Author: Yuan T. Lee
Publisher:
ISBN:
Category :
Languages : en
Pages : 82
Book Description
Rapid developments in the study of oxygen reaction chemistry occurred as it is succeeded in obtaining an O(1D) beam source and commenced investigating the dynamics of several important reactions of O(3P) and O(1D). In the reaction of O(3P) with C6H6 and C6D6, two competing channels, one producing a stabilized addition complex and the other forming radical products C6H50 + H has been identified. Studies of the effects of collision energy and of deuteration were used to clarify the reaction mechanism. The reaction of O(3P) with another aromatic hydrocarbon toluene, results in competition between two substitution channels, loss of H atom and loss of CH3. In contrast to the 0 + C6H6 reaction, no stabilized oxygen-toluene adduct was observed.
Crossed Molecular Beam Study of the Reactions of Oxygen and Fluorine Atoms
Author: Yuan T. Lee
Publisher:
ISBN:
Category :
Languages : en
Pages : 82
Book Description
Rapid developments in the study of oxygen reaction chemistry occurred as it is succeeded in obtaining an O(1D) beam source and commenced investigating the dynamics of several important reactions of O(3P) and O(1D). In the reaction of O(3P) with C6H6 and C6D6, two competing channels, one producing a stabilized addition complex and the other forming radical products C6H50 + H has been identified. Studies of the effects of collision energy and of deuteration were used to clarify the reaction mechanism. The reaction of O(3P) with another aromatic hydrocarbon toluene, results in competition between two substitution channels, loss of H atom and loss of CH3. In contrast to the 0 + C6H6 reaction, no stabilized oxygen-toluene adduct was observed.
Publisher:
ISBN:
Category :
Languages : en
Pages : 82
Book Description
Rapid developments in the study of oxygen reaction chemistry occurred as it is succeeded in obtaining an O(1D) beam source and commenced investigating the dynamics of several important reactions of O(3P) and O(1D). In the reaction of O(3P) with C6H6 and C6D6, two competing channels, one producing a stabilized addition complex and the other forming radical products C6H50 + H has been identified. Studies of the effects of collision energy and of deuteration were used to clarify the reaction mechanism. The reaction of O(3P) with another aromatic hydrocarbon toluene, results in competition between two substitution channels, loss of H atom and loss of CH3. In contrast to the 0 + C6H6 reaction, no stabilized oxygen-toluene adduct was observed.
Crossed Molecular Beam Study of the Reactions of Oxygen Atoms and Free Radicals
Author: Yuan Tseh Lee
Publisher:
ISBN:
Category :
Languages : en
Pages : 11
Book Description
The development of rare gas seeded fluorine atom beam source and reactions studied by this new source are main subject of this brief final report. F+CH3I to IF + CH3 reaction has been studied.
Publisher:
ISBN:
Category :
Languages : en
Pages : 11
Book Description
The development of rare gas seeded fluorine atom beam source and reactions studied by this new source are main subject of this brief final report. F+CH3I to IF + CH3 reaction has been studied.
Crossed Molecular Beam Studies of the Reactions of Oxygen and Fluorine Atoms
Author: Y. T. Lee
Publisher:
ISBN:
Category :
Languages : en
Pages : 83
Book Description
This annual report describes the primary photodissociation of acetylene (C2H2) and bromoiodomethane (CH2BrI) using a new molecular beam photofragmentation translational spectrometer. The new third generation molecular beam photofragmentation translational spectrometer constructed during the past year is described in detail. This apparatus incorporates many new ideas and allows us to study some of the primary dissociation processes of polyatomic molecules which were not possible in the past. The dissociation of Ch2BrI at 248 and 193 nm is extremely interesting. The competition between C-I and CC-Br bond rupture is the key question, but dissociations at 193 nm also produces IBr products. Secondary photodissociations of primary products were also found to be important. These two systems are carried out partly for the purpose of evaluating the performance of the new molecular beam photofragmentation apparatus. The results clearly show that the performance of the apparatus is as good as our original expectation and that it should be capable of handling molecules with very low vapor pressures; studies of these molecules, such as the nitroamines, are planned. Additional keywords: Unimolecular decay photochemistry; rocket fuels; energetic materials; polyatomic molecules; Naval Research. (Author).
