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Author: Publisher: ISBN: Category : Languages : en Pages :
Book Description
This research program has had two major areas of focus that are related: (1) alloy corrosion and (2) the role of selective dissolution in the stress corrosion cracking of alloy systems. These interrelated issues were examined using model systems such as Ag-Au and Cu-Au by conventional electrochemical techniques, in situ scanning tunneling microscopy (STM), in situ small angle neutron scattering (SANS), ultrahigh speed digital photography of fracture events, and computer simulations. The STM and SANS work were specifically aimed at addressing a roughening transition known to occur in alloy systems undergoing corrosion at electrochemical potentials greater than the so-called critical potential. Analytical models of de-alloying processes including the roughening transition were developed that specifically include curvature effects that are important in alloy corrosion processes. Stress-corrosion experiments were performed on the same model systems using rapid optical and electrochemical techniques on 50[micro]m--250[micro]m thick sheets and small diameter wires. The primary goal of this work was to develop a fundamental understanding of the corrosion and electrochemistry of alloys and the stress-corrosion cracking processes these alloys undergo. Computer simulations and analytical work identified surface stress and an important parameter in environmentally assisted fracture. The major results of the research on this program since the summer of 1993 are briefly summarized.
Author: Publisher: ISBN: Category : Languages : en Pages :
Book Description
This research program has had two major areas of focus that are related: (1) alloy corrosion and (2) the role of selective dissolution in the stress corrosion cracking of alloy systems. These interrelated issues were examined using model systems such as Ag-Au and Cu-Au by conventional electrochemical techniques, in situ scanning tunneling microscopy (STM), in situ small angle neutron scattering (SANS), ultrahigh speed digital photography of fracture events, and computer simulations. The STM and SANS work were specifically aimed at addressing a roughening transition known to occur in alloy systems undergoing corrosion at electrochemical potentials greater than the so-called critical potential. Analytical models of de-alloying processes including the roughening transition were developed that specifically include curvature effects that are important in alloy corrosion processes. Stress-corrosion experiments were performed on the same model systems using rapid optical and electrochemical techniques on 50[micro]m--250[micro]m thick sheets and small diameter wires. The primary goal of this work was to develop a fundamental understanding of the corrosion and electrochemistry of alloys and the stress-corrosion cracking processes these alloys undergo. Computer simulations and analytical work identified surface stress and an important parameter in environmentally assisted fracture. The major results of the research on this program since the summer of 1993 are briefly summarized.
Author: Publisher: ISBN: Category : Languages : en Pages : 26
Book Description
Results of work on fracture properties of porous dealloyed gold structures indicates that this material undergoes a brittle-ductile transition as the size scale of the porosity increases. Aspects of the work reported on and proposed address fundamental issues related corrosion in alloy systems. De-alloyed film induce brittle fracture experiments are being performed on Ag-Au and Cu-Au alloy thin sheets. An indirect potential drop technique is being developed to measure dynamic crack motion. Preliminary work is being performed to determine optimum conditions for film thickness-crack penetration experiments.
Author: V S Raja Publisher: Elsevier ISBN: 0857093762 Category : Technology & Engineering Languages : en Pages : 817
Book Description
The problem of stress corrosion cracking (SCC), which causes sudden failure of metals and other materials subjected to stress in corrosive environment(s), has a significant impact on a number of sectors including the oil and gas industries and nuclear power production. Stress corrosion cracking reviews the fundamentals of the phenomenon as well as examining stress corrosion behaviour in specific materials and particular industries. The book is divided into four parts. Part one covers the mechanisms of SCC and hydrogen embrittlement, while the focus of part two is on methods of testing for SCC in metals. Chapters in part three each review the phenomenon with reference to a specific material, with a variety of metals, alloys and composites discussed, including steels, titanium alloys and polymer composites. In part four, the effect of SCC in various industries is examined, with chapters covering subjects such as aerospace engineering, nuclear reactors, utilities and pipelines. With its distinguished editors and international team of contributors, Stress corrosion cracking is an essential reference for engineers and designers working with metals, alloys and polymers, and will be an invaluable tool for any industries in which metallic components are exposed to tension, corrosive environments at ambient and high temperatures. Examines the mechanisms of stress corrosion cracking (SCC) presenting recognising testing methods and materials resistant to SCC Assesses the effect of SCC on particular metals featuring steel, stainless steel, nickel-based alloys, magnesium alloys, copper-based alloys and welds in steels Reviews the monitoring and management of SCC and the affect of SCC in different industries such as petrochemical and aerospace
Author: Publisher: ISBN: Category : Languages : en Pages : 6
Book Description
This report describes our progress since the last reporting reporting period (March 1991) and details the third year research plans on the program. The three major components of the program relate to (1) kinetic aspects of the selective dissolution in alloys and the coarsening of de-alloyed layers, (2) measurements of crack dynamics during film induced cleavage processes, and (3) mechanical properties of the intrinsic de-alloyed layers responsible for film-induced cleavage events. We discuss progress in each of these areas below.
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Author: V S Raja
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Author: Benjamin Floyd Brown
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Author: T. Sharabi
Author: Naval Research Laboratory (U.S.)