In recent years techniques for the analysis of organic compounds in the atmosphere have been developed to increase the spectrum of detectable compounds and their detection limits. New methods have been introduced to increase the time resolution of those measurements and to resolve more complex mixtures of organic compounds. Volatile Organic Compounds in the Atmosphere describes the current state of knowledge of the chemistry of VOCs as well as the methods and techniques to analyse gaseous and particulate organic compounds in the atmosphere. The aim is to provide an authoritative review to address the needs of both graduate students and active researchers in the field of atmospheric chemistry research.

Author: Gordon Milne Barrow
Publisher:
ISBN:
Category :
Languages : en
Pages :

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Author: Barbara J. Finlayson-Pitts
Publisher: Elsevier
ISBN: 0080529070
Category : Science
Languages : en
Pages : 993

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Book Description
Here is the most comprehensive and up-to-date treatment of one of the hottest areas of chemical research. The treatment of fundamental kinetics and photochemistry will be highly useful to chemistry students and their instructors at the graduate level, as well as postdoctoral fellows entering this new, exciting, and well-funded field with a Ph.D. in a related discipline (e.g., analytical, organic, or physical chemistry, chemical physics, etc.). Chemistry of the Upper and Lower Atmosphere provides postgraduate researchers and teachers with a uniquely detailed, comprehensive, and authoritative resource. The text bridges the "gap" between the fundamental chemistry of the earth's atmosphere and "real world" examples of its application to the development of sound scientific risk assessments and associated risk management control strategies for both tropospheric and stratospheric pollutants. Serves as a graduate textbook and "must have" reference for all atmospheric scientists Provides more than 5000 references to the literature through the end of 1998 Presents tables of new actinic flux data for the troposphere and stratospher (0-40km) Summarizes kinetic and photochemical date for the troposphere and stratosphere Features problems at the end of most chapters to enhance the book's use in teaching Includes applications of the OZIPR box model with comprehensive chemistry for student use

Author: Jack George Calvert
Publisher: Oxford University Press on Demand
ISBN: 9780195146288
Category : Science
Languages : en
Pages : 556

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Book Description
This text reviews many of the aspects of the chemistry of the aromatic hydrocarbons and a consensus evaluation of the data by seven of the leading atmospheric scientists. The book covers topics ranging from the relative importance of the compounds in ozone and haze development to methods of estimating elemantary rate coefficients based on structural features of the compounds to mechanisms of aerosol generation and atmostpheric reaction of the polycyclic compounds to photochemical processes. It identifies features of the aromatic hydrocarbons requiring further study and appendicies give the structural formulas and nomenclature of the compounds reviewed in the book.