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Author: Jacques Teddy Publisher: ISBN: Category : Languages : en Pages : 0
Book Description
In this work, we describe the synthesis, structure, physical properties and some applications in catalysis of previously known carbon allotropes, and recently discovered carbon nanostructure (Chapter I). First, FB-OM-CVD deposition was used for metal or metal oxide deposition on metal oxide supports like alumina or silica, leading to the production of supported catalysts. The resulting material was used as catalyst for catalytic chemical vapor deposition of carbonaceous nanostructures i.e single- and multi-walled carbon nanotubes (SWCNTs, MWCNTs), carbon nanofibers (CNFs), and nitrogen doped carbon nanotubes (N-MWCNTs) and nanofibers (N-CNFs) (Chapter II). After catalyst removal by a H2SO4 or NaOH treatments and carboxylic surface group generation by a HNO3 treatment in the case of MWCNTs and CNFs, the carbon nanostructures were used as supports for heterogeneous catalysis. The hydrogenation of cinnamaldehyde was used as a model reaction to compare the performance of different bimetallic Pt-Ru catalysts as a function of the nature of the support. Detailed parametric studies as well as the effect of a heat treatment on the performance improvement of the Pt-Ru/MWCNT catalyst are presented. An explanation for the increase of performances upon heat treatment will be proposed after HREM, EDX, EXAFS and WAXS characterization of the catalyst (Chapter III). The prepared carbon nanostructures were also tested as supports for Pd based electrocatalysts for direct alkaline fuel cells applications in both cathodes for the ORR reaction and anodes for alcohols oxidation.
Author: Jacques Teddy Publisher: ISBN: Category : Languages : en Pages : 0
Book Description
In this work, we describe the synthesis, structure, physical properties and some applications in catalysis of previously known carbon allotropes, and recently discovered carbon nanostructure (Chapter I). First, FB-OM-CVD deposition was used for metal or metal oxide deposition on metal oxide supports like alumina or silica, leading to the production of supported catalysts. The resulting material was used as catalyst for catalytic chemical vapor deposition of carbonaceous nanostructures i.e single- and multi-walled carbon nanotubes (SWCNTs, MWCNTs), carbon nanofibers (CNFs), and nitrogen doped carbon nanotubes (N-MWCNTs) and nanofibers (N-CNFs) (Chapter II). After catalyst removal by a H2SO4 or NaOH treatments and carboxylic surface group generation by a HNO3 treatment in the case of MWCNTs and CNFs, the carbon nanostructures were used as supports for heterogeneous catalysis. The hydrogenation of cinnamaldehyde was used as a model reaction to compare the performance of different bimetallic Pt-Ru catalysts as a function of the nature of the support. Detailed parametric studies as well as the effect of a heat treatment on the performance improvement of the Pt-Ru/MWCNT catalyst are presented. An explanation for the increase of performances upon heat treatment will be proposed after HREM, EDX, EXAFS and WAXS characterization of the catalyst (Chapter III). The prepared carbon nanostructures were also tested as supports for Pd based electrocatalysts for direct alkaline fuel cells applications in both cathodes for the ORR reaction and anodes for alcohols oxidation.
Author: Noorhana Yahya Publisher: Springer Science & Business Media ISBN: 3642146732 Category : Technology & Engineering Languages : en Pages : 413
Book Description
This volume covers all aspects of carbon and oxide based nanostructured materials. The topics include synthesis, characterization and application of carbon-based namely carbon nanotubes, carbon nanofibres, fullerenes, carbon filled composites etc. In addition, metal oxides namely, ZnO, TiO2, Fe2O3, ferrites, garnets etc., for various applications like sensors, solar cells, transformers, antennas, catalysts, batteries, lubricants, are presented. The book also includes the modeling of oxide and carbon based nanomaterials. The book covers the topics: Synthesis, characterization and application of carbon nanotubes, carbon nanofibres, fullerenes Synthesis, characterization and application of oxide based nanomaterials. Nanostructured magnetic and electric materials and their applications. Nanostructured materials for petro-chemical industry. Oxide and carbon based thin films for electronics and sustainable energy. Theory, calculations and modeling of nanostructured materials.
