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Author: Helmut Münstedt Publisher: Springer ISBN: 3642554091 Category : Technology & Engineering Languages : en Pages : 564
Book Description
This book describes the properties of single polymer molecules and polymeric materials and the methods how to characterize them. Molar masses, molar mass distributions and branching structure are discussed in detail. These properties are decisive for a deeper understanding of structure/properties relationships of polymeric materials. This book therefore describes and discusses them in detail. The mechanical behavior as a function of time and temperature is a key subject of the book. The authors present it on the basis of many original results they have obtained in their long research careers. They present the temperature dependence of mechanical properties of various polymeric materials in a wide temperature range: from cryogenic temperatures to the melt. Besides an extensive data collection on the transitions of various different polymeric materials, they also carefully present the physical explanations of the observed phenomena. Glass transition and melting temperatures are discussed, particularly, with their relevance for applications. A comprehensive part of the book deals with properties of polymers in the molten state and their decisive influence on the processing of the materials. The book presents and discusses viscous and elastic properties in detail as a function of molar mass, polydispersity, and branching. This book addresses students of polymer and materials science, as well as other natural sciences. Besides this educational value, it will also serve as a valuable monograph for everyone dealing with polymers and polymeric materials, from research, over development, to applications.
Author: A. S. Argon Publisher: Cambridge University Press ISBN: 0521821843 Category : Science Languages : en Pages : 535
Book Description
A physical, mechanism-based presentation of the plasticity and fracture of polymers, covering industrial scale applications through to nanoscale biofluidic devices.
Author: Helmut Münstedt Publisher: Springer ISBN: 3642554091 Category : Technology & Engineering Languages : en Pages : 564
Book Description
This book describes the properties of single polymer molecules and polymeric materials and the methods how to characterize them. Molar masses, molar mass distributions and branching structure are discussed in detail. These properties are decisive for a deeper understanding of structure/properties relationships of polymeric materials. This book therefore describes and discusses them in detail. The mechanical behavior as a function of time and temperature is a key subject of the book. The authors present it on the basis of many original results they have obtained in their long research careers. They present the temperature dependence of mechanical properties of various polymeric materials in a wide temperature range: from cryogenic temperatures to the melt. Besides an extensive data collection on the transitions of various different polymeric materials, they also carefully present the physical explanations of the observed phenomena. Glass transition and melting temperatures are discussed, particularly, with their relevance for applications. A comprehensive part of the book deals with properties of polymers in the molten state and their decisive influence on the processing of the materials. The book presents and discusses viscous and elastic properties in detail as a function of molar mass, polydispersity, and branching. This book addresses students of polymer and materials science, as well as other natural sciences. Besides this educational value, it will also serve as a valuable monograph for everyone dealing with polymers and polymeric materials, from research, over development, to applications.
Author: Helmut Münstedt Publisher: Carl Hanser Verlag GmbH Co KG ISBN: 1569907552 Category : Technology & Engineering Languages : en Pages : 299
Book Description
Understanding the elastic properties of polymer melts is necessary for ensuring successful polymer processing and thus producing high-quality plastic parts. This unique book is the first to focus on this important topic. Starting with the molecular origin of elastic behavior and an explanation of the physical quantities involved, experimental methods and the dependence of elastic behavior on experimental parameters are then presented. Elastic properties of filled and unfilled systems are compared directly, and polymer blends are also considered. Elastic effects in various applications are included, such as in extrudate swell, internal stresses, and shrink films, to illustrate the importance of this field in the plastics processing industry.
Author: Connie B. Roth Publisher: CRC Press ISBN: 1315305135 Category : Science Languages : en Pages : 587
Book Description
"the present book will be of great value for both newcomers to the field and mature active researchers by serving as a coherent and timely introduction to some of the modern approaches, ideas, results, emerging understanding, and many open questions in this fascinating field of polymer glasses, supercooled liquids, and thin films" –Kenneth S. Schweizer, Morris Professor of Materials Science & Engineering, University of Illinois at Urbana-Champaign (from the Foreword) This book provides a timely and comprehensive overview of molecular level insights into polymer glasses in confined geometries and under deformation. Polymer glasses have become ubiquitous to our daily life, from the polycarbonate eyeglass lenses on the end of our nose to large acrylic glass panes holding water in aquarium tanks, with advantages over glass in that they are lightweight and easy to manufacture, while remaining transparent and rigid. The contents include an introduction to the field, as well as state of the art investigations. Chapters delve into studies of commonalities across different types of glass formers (polymers, small molecules, colloids, and granular materials), which have enabled microscopic and molecular level frameworks to be developed. The authors show how glass formers are modeled across different systems, thereby leading to treatments for polymer glasses with first-principle based approaches and molecular level detail. Readers across disciplines will benefit from this topical overview summarizing the key areas of polymer glasses, alongside an introduction to the main principles and approaches.
Author: G.M. Swallowe Publisher: Springer Science & Business Media ISBN: 9401592314 Category : Science Languages : en Pages : 313
Book Description
This volume represents a continuation of the Polymer Science and Technology series edited by Dr. D. M. Brewis and Professor D. Briggs. The theme of the series is the production of a number of stand alone volumes on various areas of polymer science and technology. Each volume contains short articles by a variety of expert contributors outlining a particular topic and these articles are extensively cross referenced. References to related topics included in the volume are indicated by bold text in the articles, the bold text being the title of the relevant article. At the end of each article there is a list of bibliographic references where interested readers can obtain further detailed information on the subject of the article. This volume was produced at the invitation of Derek Brewis who asked me to edit a text which concentrated on the mechanical properties of polymers. There are already many excellent books on the mechanical properties of polymers, and a somewhat lesser number of volumes dealing with methods of carrying out mechanical tests on polymers. Some of these books are listed in Appendix 1. In this volume I have attempted to cover basic mechanical properties and test methods as well as the theory of polymer mechanical deformation and hope that the reader will find the approach useful.
