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Covalent Organic Frameworks

Covalent Organic Frameworks PDF Author: Atsushi Nagai
Publisher: CRC Press
ISBN: 1000759172
Category : Science
Languages : en
Pages : 154

Book Description
Rational synthesis of extended arrays of organic matter in bulk, solution, crystals, and thin films has always been a paramount goal of chemistry. The classical synthetic tools to obtain long-range regularity are, however, limited to noncovalent interactions, which usually yield structurally more random products. Hence, a combination of porosity and regularity in organic covalently bonded materials requires not only the design of molecular building blocks that allow for growth into a nonperturbed, regular geometry but also a condensation mechanism that progresses under reversible, thermodynamic, self-optimizing conditions. Covalent organic frameworks (COFs), a variety of 2D crystalline porous materials composed of light elements, resemble an sp2-carbon-based graphene sheet but have a different molecular skeleton formed by orderly linkage of building blocks to constitute a flat organic sheet. COFs have attracted considerable attention in the past decade because of their versatile applications in gas storage and separation, catalysis, sensing, drug delivery, and optoelectronic materials development. Compared to other porous materials, COFs allow for atomically precise control of their architectures by changing the structure of their building blocks, whereby the shapes and sizes of their pores can be well-tuned. Covalent Organic Frameworks is a compilation of different topics in COF research, from COF design and synthesis, crystallization, and structural linkages to the theory of gas sorption and various applications of COFs, such as heterogeneous catalysts, energy storage (e.g., semiconductors and batteries), and biomedicine. This handbook will appeal to anyone interested in nanotechnology and new materials of gas adsorption and storage, heterogeneous catalysts, electronic devices, and biomedical devices.

Covalent Organic Frameworks

Covalent Organic Frameworks PDF Author: Atsushi Nagai
Publisher: CRC Press
ISBN: 1000759172
Category : Science
Languages : en
Pages : 154

Book Description
Rational synthesis of extended arrays of organic matter in bulk, solution, crystals, and thin films has always been a paramount goal of chemistry. The classical synthetic tools to obtain long-range regularity are, however, limited to noncovalent interactions, which usually yield structurally more random products. Hence, a combination of porosity and regularity in organic covalently bonded materials requires not only the design of molecular building blocks that allow for growth into a nonperturbed, regular geometry but also a condensation mechanism that progresses under reversible, thermodynamic, self-optimizing conditions. Covalent organic frameworks (COFs), a variety of 2D crystalline porous materials composed of light elements, resemble an sp2-carbon-based graphene sheet but have a different molecular skeleton formed by orderly linkage of building blocks to constitute a flat organic sheet. COFs have attracted considerable attention in the past decade because of their versatile applications in gas storage and separation, catalysis, sensing, drug delivery, and optoelectronic materials development. Compared to other porous materials, COFs allow for atomically precise control of their architectures by changing the structure of their building blocks, whereby the shapes and sizes of their pores can be well-tuned. Covalent Organic Frameworks is a compilation of different topics in COF research, from COF design and synthesis, crystallization, and structural linkages to the theory of gas sorption and various applications of COFs, such as heterogeneous catalysts, energy storage (e.g., semiconductors and batteries), and biomedicine. This handbook will appeal to anyone interested in nanotechnology and new materials of gas adsorption and storage, heterogeneous catalysts, electronic devices, and biomedical devices.

Introduction to Reticular Chemistry

Introduction to Reticular Chemistry PDF Author: Omar M. Yaghi
Publisher: John Wiley & Sons
ISBN: 3527821104
Category : Science
Languages : en
Pages : 684

Book Description
A concise introduction to the chemistry and design principles behind important metal-organic frameworks and related porous materials Reticular chemistry has been applied to synthesize new classes of porous materials that are successfully used for myraid applications in areas such as gas separation, catalysis, energy, and electronics. Introduction to Reticular Chemistry gives an unique overview of the principles of the chemistry behind metal-organic frameworks (MOFs), covalent organic frameworks (COFs), and zeolitic imidazolate frameworks (ZIFs). Written by one of the pioneers in the field, this book covers all important aspects of reticular chemistry, including design and synthesis, properties and characterization, as well as current and future applications Designed to be an accessible resource, the book is written in an easy-to-understand style. It includes an extensive bibliography, and offers figures and videos of crystal structures that are available as an electronic supplement. Introduction to Reticular Chemistry: -Describes the underlying principles and design elements for the synthesis of important metal-organic frameworks (MOFs) and related materials -Discusses both real-life and future applications in various fields, such as clean energy and water adsorption -Offers all graphic material on a companion website -Provides first-hand knowledge by Omar Yaghi, one of the pioneers in the field, and his team. Aimed at graduate students in chemistry, structural chemists, inorganic chemists, organic chemists, catalytic chemists, and others, Introduction to Reticular Chemistry is a groundbreaking book that explores the chemistry principles and applications of MOFs, COFs, and ZIFs.

