Destruction of Chlorinated Hydrocarbons by Zero-valent and Bimetallic Zinc Reductants in Bench-scale Investigations PDF Download

Author: Christopher Scott Cushman
Publisher:
ISBN:
Category : Chlorohydrocarbons
Languages : en
Pages : 128

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Author: Eric D. van Hullebusch
Publisher: Springer Nature
ISBN: 3030403483
Category : Science
Languages : en
Pages : 438

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Book Description
This book provides a comprehensive overview of innovative remediation techniques and strategies for soils contaminated by heavy metals or organic compounds (e.g. petroleum hydrocarbons, NAPLs and chlorinated organic compounds). It discusses various novel chemical remediation approaches (in-situ and ex-situ) used alone and in combination with physical and/or thermal treatment. Further, it addresses the recovery of NAPLs, reuse of leaching solutions, and in-situ chemical reduction and oxidation, and explores the chemical enhancement of physical NAPLs recovery from both practical and theoretical perspectives. Also presenting the state-of-the-art in waste-assisted bioremediation to improve soil quality and the remediation of petroleum hydrocarbons, the book is a valuable resource for students, researchers and R&D professionals in industry engaged in the treatment of contaminated soils.

Author: Fang Yu
Publisher:
ISBN:
Category : Chlorohydrocarbons
Languages : en
Pages : 71

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Chlorinated hydrocarbons (CHCs) in groundwater can be treated by monometallic and bimetallic metal reductants through abiotic degradation. The breakdown of CHC is achieved by gaining electrons from those reductants and removing chlorines from CHC molecules to transform the CHCs into less chlorinated compounds. As a proven technology in groundwater treatment, permeable reactive barriers (PRBs) have been used to passively treat contaminated groundwater, in which granular metals can be used as reactive materials. This study explored the abiotic degradation of CHCs by zero-valent magnesium (ZVM) and bimetallic palladium/magnesium (Pd/Mg) reductants. Different CHCs (carbon tetrachloride, chloroform, dichloromethane (DCM), 1,2-dichloroethane (1,2-DCA), 1,1,2-trichloroethane (1,1,2-TCA), 1,1,2,2-tetrachloroethane (1,1,2,2-TeCA), 1,2-dichloropropane (1,2-DCP), and 1,2,3-Trichloropropane (1,2,3-TCP) were chosen as target contaminants. Results showed that even with its high reduction potential, ZVM did not treat CHCs effectively due to corrosion of Mg by water, which formed Mg (OH)2(s) precipitate on the metal surface and prevented further reaction. Such inhibition can be reduced by lowering pH conditions. However, in the presence of Pd, CHCs were removed at a much faster rate at neutral pH conditions. Hydrocarbons were produced as sole products, which indicated complete degradation of CHCs by Pd/Mg. Recalcitrant CHCs such as DCM, 1, 1,2-TCA, 1,2-DCP and 1,2,3-TCP were found to be effectively degraded by Pd/Mg. No significant effect of Pd loading on CHC degradation was observed, while the degradation was accelerated by increasing the Mg loading.

Author: Md Abu Raihan Chowdhury
Publisher:
ISBN:
Category : Chlorohydrocarbons
Languages : en
Pages : 64

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Book Description
Nanoscale Zero Valent Iron (NZVI) has shown limited effectiveness in degrading chlorinated hydrocarbons (CHCs), like 1,1,1-Trichloroethane (1,1,1-TCA) and Trichloroethene (TCE), in aqueous solution. A rapid agglomeration behavior of NZVI particles due to van der waals and magnetic forces can negatively impact its overall effectiveness due to increase in particle size, and decline in CHC degradation kinetics. Different support materials, such as clays and activated carbon, have been used to stabilize NZVI particle and reduce agglomeration in aqueous solution. In this bench-scale study, NZVI supported on Powdered Activated Charcoal (PAC) was selected to prepare a composite, called PAC/NZVI, for a more effective treatment of 1,1,1-TCA and TCE in aqueous solution. The study shows that PAC/NZVI has both adsorption and degradation capability toward 1,1,1-TCA and TCE. PAC exhibited high porosity to accommodate NZVI as a suitable support in order to keep NZVI in suspension in aqueous medium and to minimize agglomeration. Bench-scale experiments with variable concentrations of PAC (0.1{u2013}0.8 g/L) and NZVI (0.2{u2013}0.6 g/L) showed that PAC/NZVI composite can be highly efficient in rapid 1,1,1-TCA removal by adsorption, and effective in overall degradation leading to production of non-chlorinated daughter products. Increase in PAC concentration in the composite was correlated with greater removal of 1,1,1-TCA by sorption whereas lower PAC concentration yielded greater degradation kinetics and higher byproduct yields. PAC/NZVI was found to be active for more than three months presumably because NZVI embedded within hydrophobic pore spaces of PAC did not get oxidized. Cu amendment to NZVI as a secondary/catalysts metal showed faster degradation and higher byproduct yields.