Publisher:
ISBN:
Category :
Languages : en
Pages : 83
Book Description
This annual report describes the primary photodissociation of acetylene (C2H2) and bromoiodomethane (CH2BrI) using a new molecular beam photofragmentation translational spectrometer. The new third generation molecular beam photofragmentation translational spectrometer constructed during the past year is described in detail. This apparatus incorporates many new ideas and allows us to study some of the primary dissociation processes of polyatomic molecules which were not possible in the past. The dissociation of Ch2BrI at 248 and 193 nm is extremely interesting. The competition between C-I and CC-Br bond rupture is the key question, but dissociations at 193 nm also produces IBr products. Secondary photodissociations of primary products were also found to be important. These two systems are carried out partly for the purpose of evaluating the performance of the new molecular beam photofragmentation apparatus. The results clearly show that the performance of the apparatus is as good as our original expectation and that it should be capable of handling molecules with very low vapor pressures; studies of these molecules, such as the nitroamines, are planned. Additional keywords: Unimolecular decay photochemistry; rocket fuels; energetic materials; polyatomic molecules; Naval Research. (Author).
Crossed Molecular Beam Studies of Atmospheric Chemical Reaction Dynamics
Crossed Molecular Beam Studies of Unimolecular Reaction Dynamics. [Angular and Velocity Distributions].
Author:
Publisher:
ISBN:
Category :
Languages : en
Pages :
Book Description
The study of seven radical-molecule reactions using the crossed molecular beam technique with supersonic nozzle beams is reported. Product angular and velocity distributions were obtained and compared with statistical calculations in order to identify dynamical features of the reactions. In the reaction of chlorine and fluorine atoms with vinyl bromide, the product energy distributions are found to deviate from predictions of the statistical model. A similar effect is observed in the reaction of chlorine atoms with 1, 2 and 3-bromopropene. The reaction of oxygen atoms with ICl and CF3I has been used to obtain an improved value of the IO bond energy, 55.0 +- 2.0 kcal mol−1. In all reactions studied, the product energy and angular distributions are found to be coupled, and this is attributed to a kinematic effect of the conservation of angular momentum.
Publisher:
ISBN:
Category :
Languages : en
Pages :
Book Description
The study of seven radical-molecule reactions using the crossed molecular beam technique with supersonic nozzle beams is reported. Product angular and velocity distributions were obtained and compared with statistical calculations in order to identify dynamical features of the reactions. In the reaction of chlorine and fluorine atoms with vinyl bromide, the product energy distributions are found to deviate from predictions of the statistical model. A similar effect is observed in the reaction of chlorine atoms with 1, 2 and 3-bromopropene. The reaction of oxygen atoms with ICl and CF3I has been used to obtain an improved value of the IO bond energy, 55.0 +- 2.0 kcal mol−1. In all reactions studied, the product energy and angular distributions are found to be coupled, and this is attributed to a kinematic effect of the conservation of angular momentum.
Crossed Molecular Beam Studies of Ground State Oxygen Atom Reactions
Crossed Molecular Beam Study on the Reaction Dynamics of Fluorine Molecule with Propene
Crossed Molecular Beam Studies of Unimolecular Reaction Dynamics
Molecular Beam Studies of Oxygen Atom Reactions with Unsaturated Hydrocarbons
Author: Annemarie Schmoltner
Publisher:
ISBN:
Category :
Languages : en
Pages : 628
Book Description
Publisher:
ISBN:
Category :
Languages : en
Pages : 628
Book Description
Crossed-molecular-beams Reactive Scattering of Oxygen Atoms
Author:
Publisher:
ISBN:
Category :
Languages : en
Pages :
Book Description
The reactions of O(3P) with six prototypical unsaturated hydrocarbons, and the reaction of O(1D) with HD, have been studied in high-resolution crossed-molecular-beams scattering experiments with mass-spectrometric detection. The observed laboratory-product angular and velocity distributions unambiguously identify parent-daughter ion pairs, distinguish different neutral sources of the same ion, and have been used to identify the primary products of the reactions. The derived center-of-mass product angular and translational energy distributions have been used to elucidate the detailed reaction dynamics. These results demonstrate that O(3P)-unsaturated hydrocarbon chemistry is dominated by single bond cleavages, leading to radical products exclusively.
Publisher:
ISBN:
Category :
Languages : en
Pages :
Book Description
The reactions of O(3P) with six prototypical unsaturated hydrocarbons, and the reaction of O(1D) with HD, have been studied in high-resolution crossed-molecular-beams scattering experiments with mass-spectrometric detection. The observed laboratory-product angular and velocity distributions unambiguously identify parent-daughter ion pairs, distinguish different neutral sources of the same ion, and have been used to identify the primary products of the reactions. The derived center-of-mass product angular and translational energy distributions have been used to elucidate the detailed reaction dynamics. These results demonstrate that O(3P)-unsaturated hydrocarbon chemistry is dominated by single bond cleavages, leading to radical products exclusively.