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Author: Publisher: ISBN: Category : Languages : en Pages : 11
Book Description
A process of preparing anhydrous actinide metal trichlorides of plutonium or neptunium by reacting an aqueous solution of an actinide metal trichloride selected from the group consisting of plutonium trichloride or neptunium trichloride with a reducing agent capable of converting the actinide metal from an oxidation state of +4 to +3 in a resultant solution, evaporating essentially all the solvent from the resultant solution to yield an actinide trichloride hydrate material, dehydrating the actinide trichloride hydrate material by heating the material in admixture with excess thionyl chloride, and recovering anhydrous actinide trichloride is provided.
Author: Publisher: ISBN: Category : Languages : en Pages : 11
Book Description
A process of preparing anhydrous actinide metal trichlorides of plutonium or neptunium by reacting an aqueous solution of an actinide metal trichloride selected from the group consisting of plutonium trichloride or neptunium trichloride with a reducing agent capable of converting the actinide metal from an oxidation state of +4 to +3 in a resultant solution, evaporating essentially all the solvent from the resultant solution to yield an actinide trichloride hydrate material, dehydrating the actinide trichloride hydrate material by heating the material in admixture with excess thionyl chloride, and recovering anhydrous actinide trichloride is provided.
Author: Publisher: ISBN: Category : Languages : en Pages :
Book Description
A process of preparing anhydrous actinide metal trichlorides of plutonium or neptunium by reacting an aqueous solution of an actinide metal trichloride selected from the group consisting of plutonium trichloride or neptunium trichloride with a reducing agent capable of converting the actinide metal from an oxidation state of +4 to +3 in a resultant solution, evaporating essentially all the solvent from the resultant solution to yield an actinide trichloride hydrate material, dehydrating the actinide trichloride hydrate material by heating the material in admixture with excess thionyl chloride, and recovering anhydrous actinide trichloride is provided.
Author: Robert J. Lemire Publisher: Elsevier ISBN: 9780444503794 Category : Medical Languages : en Pages : 876
Book Description
Unlike earlier books in this series, this review describes the selection of chemical thermodynamic data for species of two elements, neptunium and plutonium. Although this came about more by circumstance than design, it has allowed for a more consistent approach to chemical interpretation than might have occurred in two separate treatments. It has also drawn attention to cases where the available data do not show expected parallels, and where further work may be useful to confirm or refute apparent differences in the behaviour of neptunium and plutonium.
Author: V. S. Yemel'Yanov Publisher: Elsevier ISBN: 1483186024 Category : Technology & Engineering Languages : en Pages : 600
Book Description
The Metallurgy of Nuclear Fuel: Properties and Principles of the Technology of Uranium, Thorium and Plutonium is a systematic analysis of the metallurgy of nuclear fuel, with emphasis on the physical, mechanical, and chemical properties as well as the technology of uranium, thorium, and plutonium, together with their alloys and compounds. The minerals and raw material sources of nuclear fuel are discussed, along with the principles of the technology of the raw material processing and the production of the principal compounds, and of the pure metals and alloys. Comprised of three parts, this volume begins with an introduction to the history of the discovery of uranium and its position in the periodic system; its use as a nuclear fuel; radioactivity and isotopic composition; alloys and compounds; and physical, mechanical, and chemical properties. The effect of mechanical and thermal treatment, thermal cycling and irradiation on the physicochemical properties of uranium is also examined. The next two sections are devoted to thorium and plutonium and includes chapters dealing with their uses, alloys and compounds, and methods of recovery and purification. This book is written for university students, but should also prove useful to young production engineers and scientific workers who are concerned with problems in the metallurgy of nuclear fuel.
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Author: Robert J. Lemire
Author: V. S. Yemel'Yanov