Author: Arun R. Gavaskar
Publisher:
ISBN:
Category : Science
Languages : en
Pages : 198

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Book Description
Because of the limitations of conventional pump-and-treat systems in treating groundwater contaminants, permeable barriers are potentially more cost-effective than pump-and-treat systems for treating dissolved chlorinated solvent plumes, which may persist in the saturated zone for several decades. Other contaminants, such as chromium or other soluble heavy metals, can also be treated with this technology. Permeable Barriers for Groundwater Remediation discusses the types of permeable barriers, their design and construction, and how they can be monitored to evaluate compliance. It provides practical guidance on reactive media selection, treatability testing, hydrogeologic and geochemical modeling, and innovative installation techniques for the evaluation and application of this promising new technology. The types of permeable barriers discussed include: trench-type and caisson-based reactive cells; innovative emplacements, such as horizontal trenching and jetting; and continuous reactive barriers versus funnel-and-gate systems.

Author: Minghua Zhou
Publisher: Springer
ISBN: 9811064067
Category : Science
Languages : en
Pages : 437

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Book Description
This volume discusses the theoretical fundamentals and potential applications of the original electro-Fenton (EF) process and its most innovative and promising versions, all of which are classified as electrochemical advanced oxidation processes. It consists of 15 chapters that review the latest advances and trends, material selection, reaction and reactor modeling and EF scale-up. It particularly focuses on the applications of EF process in the treatment of toxic and persistent organic pollutants in water and soil, showing highly efficient removal for both lab-scale and pre-pilot setups. Indeed, the EF technology is now mature enough to be brought to market, and this collection of contributions from leading experts in the field constitutes a timely milestone for scientists and engineers.

Author: Olcay Tunay
Publisher: IWA Publishing
ISBN: 1843393077
Category : Science
Languages : en
Pages : 361

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Book Description
This book covers the most recent scientific and technological developments (state-of-the-art) in the field of chemical oxidation processes applicable for the efficient treatment of biologically-difficult-to-degrade, toxic and/or recalcitrant effluents originating from different manufacturing processes. It is a comprehensive review of process and pollution profiles as well as conventional, advanced and emerging treatment processes & technologies developed for the most relevant and pollution (wet processing)-intensive industrial sectors. It addresses chemical/photochemical oxidative treatment processes, case-specific treatability problems of major industrial sectors, emerging (novel) as well as pilot/full-scale applications, process integration, treatment system design & sizing criteria (figure-of-merits), cost evaluation and success stories in the application of chemical oxidative treatment processes. Chemical Oxidation Applications for Industrial Wastewaters is an essential reference for lecturers, researchers, industrial and environmental engineers and practitioners working in the field of environmental science and engineering. Visit the IWA WaterWiki to read and share material related to this title: http://www.iwawaterwiki.org/xwiki/bin/view/Articles/CHEMICALOXIDATIONAPPLICATIONSFORINDUSTRIALWASTEWATERS Authors: Professor Olcay Tünay, Professor Isik Kabdasli, Associate Professor Idil Arslan-Alaton and Assistant Professor Tugba Ölmez-Hanci, Environmental Engineering Department, Istanbul Technical University, Turkey.