Author: Montgomery T. Shaw Publisher: John Wiley & Sons ISBN: 0470388447 Category : Technology & Engineering Languages : en Pages : 410
Book Description
An introduction to the rheology of polymers Designed for practicing scientists and engineers interested in polymer rheology science, education, consulting, or research and development, Introduction to Polymer Rheology is a comprehensive yet accessible guide to the study of the deformation and flow of matter under applied stress. Often considered a complicated topic for beginners, the book makes grasping the fundamentals of polymer rheology easy by presenting information in an approachable way and limiting the use of complex mathematics. By doing so, this introductory overview provides readers with easy access to the key concepts underlying the flow behavior of polymer melts, solutions, and suspensions. Incorporating sample problems that are worked through and explained on the page, as well as numerous practice problems to gauge learning comprehension, the book prepares new students and practitioners for moving on to more advanced concepts. Comprising twelve chapters, the book covers stress, velocity and rate of deformation, the relationship between stress and rate of deformation (Newtonian fluid), generalized Newtonian fluids, normal stresses and elastic behavior, experimental methods, small and large strain, the molecular origins of rheological behavior, elementary polymer processing concepts, quality control in rheology, and the flow of modified polymers and those with supermolecular structure. The essential reference for accurately interpreting polymer rheology data, Introduction to Polymer Rheology provides readers with an elementary understanding of the key issues and modern approaches to resolving problems in the field.
Author: Frederick R. Eirich Publisher: Academic Press ISBN: 1483272982 Category : Technology & Engineering Languages : en Pages : 662
Book Description
Rheology: Theory and Applications, Volume 5 focuses on overtly fluid behavior of polymers, including the theory of large deformations, thermoelastic effects, elastic phenomena observed during the extrusion of polymeric melts, and theories of the structure of liquids and glasses. The selection first elaborates on the application of large deformation theory to the thermomechanical behavior of rubberlike polymers and unstable flow of molten polymers. Discussions focus on the mechanism proposed for unstable flow, ripple and associated effects, direct observation of waviness phenomena, empirical behavior of porous, unfilled, and filled rubberlike polymers, and problems connected with the interpretation of mechanical response parameters. The text then examines elasticity effects in polymer extrusion and strength and extensibility of elastomers. The publication takes a look at free volume and polymer rheology and studies of the deformation of crystalline polymers. Topics include the contribution of the two orientation processes to the birefringence, deformation of superstructure, rate of orientation of crystalline regions, free volume and physical state, glass transition and free volume, and reappraisal of time-temperature superposition. The manuscript also elaborates on the deformation and dissipative processes in high polymeric solids and the thermodynamics of deformation. The selection is a vital source of data for researchers interested in the theories and applications of rheology.
Author: Tim A. Osswald Publisher: Hanser Gardner Publications ISBN: 9781569905173 Category : Technology & Engineering Languages : en Pages : 225
Book Description
Rheology unites the seemingly unrelated fields of plasticity and non-Newtonian fluids by recognizing that both these types of materials are unable to support a shear stress in static equilibrium. In this sense, a plastic solid is a fluid. Granular rheology refers to the continuum mechanical description of granular materials. In this book, rheology--the study of the deformation and flow of matter--is treated primarily in the context of the stresses generated during the flow of complex materials such as polymers, colloids, foams, and gels. A rapidly growing and industrially important field, it plays a significant role in polymer processing, food processing, coating and printing, and many other manufacturing processes.
Author: R.S. Lenk Publisher: Springer Science & Business Media ISBN: 940109666X Category : Science Languages : en Pages : 380
Book Description
Everything flows, so rheology is a universal science. Even if we set aside claims of such width, there can be no doubt of its importance in polymers. It joins with chemistry in the polymerisation step but polymer engineering is supreme in all the succeeding steps. This is the area concerned with the fabrication of the polymer into articles or components, with their design to meet the needs in service, and with the long and short term performance of the article or component. This is a typical area of professional engineering activity, but one as yet without its proper complement of professional engineers. An understanding of polymer rheology is the key to effective design and material plus process selection, to efficient fabrication, and to satisfactory service, yet few engineers make adequate use of what is known and understood in polymer rheology. Its importance in the flow processes of fabrication is obvious. Less obvious, but equally important, are the rheological phenomena which determine the in-service performance. There is a gap between the polymer rheologist and the polymer engineer which is damaging to both parties and which contributes to a less than satisfactory use of polymers in our society. It is important that this gap be filled and this book makes an attempt to do so. It presents an outline of what is known in a concise and logical fashion. It does this starting from first principles and with the minimum use of complex mathematics.
Author: Helmut Münstedt
Author: A. S. Argon
Author: Helmut Münstedt
Author: Helmut Münstedt
Author: Connie B. Roth
Author: G.M. Swallowe
Author: Montgomery T. Shaw
Author: Lawrence E. Nielsen
Author: Frederick R. Eirich
Author: Tim A. Osswald
Author: R.S. Lenk