Hybrid Metal-Organic Framework and Covalent Organic Framework Polymers

Hybrid Metal-Organic Framework and Covalent Organic Framework Polymers PDF Author: Bo Wang
Publisher: Royal Society of Chemistry
ISBN: 1839163461
Category : Technology & Engineering
Languages : en
Pages : 313

Book Description
Metal–organic frameworks (MOFs) are crystalline porous materials constructed from metal ions/clusters and organic linkers, combining the merits of both organic and inorganic components. Due to high porosity, rich functionalities, well-defined open channels and diverse structures, MOFs show great potentials in field such as gas storage and separation, catalysis, and sensing. Combining them with polymers tunes their chemical, mechanical, electrical and optical properties, and endows MOFs with processability. Covalent organic frameworks (COFs) are crystalline porous materials built from organic molecular units with diverse structures and applications. Hybrid materials with intriguing properties can be achieved by appropriate preparation methods and careful selection of MOFs/COFs and polymers, broadening their potential applications. This book documents the latest research progress in MOF/COF-polymer hybrid materials and reviews and summarises hybridization strategies to achieve MOF/COF polymeric composites. It also introduces various applications and potential applicable scenarios of hybrid MOF/COF polymers. Hybrid Metal–Organic Framework and Covalent Organic Framework Polymers offers an overview to readers who are new to this field, and will appeal to graduate students and researchers working on porous materials, polymers, hybrid materials, and supramolecular chemistry.

Comprehensive Supramolecular Chemistry II

Comprehensive Supramolecular Chemistry II PDF Author: George W. Gokel
Publisher: Elsevier
ISBN: 0128031999
Category : Science
Languages : en
Pages : 4627

Book Description
Comprehensive Supramolecular Chemistry II, Second Edition, Nine Volume Set is a ‘one-stop shop’ that covers supramolecular chemistry, a field that originated from the work of researchers in organic, inorganic and physical chemistry, with some biological influence. The original edition was structured to reflect, in part, the origin of the field. However, in the past two decades, the field has changed a great deal as reflected in this new work that covers the general principles of supramolecular chemistry and molecular recognition, experimental and computational methods in supramolecular chemistry, supramolecular receptors, dynamic supramolecular chemistry, supramolecular engineering, crystallographic (engineered) assemblies, sensors, imaging agents, devices and the latest in nanotechnology. Each section begins with an introduction by an expert in the field, who offers an initial perspective on the development of the field. Each article begins with outlining basic concepts before moving on to more advanced material. Contains content that begins with the basics before moving on to more complex concepts, making it suitable for advanced undergraduates as well as academic researchers Focuses on application of the theory in practice, with particular focus on areas that have gained increasing importance in the 21st century, including nanomedicine, nanotechnology and medicinal chemistry Fully rewritten to make a completely up-to-date reference work that covers all the major advances that have taken place since the First Edition published in 1996

Encyclopedia of Interfacial Chemistry

Encyclopedia of Interfacial Chemistry PDF Author:
Publisher: Elsevier
ISBN: 0128098945
Category : Science
Languages : en
Pages : 5276

Book Description
Encyclopedia of Interfacial Chemistry: Surface Science and Electrochemistry, Seven Volume Set summarizes current, fundamental knowledge of interfacial chemistry, bringing readers the latest developments in the field. As the chemical and physical properties and processes at solid and liquid interfaces are the scientific basis of so many technologies which enhance our lives and create new opportunities, its important to highlight how these technologies enable the design and optimization of functional materials for heterogeneous and electro-catalysts in food production, pollution control, energy conversion and storage, medical applications requiring biocompatibility, drug delivery, and more. This book provides an interdisciplinary view that lies at the intersection of these fields. Presents fundamental knowledge of interfacial chemistry, surface science and electrochemistry and provides cutting-edge research from academics and practitioners across various fields and global regions

Modular Chemistry

Modular Chemistry PDF Author: Josef Michl
Publisher: Springer
ISBN: 9789401063531
Category : Science
Languages : en
Pages : 677