Author: David M. Kempisty
Publisher: CRC Press
ISBN: 0429945027
Category : Science
Languages : en
Pages : 495

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Book Description
Per- and polyfluorinated alkyl substances (PFAS), often referred to as per- (and poly) fluorinated compounds (PFCs), have been used for years in many everyday3⁄4 and some lifesaving3⁄4 products. However, their use has been linked to adverse health effects in humans, a problem compounded by their persistence in the environment. This book discusses the various challenges of PFAS in our environment today, including their historical use as well as their chemical and toxicological properties. It also presents robust discussion of analytical challenges and special considerations in sampling. The work goes on to give practical recommendations for dealing with these compounds in today's dynamic regulatory landscape and includes several chapters on various remediation techniques. Key Features: Comprehensive overview of per- and polyfluorinated alkyl substances (PFAS) historical use and chemical/physical properties which help us understand their persistence, transport, and transformation pathways in the environment In-depth analysis of PFAS toxicology Detailed descriptions of conventional and state-of-the-art remediation technologies Practical recommendations for dealing with PFAS in a dynamic regulatory landscape Robust discussion of important sampling and analytical considerations Perfluoroalkyl Substances in the Environment: Theory, Practice, and Innovation explores the challenges across the topical areas of regulation and management, toxicology, environmental remediation, and analytical sampling and analysis.Readers will find this text helpful in understanding complexities associated with PFAS and informing management strategies to effectively protect this and future generations.

Author: Wei Zhang
Publisher: John Wiley & Sons
ISBN: 1119288584
Category : Science
Languages : en
Pages : 1127

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Book Description
An updated overview of the rapidly developing field of green techniques for organic synthesis and medicinal chemistry Green chemistry remains a high priority in modern organic synthesis and pharmaceutical R&D, with important environmental and economic implications. This book presents comprehensive coverage of green chemistry techniques for organic and medicinal chemistry applications, summarizing the available new technologies, analyzing each technique’s features and green chemistry characteristics, and providing examples to demonstrate applications for green organic synthesis and medicinal chemistry. The extensively revised edition of Green Techniques for Organic Synthesis and Medicinal Chemistry includes 7 entirely new chapters on topics including green chemistry and innovation, green chemistry metrics, green chemistry and biological drugs, and the business case for green chemistry in the generic pharmaceutical industry. It is divided into 4 parts. The first part introduces readers to the concepts of green chemistry and green engineering, global environmental regulations, green analytical chemistry, green solvents, and green chemistry metrics. The other three sections cover green catalysis, green synthetic techniques, and green techniques and strategies in the pharmaceutical industry. Includes more than 30% new and updated material—plus seven brand new chapters Edited by highly regarded experts in the field (Berkeley Cue is one of the fathers of Green Chemistry in Pharma) with backgrounds in academia and industry Brings together a team of international authors from academia, industry, government agencies, and consultancies (including John Warner, one of the founders of the field of Green Chemistry) Green Techniques for Organic Synthesis and Medicinal Chemistry, Second Edition is an essential resource on green chemistry technologies for academic researchers, R&D professionals, and students working in organic chemistry and medicinal chemistry.

Author: Grazyna Stochel
Publisher: John Wiley & Sons
ISBN: 9781405193276
Category : Science
Languages : en
Pages : 398

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Book Description
Bioinorganic photochemistry is a rapidly evolving field integrating inorganic photochemistry with biological, medical and environmental sciences. The interactions of light with inorganic species in natural systems, and the applications in artificial systems of medical or environmental importance, form the basis of this challenging inter-disciplinary research area. Bioinorganic Photochemistry provides a comprehensive overview of the concepts and reactions fundamental to the field, illustrating important applications in biological, medical and environmental sciences. Topics covered include: Cosmic and environmental photochemistry Photochemistry of biologically relevant nanoassemblies Molecular aspects of photosynthesis Photoinduced electron transfer in biosystems Modern therapeutic strategies in photomedicine The book concludes with an outlook for the future of environmental protection, discussing emerging techniques in the field of pollution abatement, and the potential for bioinorganic photochemistry as a pathway to developing cheap, environmentally friendly sources of energy. Written as an authoritative guide for researchers involved in the development of bioinorganic photochemical processes, Bioinorganic Photochemistry is also accessible to scientists new to the field, and will be a key reference source for advanced courses in inorganic, and bioinorganic chemistry.