Author: Mineo Hiramatsu Publisher: Springer Science & Business Media ISBN: 3211997180 Category : Technology & Engineering Languages : en Pages : 168
Book Description
Representing the first text to cover this exciting new area of research, this book will describe synthesis techniques of CNWs, their characterization and various expected applications using CNWs. Carbon-nanowalls (CNWs) can be described as two-dimensional graphite nanostructures with edges comprised of stacks of plane graphene sheets standing almost vertically on the substrate. These sheets form a wall structure with a high aspect ratio. The thickness of CNWs ranges from a few nm to a few tens of nm. The large surface area and sharp edges of CNWs may prove useful for a number of applications such as electrochemical devices, field electron emitters, storage materials for hydrogen gas, catalyst support. In particular, vertically standing CNWs with a high surface-to-volume ratio, serve as an ideal material for catalyst support for fuel cells and in gas storage materials.
Author: Ravindra Rajarao Publisher: LAP Lambert Academic Publishing ISBN: 9783659219856 Category : Languages : en Pages : 252
Book Description
Since the discovery of carbon nanotubes by Sumio Iijima, an intensive research on carbon materials has been carried out. Carbon nanotubes and carbon nanofibers have drawn much attention due to their electronic and mechanical properties. However, because of low production capacity and high production costs at present, their applications cannot be extended until large-scale production is realized. Among the many synthetic methods, chemical vapor deposition method has advantages of high yield, high selectivity and low cost over traditional physical ones such as laser ablation and arc-discharge. High yield synthesis of one dimensional carbon nanostructures is essential for applications. In this book, an economical and environmental friendly route for the scalable production of CNTs and CNFs on easy soluble support has been discussed. The use of synthesized carbon nanotubes as catalyst support for oxidation of alcohols by Schiff base complexes and also as hydrogen storage materials is discussed in detail.
Author: Boris Ildusovich Kharisov Publisher: Springer ISBN: 3030035050 Category : Technology & Engineering Languages : en Pages : 790
Book Description
This book provides a detailed description of metal-complex functionalized carbon allotrope forms, including classic (such as graphite), rare (such as M- or T-carbon), and nanoforms (such as carbon nanotubes, nanodiamonds, etc.). Filling a void in the nanotechnology literature, the book presents chapters generalizing the synthesis, structure, properties, and applications of all known carbon allotropes. Metal-complex composites of carbons are described, along with several examples of their preparation and characterization, soluble metal-complex carbon composites, cost-benefit data, metal complexes as precursors of carbon allotropes, and applications. A lab manual on the synthesis and characterization of carbon allotropes and their metal-complex composites is included. Provides a complete description of all carbon allotropes, both classic and rare, as well as carbon nanostructures and their metal-complex composites; Contains a laboratory manual of experiments on the synthesis and characterization of metal-complex carbon composites; Discusses applications in diverse fields, such as catalysis on supporting materials, water treatment, sensors, drug delivery, and devices.
Author: Ge Li Publisher: ISBN: Category : Languages : en Pages :
Book Description
This thesis discussed the design of substrate and catalyst for chemical vapor deposition synthesis of carbon nanotubes (CNT). It was focused on synthesis CNTs on the various substrates, such as Si, Cu and SiC. The research was structured as following: (1) characterization of the Al2O3 buffer layer produced by plasma oxidation in order to find out the its effect on CNT growth; (2) study of the position parameters in CVD system to optimize process condition for manufacturing CNTs; (3) exploring novel composite catalyst alloys; (4) design new substrate for synthesis of vertically aligned CNTs on Cu and SiC for thermal application. Advanced surface analysis techniques were used to explore the role of AI2O3 supporting layer and of the composite catalyst. Although the data is insufficient for coming to a conclusion on the mechanism behind CNT super-growth, the preliminary studies provide guidance for selecting catalyst composite which will allow scaling up CNT production. A series of experiments using two CVD system (ET 1000 & ET 3000) were conducted which allowed for optimize the growth parameter and produce CNT arrays with uniform length. Vertically aligned CNTs arrays were successfully synthesized on copper and SiC substrates by adding supporting layers and adjusting the CVD growth conditions. This achievement engenders a wide range of future application in the field of thermal management.