Book Description
Modular Chemistry: the First Steps In recent years, there has been increasing interest among chemists, physicists, materials scientists, biologists, engineers, and others in the assembly of well defmed, relatively large functional structures from repetitive units that themselves are molecules of some complexity. Using the dictionary defmition of a module (a detachable section, compartment, or unit with a specific purpose or function, and in electronics, a compact assembly functioning as a component of a larger unit) [1], we feel that this newly emerging field of endeavor could be called "modular chemistry" [2]. The NATO Advanced Research Workshop on Modular Chemistry that was held on September 9 to 12, 1995, at Aspen Lodge near Estes Park, Colorado, was meant to bring together prominent contributors to modular chemistry as it is being born, and to examine the associated birth pangs. It was concluded that although real, these are not nearly as bad as giving birth to a hedgehog tail first, and that the ultimate rewards were likely to be far more satisfying in terms of new ideas and enabling methodology. The level of excitement about the possibilities that are opening up for modular chemists, and also the challenge involved, are perhaps best documented by noting that the planned discussion periods at the workshop were as long as the oral presentation periods, and yet, each discussion ran over the allocated time.

Composite Nanoadsorbents

Composite Nanoadsorbents PDF Author: George Z. Kyzas
Publisher: Elsevier
ISBN: 0128141336
Category : Technology & Engineering
Languages : en
Pages : 385

Book Description
Composite Nanoadsorbents discusses the most recent advances in the field, including promising techniques for waste water decontamination and the advantages and drawbacks of nanoadsorbents in these applications. The implications of nanoadsorbents to public health and future developments for facilitating environmental sustainability are also discussed. New approaches for nanomaterials are analyzed, focusing on the effect of nanotechnology in adsorption applications. The effectiveness of nanosized materials is evaluated, along with cost factors and new synthesis routes of composite nanomaterials. Combining the areas of nanotechnology, adsorption, and composite surface chemistry, the synthesis, modifications and applications of nanotechnology in the adsorption process are demonstrated. Edited by a prolific expert in the field, this book will be a valuable resource for researchers, postgraduate students and professionals in the fields of nanotechnology, adsorption and materials synthesis. Bridges the gap between theory and application of composite nanoadsorbents Provides an understanding of the benefits of nanoadsorbents and their cost, efficiency and novelty Includes material on inorganic nanoadsorbents and carbon nanotubes

Comprehensive Nanoscience and Nanotechnology

Comprehensive Nanoscience and Nanotechnology PDF Author:
Publisher: Academic Press
ISBN: 012812296X
Category : Technology & Engineering
Languages : en
Pages : 1881

Book Description
Comprehensive Nanoscience and Technology, Second Edition, Five Volume Set allows researchers to navigate a very diverse, interdisciplinary and rapidly-changing field with up-to-date, comprehensive and authoritative coverage of every aspect of modern nanoscience and nanotechnology. Presents new chapters on the latest developments in the field Covers topics not discussed to this degree of detail in other works, such as biological devices and applications of nanotechnology Compiled and written by top international authorities in the field

Mixed Matrix Membranes

Mixed Matrix Membranes PDF Author: Clara Casado-Coterillo
Publisher: MDPI
ISBN: 3039219766
Category : Technology & Engineering
Languages : en
Pages : 146

Book Description
Mixed matrix membranes (MMMs) have attracted a large amount of interest in research laboratories worldwide in recent decades, motivated by the gap between a growing interest in developing novel mixed matrix membranes by various research groups and the lack of large-scale implementation. This Special Issue contains six publications dealing with the current opportunities and challenges of mixed matrix membranes development and applications to solve environmental and health challenges of the society of 21st century.

Porous Organic Frameworks

Porous Organic Frameworks PDF Author: Guangshan Zhu
Publisher: Springer
ISBN: 3662454564
Category : Technology & Engineering
Languages : en
Pages : 135

Book Description
This book describes the design, synthesis, characterization and applications of porous organic frameworks (POFs). Special emphasis is placed on the utilization of porous materials for CO2 capture and CH4 and H2 storage, which have promising potential for addressing the issues of environmental degradation and climate change. It also includes two chapters introducing the properties of POFs and defining the principles of synthesis, as well as a chapter dealing with post-modified POFs. This book is intended for those readers who are interested in porous materials and their applications. Guangshan Zhu is a professor at the College of Chemistry, Jilin University, China.