Author: Hosam El-Din Saleh Publisher: BoD – Books on Demand ISBN: 1789844010 Category : Technology & Engineering Languages : en Pages : 250
Book Description
Carbon nanotubes belong to new nanomaterials and have been known for almost 20 years, but their history is somewhat lengthier. They have been identified as promising candidates for various applications.High-temperature preparation techniques are conventional techniques for the synthesis of carbon nanotubes using arc discharge or laser ablation, but today these methods are being replaced by low-temperature vapor deposition techniques, since orientation, alignment, nanotube length, diameter, purity, and density of carbon nanotubes can be precisely controlled. The synthesis of carbon nanotubes by chemical vapor deposition on catalyst arrays leads to nanotube models grown from specific sites on surfaces. The controlled synthesis of nanotubes opens up interesting possibilities in nanoscience and nanotechnologies, including electrical, mechanical and electromechanical properties and devices, chemical functionalization, surface chemistry and photochemistry, molecular sensors, and interfacing with moderate biological systems.Carbon nanotubes are used in many applications due to their unique electrical, mechanical, optical, thermal, and other properties. Conductive and high-strength composite materials, energy saving and energy conversion devices, sensors, visualization of field emissions and sources of radiation, means for storing hydrogen, and nanoscale semiconductor devices, probes, and interconnections are some of the many applications of carbon nanotubes.
Author: Philippe Serp Publisher: Royal Society of Chemistry ISBN: 1782624570 Category : Science Languages : en Pages : 570
Book Description
"We heartily recommend this book to all readers who wish to gain a better understanding of nanostructured carbon materials surface properties and used in catalysis." An-Hui Lu, ChemCatChem There is great interest in using nanostructured carbon materials in catalysis, either as supports for immobilizing active species or as metal-free catalysts due to their unique structural, thermal, chemical, electronic and mechanical properties, and tailorable surface chemistry. This book looks at the structure and properties of different doped and undoped nanocarbons including graphene; fullerenes; nanodiamonds; carbon nanotubes and nanofibers; their synthesis and modification to produce catalysts. Special attention is paid to adsorption, as it impacts the application of these materials in various industrially relevant catalytic reactions discussed herein, in addition to photocatalysis and electrocatalysis. Written by leading experts in the area, this is the first book to provide a comprehensive view of the subject for the catalysis community.
Author: Klaus Muellen Publisher: Walter de Gruyter GmbH & Co KG ISBN: 3110381621 Category : Science Languages : en Pages : 380
Book Description
Chemistry of Carbon Nanostructures aims to present the current state-of-the-art synthesis and application of carbon materials like nano diamonds, ribbons and graphene-like structures in science and engineering. Edited by Professor Klaus Müllen, who received the Adolf von Bayer Medal for his contribution to Carbon Chemistry, and Xinliang Feng, this book combines outstanding contributions by a renowned international team of experts. The authors discuss chemical aspects of carbon nanostructures, their synthesis, functionalization and design strategies for defi ned applications. Recent advances in carbon nanomembranes, molecule-assisted ultrasound-induced liquid-phase exfoliation of graphene, and solution synthesis of graphene nanoribbons and biological application of nanodiamonds are highlighted topics. This book provides an excellent reference on the chemistry of carbon nanostructures for Chemists, Materials Scientists, Condensed-matter Physicists, Surface Scientists, and Engineers.
Author: Bharat Apparao Bhanvase Publisher: Elsevier ISBN: 0443135800 Category : Technology & Engineering Languages : en Pages : 546
Book Description
Bio-derived Carbon Nanostructures: Fundamentals, Synthesis and Applications explores the entire journey, from selecting the right source materials to crafting them into precisely engineered carbon nanostructures with a purpose. Opening with an exploration of raw materials and their structural intricacies, offering readers a profound insight into the transformation of bio-based resources into highly functional carbon nanostructures. These remarkable materials find applications that span energy, environmental solutions, catalysis, and innovative additives. Unveiling the latest technological advancements, this book delves into the exciting realm of emerging applications and the challenges of scaling up these technologies for widespread use. These novel materials originate from nature, promising a sustainable future. Ideal for students, researchers and those in industry focusing on materials science and biomass utilization, and chemical engineers, this book is the key to unlocking the potential of novel carbon-based nanomaterials for a sustainable tomorrow. Presents the art of crafting bio-derived carbon nanostructures, their applications, and scale up issues Unveils the secrets behind various fabrication techniques and provides background for manufacturing. Embarks on a journey through the fundamentals of process-property relationships and cutting-edge characterization methods Explores and compares diverse preparation and characterization techniques, unveiling their remarkable outcomes
Author: Jacques Teddy
Author: Jacques Teddy
Author: Noorhana Yahya
Author: Mineo Hiramatsu
Author: Ravindra Rajarao
Author: Boris Ildusovich Kharisov
Author: Ge Li
Author: Hosam El-Din Saleh
Author: Philippe Serp
Author: Klaus Muellen
Author: Bharat Apparao Bhanvase